Citation: LIU Li, TIAN Fang-Hua, WANG Xian-You, ZHOU Meng. Electrochemical Behavior of LiV₃O₈ in Aqueous Li₂SO₄ Solution[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2600-2604. doi: 10.3866/PKU.WHXB20111126 shu

Electrochemical Behavior of LiV₃O₈ in Aqueous Li₂SO₄ Solution

LIU Li ^1,2, ,
TIAN Fang-Hua ¹ ,
WANG Xian-You ^1,2 ,
ZHOU Meng ¹

1.
1. Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, School of Chemistry, Xiangtan 411105, Hunan Province, P. R. China;
2. Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University, Xiangtan 411105, Hunan Province, P. R. China

Received Date: 13 July 2011
Available Online: 15 September 2011
Fund Project: 国家自然科学基金(20871101) (20871101) 湖南省教育厅项目(10C1250) (10C1250) 湖南省自然科学基金(11JJ4038) (11JJ4038)湖南省科技厅项目(2010RS4027)资助 (2010RS4027)

Nanostructured LiV₃O₈ powder was synthesized by a low-temperature solid-state method. Scanning election microscopy (SEM) and transmission electron microscopy (TEM) show that the as-prepared material is composed of nanostructured particles. X-ray diffraction (XRD) measurements indicate that the as-prepared material has a monoclinic structure with a space group of P2₁/m. The electrochemical properties of the LiV₃O₈ electrodes in 1 mol·L^-1 Li₂SO₄, 2 mol·L^-1 Li₂SO₄, and saturated Li₂SO₄ aqueous electrolytes were studied using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) in this work. The results show that the LiV₃O₈ electrode in the saturated Li₂SO₄ electrolyte has the best electrochemical properties. An aqueous rechargeable lithium battery (ARLB) containing a LiV₃O₈ anode, a LiNi_1/3Co_1/3Mn_1/3O₂ cathode, and a saturated Li₂SO₄ electrolyte was fabricated. The battery delivered an initial capacity of 95.2 mAh·g^-1 and retained a capacity of 37.0 mAh·g^-1 after 100 cycles at a charge-discharge rate of 0.5C (1C=300 mA·g^-1).
- Aqueous rechargeable lithium battery,
- LiV₃O₈,
- Li₂SO₄ aqueous solution,
- Aqueous electrolyte,
- Electrochemical property
1. [1]
  (1) Liu, X. H.; Saito, T.; Doi, T.; Okada, S.; Yamaki, J. J. Power Sources 2009, 189, 706.
2. [2]
  (2) Zhang, S.; Li, Y.;Wu, C.; Zheng, F.; Xie, Y. J. Phys. Chem. C 2009, 113, 15058.
3. [3]
  (3) Li,W.; Dahn, J. R.;Wainwright, D. Science 1994, 264, 1115.
4. [4]
  (4) James, G. Science 1994, 264, 1084.
5. [5]
  (5) Luo, J. Y.; Xia, Y. Y. Adv. Funct. Mater. 2007, 17, 3877.
6. [6]
  (6) Kohler, J.; Makihara, H.; Uegaito, H.; Inoue, H.; Toki, M. Electrochim. Acta 2000, 46, 59.
7. [7]
  (7) Wang, G.; Fu, L.; Zhao, N.; Yang, L.;Wu, Y.;Wu, H. Angew. Chem. Int. Edit. 2007, 46, 295.
8. [8]
  (8) Ruffo, R.;Wessells, C.; Huggins, R. A.; Cui, Y. Electrochem. Commun. 2009, 11, 247.
9. [9]
  (9) Zeng, X. L.; Huang, Y. Y.; Luo, F. L.; He, Y. B.; Tong, D. G. J. Sol-Gel Sci. Technol. 2010, 54, 139.
10. [10]
  (10) Zhao, M. S.; Song, X. P.;Wang, F.; Dai,W. M.; Lu, X. G. Electrochim. Acta 2011, 56, 5673.
11. [11]
  (11) Wang, G. J.; Zhang, H. P.; Fu, L. J.;Wang, B.;Wu, Y. P. Electrochem. Commun. 2007, 9, 1873.
12. [12]
  (12) Wang, Y.; Luo, J.;Wang, C.; Xia, Y. J. Electrochem. Soc. 2006, 153, A1425.
13. [13]
  (13) Liu, L.; Jiao, L.; Sun, J.; Zhao, M.; Zhang, Y.; Yuan, H.;Wang, Y. Solid State Ionics 2008, 178, 1756.
14. [14]
  (14) Caballero, A.; Morales, J.; Vargas, O. A. J. Power Sources 2010, 195, 4318.
15. [15]
  (15) Heli, H.; Yadegari, H.; Jabbari, A. Materials Chemistry and Physics 2011, 126, 477.
