Citation: LIN Xiao, WU Ming-Xing, AN Jiang, MIAO Qing-Qing, QIN Da, MA Ting-Li. Optimization of the Photoelectric Performance of Large-Scale All-Flexible Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2577-2582. doi: 10.3866/PKU.WHXB20111112 shu

Optimization of the Photoelectric Performance of Large-Scale All-Flexible Dye-Sensitized Solar Cells

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Received Date: 4 July 2011
Available Online: 2 September 2011
Fund Project: 国家自然科学基金(50773008) (50773008)国家高技术研究发展计划(863) (2009AA03Z220)资助项目 (863) (2009AA03Z220)

Highly efficient large scale flexible dye-sensitized solar cells (DSCs) were successfully designed and fabricated. By the introduction of a light scattering layer or pressure, the DSC efficiency was greatly improved. The flexible DSCs with a small surface area (0.4 cm × 0.4 cm) gave a high energy conversion efficiency of 5.50%. The energy conversion efficiencies of large area DSCs (2 cm×3 cm, active area of 2.7 cm²) improved from 1.52% to 1.81% and 2.50%, which is an increase of 20.0% and 66.7% compared with the DSCs prepared without any treatment. The 5 cm×7 cm DSCs (active area of 16.2 cm²) without any optimization showed an energy conversion efficiency of 1.60% under a sunlight intensity of 40 mW·cm^-2. The mechanism for the improvement in efficiency was also studied. The results of electrochemical impedance spectroscopy (EIS) demonstrated that the pressure method can significantly reduce the series resistance (R_s) and the charge transfer resistance (R_ct) in the TiO₂/dye/electrolyte interface. Scanning electron microscopy (SEM) showed that the TiO₂ particles were far more closely connected after pressing, which was helpful for electron transport in the TiO₂ network as well as for dye adsorption. In addition, the photovoltaic parameters of these flexible DSCs were found to be stable after the 900 h stability tests. The experimental results obtained for these flexible DSCs can be used as a foundation for further basic research and for industrialization technical research.
- All-flexibility,
- Solar cell,
- Scattering layer,
- Pressure method,
- Stability
1. [1]
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737.
2. [2]
  (2) Grätzel, M. Nature 2001, 414, 338.
3. [3]
  (3) Tao, L.; Yang, Y. Z.; Shi, C.W.;Wu, Y. C.;Wu, X. Y. Acta Phys. -Chim. Sin. 2010, 26, 578. [桃李, 杨燕珍, 史成武, 吴玉程, 吴小燕. 物理化学学报, 2010, 26, 578.]
4. [4]
  (4) Li, B.; Cheng, P.; Deng, C. S. Chin. J. Chem. 2007, 20, 816.
5. [5]
  (5) Hagfeldt, A.; Boschloo, G.; Sun, L. C.; Kloo, L.; Pettersson, H. Chem. Rev. 2010, 110, 6595.
6. [6]
  (6) Pichot, F.; Pitts, J. R.; Gregg, B. A. Langmuir 2000, 16, 5626.
7. [7]
  (7) Chen, D. H.; Huang, F. Z.; Cheng, Y. B.; Caruso, R. A. Adv. Mater. 2009, 21, 2206.
8. [8]
  (8) Wang, Y.;Wu, J. H.; Fan, L. Q.; Lan, Z.; Xiao, Y. M.; Li, Q. H.; Huang, M. L. Mater. Rev. 2010, 24, 131. [王岳, 吴季怀, 范乐庆, 兰章, 肖尧明, 李清华, 黄妙良. 材料导报, 2010, 24, 131.]
9. [9]
  (9) Wang, M. K.; Anghel, A. M.; Marsan, B.; Ha, N. C.; Pootrakulchote, N.; Zakeeruddin, S. M.; Grätzel, M. J. Am. Chem. Soc. 2009, 131, 15976.
10. [10]
  (10) Yang, L.; Xin, G.;Wu, L. Q.; Ma, T. L. Prog. Chem. 2009, 21, 2242. [杨丽, 辛刚, 吴丽琼, 马廷丽. 化学进展, 2009, 21, 2242.]
11. [11]
  (11) Iwasaki, M.; Lee, C.W.; Kim, T. H.; Park,W. K. J. Ceram. Soc. Jpn. 2008, 116, 153.
12. [12]
  (12) Lindström, H.; Holmberg, A.; Magnusson, E.; Lindquist, S. E.; Malmqvist, L.; Hagfeldt, A. Nano Lett. 2001, 1, 97.
13. [13]
  (13) Lin, H.; Li, X.; Liu, Y. Z.; Li, J. B. Mater. Sci. Eng. B 2009, 161, 2.
14. [14]
  (14) Ma, T. L.; Fang, X. M.; Akiyama, M.; Inoue, K.; Nomam, H.; Abe, E. J. Electroanal. Chem. 2004, 574, 77.
15. [15]
  (15) Yang, L.;Wu, L. Q.;Wu, M. X.; Xin, G.; Lin, H.; Ma, T. L. Electrochem. Commun. 2010, 12, 1000.
16. [16]
  (16) Papageorgiou, N.; Maier,W. F.; Grätzel, M. J. Electrochem. Soc. 1997, 144, 876.
17. [17]
  (17) Han, L.; Koide, N.; Chiba, Y.; Islam, A.; Komiya, R.; Fuke, N.; Fukui, A.; Yamanaka, R. Appl. Phys. Lett. 2005, 86, 21350.
18. [18]
  (18) Usami, A. Sol. Energy Mater. Sol. Cells 2000, 64, 73.
19. [19]
