Citation: XU Shou-Dong, ZHUANG Quan-Chao, SHI Yue-Li, ZHU Ya-Bo, QIU Xiang-Yun, SUN Zhi. Electrochemical Impedance Spectra of Intercalation Compound Electrodes: Models and Theoretical Simulations[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2353-2359. doi: 10.3866/PKU.WHXB20111004 shu

Electrochemical Impedance Spectra of Intercalation Compound Electrodes: Models and Theoretical Simulations

XU Shou-Dong ^1,2 ,
ZHUANG Quan-Chao ^1, ,
SHI Yue-Li ¹ ,
ZHU Ya-Bo ^1,2 ,
QIU Xiang-Yun ^1,2 ,
SUN Zhi ¹

1.
1. Li-ion Batteries Laboratory, School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China;
2. School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China

Received Date: 4 May 2011
Available Online: 15 August 2011
Fund Project: 中央高校基本科研业务费专项资金(2010LKHX03, 2010QNB04, 2010QNB05) (2010LKHX03, 2010QNB04, 2010QNB05) 中国矿业大学科技攀登计划(ON090237) (ON090237)江苏省自然科学研究基金(BK2008129)资助项目 (BK2008129)

Single intercalation particles, mixed particles, homogeneous porous electrodes and nonhomogeneous, multilayered porous electrode models are proposed in this paper. Some peculiar features of impedance spectra were simulated using the above-mentioned models. The results reveal that the features of impedance spectra of the single intercalation particle and the mixed particles are the same and the features consist of lithium ion migration through the solid electrolyte interphase (SEI) film (R_SEI‖C_SEI semicircle), an electron and ion transfer process (R_ct‖C_dl semicircle), and a finite-diffusion Warburg element. For the nonhomogeneous, multilayered porous electrodes model, a peculiar feature of impedance spectra is that a new arc appears in the Nyquist plot. A detailed analysis revealed that a different particle size distribution could lead to the appearance of a new arc and a different layer distribution (a thicker layer and a thinner layer), which could lead to a well-developed semicircle.
- Lithium ion battery,
- Intercalation compound,
- Nonhomogeneous,
- Porous electrode,
- Electrochemical impedance spectroscopy
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