Citation: LIU Lei, SONG Shi-Yong, ZHANG Ping-Yu. Preparation and Micro-Tribological Study on Dually Mixed Self-Assembled Monolayers[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 427-432. doi: 10.3866/PKU.WHXB201111213 shu

Preparation and Micro-Tribological Study on Dually Mixed Self-Assembled Monolayers

1.
1. Institute of Pharmaceutics, Pharmaceutical College, Henan University, Kaifeng 475004, Henan Province, P. R. China;
2. Key Laboratory for Special Functional Materials, Ministry of Education, Kaifeng 475004, Henan Province, P. R. China

Received Date: 29 August 2011
Available Online: 21 November 2011
Fund Project: 国家自然科学基金(51005057)资助项目 (51005057)

A series of dually mixed self-assembled monolayers were prepared by a simple step-by-step method. Four carbonyl chlorides with different chain lengths were selected and assembled onto a N-[3- (trimethoxylsilyl)propyl] ethylene diamine self-assembled monolayer. Different mixed films were obtained by controlling the ratio of co-deposited carbonyl chlorides. The structures of the films were characterized by measuring their contact angles, ellipsometric thickness, and atomic force microscopy. No phase separation was observed in the mixed films. Micro-tribological studies were also carried out on the films. It was found that frictional coefficients decreased as the ratio of the longer component was increased.
- Self-assembled monolayer,
- Micro-tribology,
- Mixed film,
- Contact angle,
- Ellipsometirc thickness,
- Atomic force microscopy
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