  (19) Huang, F. Z.; Chen, D. H.; Zhang, X. L.; Caruso, R. A.; Cheng, Y. B. Adv. Funct. Mater. 2010, 20, 1301.
20. [20]
  (20) Liu, J.; Yang, H. T.; Zhang, J. B.; Zhou, X.W.; Lin Y. Acta Phys. -Chim. Sin. 2011, 27, 408. [刘佳, 杨浩田, 张敬波, 周晓文, 林原. 物理化学学报, 2011, 27, 408.]
21. [21]
  (21) Koide, N.; Islam, A.; Chiba, Y.; Han, L. Y. J. Photochem. Photobiol. A: Chem. 2006, 182, 296.
22. [22]
  (22) Kern, R.; Sastrawan, R.; Ferber, J.; Stangl, R.; Luther, J. Electrochim. Acta 2002, 47, 4213.
23. [23]
  (23) Wang, Q.; Moser, J. E.; Grätzel, M. J. Phys. Chem. B 2005, 109, 14945.
24. [24]
  (24) Green, A. N. M.; Palomares, E.; Haque, S. A.; Kroon, J. M.; Durrant, J. R. J. Phys. Chem. B 2005, 109, 12525.
25. [25]
  (25) Ikegami, M.; Suzuki, J.; Teshima, K.; Kawaraya, M.; Miyasaka, T. Sol. Energy Mater. Sol. Cells 2009, 93, 836.
26. [26]
  (26) Trupke, T.;Würfel, P.; Uhlendorf, I. J. Phys. Chem. B 2000, 104, 11484.
1. [1]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
2. [2]
  Fengying Zhang , Yanglin Mei , Yuman Jiang , Shenshen Zheng , Kaibo Zheng , Ying Zhou . Research progress of transient absorption spectroscopy in solar energy conversion and utilization. Acta Physico-Chimica Sinica, 2025, 41(9): 100118-0. doi: 10.1016/j.actphy.2025.100118
3. [3]
  Mingxuan Qi , Lanyu Jin , Honghe Yao , Zipeng Xu , Teng Cheng , Qi Chen , Cheng Zhu , Yang Bai . Recent progress on electrical failure and stability of perovskite solar cells under reverse bias. Acta Physico-Chimica Sinica, 2025, 41(8): 100088-0. doi: 10.1016/j.actphy.2025.100088
4. [4]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . Emerging Irreversible and Reversible Ion Migrations in Perovskites. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-0. doi: 10.3866/PKU.WHXB202311011
5. [5]
  Yawen Guo , Dawei Li , Yang Gao , Cuihong Li . Recent Progress on Stability of Organic Solar Cells Based on Non-Fullerene Acceptors. Acta Physico-Chimica Sinica, 2024, 40(6): 2306050-0. doi: 10.3866/PKU.WHXB202306050
6. [6]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
7. [7]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
8. [8]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
9. [9]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
10. [10]
  Ying Liang , Yuheng Deng , Shilv Yu , Jiahao Cheng , Jiawei Song , Jun Yao , Yichen Yang , Wanlei Zhang , Wenjing Zhou , Xin Zhang , Wenjian Shen , Guijie Liang , Bin Li , Yong Peng , Run Hu , Wangnan Li . Machine learning-guided antireflection coatings architectures and interface modification for synergistically optimizing efficient and stable perovskite solar cells. Acta Physico-Chimica Sinica, 2025, 41(9): 100098-0. doi: 10.1016/j.actphy.2025.100098
11. [11]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
12. [12]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-0. doi: 10.1016/j.actphy.2025.100082
13. [13]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
14. [14]
  Meng-Yin Wang , Ruo-Bei Huang , Jian-Feng Xiong , Jing-Hua Tian , Jian-Feng Li , Zhong-Qun Tian . Critical Role and Recent Development of Separator in Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2307017-0. doi: 10.3866/PKU.WHXB202307017
15. [15]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
16. [16]
  Nengmin ZHU , Wenhao ZHU , Xiaoyao YIN , Songzhi ZHENG , Hao LI , Zeyuan WANG , Wenhao WEI , Xuanheng CHEN , Weihai SUN . Preparation of high-performance CsPbBr₃ perovskite solar cells by the aqueous solution solvent method. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1131-1140. doi: 10.11862/CJIC.20240419
17. [17]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂ Nanosheets Improved the Buried Interface for Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-0. doi: 10.3866/PKU.WHXB202407025
18. [18]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
19. [19]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
20. [20]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309

Get Citation

PDF

XML

Metrics

PDF Downloads(1080)
Abstract views(2752)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142