16. [16]
  (16) Nakayama, N.; Yamada, I.; Huang, Y.; Nozawa, T.; Iriyam, Y.; Abe, T.; Ogumi, Z. Electrochim. Acta 2009, 54, 3428.
17. [17]
  (17) Wang, H.; Huang, K.; Zeng, Y.; Yang, S.; Chen, L. Electrochim. Acta 2007, 52, 3280.
18. [18]
  (18) Wang, H.; Zeng, Y.; Huang, K.; Liu, S.; Chen, L. Electrochim. Acta 2007, 52, 5102.
19. [19]
  (19) Wang, G. J.; Qu, Q. T.;Wang, B.; Shi, Y.; Tian, S.;Wu, Y. P.; Holze, R. J. Power Sources 2009, 189, 503.
20. [20]
  (20) Wang, G. J.; Zhao, N. H.; Yang, L. C.;Wu, Y. P.;Wu, H. Q.; Holze, R. Electrochim. Acta 2007, 52, 4911.
21. [21]
  (21) Tang,W.; Liu, L. L.; Tian, S.; Li, L.; Yue, Y. B.;Wu, Y. P.; Guan, S. Y.; Zhu, K. Electrochem. Commun. 2010, 12, 1524.
22. [22]
  (22) Luo, J. Y.; Cui,W. J.; He, P.; Xia, Y. Y. Nature Chemistry 2010, 2, 760.
23. [23]
  (23) Wang, G. J.; Fu, L. J.;Wang, B.; Zhao, N. H.;Wu, Y. P.; Holze, R. J. Appl. Electrochem. 2008, 38, 579.
24. [24]
  (24) Wang, G. J.; Qu, Q. T.;Wang, B.; Shi, Y.; Tian, S.;Wu, Y. P.; Holze, R. Electrochim. Acta 2009, 54, 1199.
25. [25]
  (25) Chen, C. H.; Liu, J.; Amine, K. J. Power Sources 2001, 96, 321.
26. [26]
  (26) Zhao, Y.;Wang, Y. Y.; Lai, Q. Y. L.; Chen, M.; Hao, Y. J.; Ji, X. Y. Synthetic Metals 2009, 159, 336.
1. [1]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
2. [2]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-0. doi: 10.3866/PKU.WHXB202405002
3. [3]
  Hao Chen , Dongyue Yang , Gang Huang , Xinbo Zhang . Progress on Liquid Organic Electrolytes of Li-O₂ Batteries. Acta Physico-Chimica Sinica, 2024, 40(7): 2305059-0. doi: 10.3866/PKU.WHXB202305059
4. [4]
  Yuanyuan JIANG , Fangfang TU , Yuhong ZHANG , Shi CHEN , Jiayuan XIANG , Xinhui XIA . Preparation and electrochemical properties of high-stability cathode prelithiation additive. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1101-1111. doi: 10.11862/CJIC.20240441
5. [5]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
6. [6]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
7. [7]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
8. [8]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
9. [9]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
10. [10]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
11. [11]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
12. [12]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
13. [13]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
14. [14]
  Rui Yang , Hui Li , Qingfei Meng , Wenjie Li , Jiliang Wu , Yongjin Fang , Chi Huang , Yuliang Cao . Influence of PC-based Electrolyte on High-Rate Performance in Li/CrO_x Primary Battery. Acta Physico-Chimica Sinica, 2024, 40(9): 2308053-0. doi: 10.3866/PKU.WHXB202308053
15. [15]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106
16. [16]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2406014-0. doi: 10.3866/PKU.WHXB202406014
17. [17]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
18. [18]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
19. [19]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
20. [20]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094

Get Citation

PDF

XML

Metrics

PDF Downloads(1209)
Abstract views(2270)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Behavior of LiV3O8 in Aqueous Li2SO4 Solution

Metrics

通讯作者: 陈斌, bchen63@163.com

Electrochemical Behavior of LiV₃O₈ in Aqueous Li₂SO₄ Solution