Citation: LIU Yan, WEI Zhong-Ling, YANG Fu-Wei, ZHANG Zhao. Anodizing of AZ91D Magnesium Alloy in Borate-Terephthalic Acid Electrolyte[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2385-2392. doi: 10.3866/PKU.WHXB20110931 shu

Anodizing of AZ91D Magnesium Alloy in Borate-Terephthalic Acid Electrolyte

1.
1. Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China;
2. Magnesium Technology Co., Ltd, Chinese Academy of Sciences, Jiaxing 314051, Zhejiang Province, P. R. China;
3. Department of Chemistry, Tianshui Normal University, Tianshui 741000, Gansu Province, P. R. China

Received Date: 16 March 2011
Available Online: 27 July 2011
Fund Project: 国家自然科学基金(50771092, 21073162) (50771092, 21073162) 上海市重点基础研究项目(08JC1421600) (08JC1421600)嘉兴市科技领军人才计划项目(2008AZ2018)资助 (2008AZ2018)

Anodizing a AZ91D magnesium alloy in environmentally friendly borate-terephthalic acid (TPA) electrolyte was studied. The effect of TPA on the anodizing process and the properties of the resultant anodized film were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectrometry (EDS), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The results showed that the anodizing process, the surface morphology, thickness, phase structure, and corrosion resistance of the anodized film were strongly dependent on the concentration of TPA. In the presence of adequate TPA, a moderate anodizing process was obtained. The current density of the anodizing process was reduced and excessive sparking in the anodizing process was obviously inhibited. In the presence of TPA, the quality of the anodized film improved. The film became more compact and smooth in structure. The thickness of the film decreased slightly. The interface between the anodized film and the magnesium substrate became indistinct indicating a better adhesion between them. The corrosion resistance of the anodized film was obviously enhanced. From these highly positive results, TPA can be used as an effective additive for the anodizing treatment of magnesium alloy. The proposed anodizing process is of importance to make the existing anodizing process 'greener' and to improve the quality of the anodized film.
- Anodizing,
- Environmentally friendly electrolyte,
- Magnesium alloy,
- Terephthalic acid,
- Corrosion resistance
1. [1]
  (1) Gray, J. E.; Luan, B. J. Alloy. Compd. 2002, 336, 88.
2. [2]
  (2) Song, G. L.; Song, S. Z. Acta Phys. -Chim. Sin. 2006, 22, 1222.
3. [3]
  [宋光铃, 宋诗哲. 物理化学学报, 2006, 22, 1222.]
4. [4]
  (3) Jönsson, M. D.; Persson, C.; Leygraf. Corrosion Sci. 2008, 50, 1406.
5. [5]
  (4) Song, G. L. Corrosion Sci. 2007, 49, 1696.
6. [6]
  (5) Huang, R.; Chen, M. A.; Lu, X. B. Acta Phys. -Chim. Sin. 2011, 27, 113.
7. [7]
  [黄荣, 陈明安, 路学斌. 物理化学学报, 2011, 27, 113.]
8. [8]
  (6) Hamdy, A. S. Surf. Coat. Technol. 2008, 203, 240.
9. [9]
  (7) Zhang, L. J.; Zhang, Z.; Zhang, J. Q. Acta Phys. -Chim. Sin. 2008, 24, 1831.
10. [10]
  [张丽君, 张昭, 张鉴清. 物理化学学报. 2008, 24, 1831.]
11. [11]
  (8) Ryu, H. S.; Hong, S. H. J. Electrochem. Soc. 2009, 156, C298.
12. [12]
  (9) Bestetti, M.; Cavallotti, P. L. A.; Forno, Da.; Pozzi, S. T. I. Met. Finish. 2007, 85, 316.
13. [13]
  (10) Laleh, M.; Sabour Rouhaghdam, A.; Shahrabi, T.; Shanghi, A. J. Alloy. Compd. 2010, 496, 548.
14. [14]
  (11) Guo, J.;Wang, L. P.; Liang, J.; Xue, Q. J.; Yan, F. G. J. Alloy. Compd. 2009, 48, 903.
15. [15]
  (12) Walsh, F. C.; Low, C. T. J.;Wood, R. J. K.; Stevens, K. T.; Archer, J.; Poeton, A. R.; Ryder, A. Trans. Inst. Metal Finish. 2009, 87, 122.
16. [16]
  (13) Evangelides, H. A. Method of Electrolytically Coating Magnesium and Electrolyte Therefor. US Patent 2723952, 1955-11-15.
17. [17]
  (14) The Dow Chemical Company. Bath for Method of Producing a Corrosion Resistant Coating upon Light Metals. US Patent GB 762195. 1956-11-28.
18. [18]
  (15) Luo, H. H.; Cai, Q. Z.;Wei, B. K.; Yu, B.; He, J.; Li, D. J. Acta Phys. -Chim. Sin. 2008, 24, 481.
19. [19]
  [骆海贺, 蔡启舟, 魏伯康, 余博, 何剑, 李定骏. 物理化学学报, 2008, 24, 481.]
20. [20]
  (16) Wang, L.; Chen, L.; Yan, Z. C.;Wang, H. L.; Peng, J. Z. J. Alloy. Compd. 2009, 480, 469.
21. [21]
  (17) Zhang, P.; Nie, X.; Northwood, D. O. Surf. Coat. Technol. 2009, 203, 3271.
22. [22]
  (18) Bai, A.; Chen, Z. J. Surf. Coat. Technol. 2009, 203, 1956.
23. [23]
  (19) Guo, X. H.; An, M. Z.; Yang, P. X.; Li, H. X.; Su, C. N. J. Alloy. Compd. 2009, 482, 487.
24. [24]
  (20) Zhang, R. F.; Zhang, S. F.; Duo, S.W. Appl. Surf. Sci. 2009, 255, 7893.
25. [25]
  (21) Wu, D.; Liu, X. D.; Lu, K.; Zhang, Y. P.;Wang, H. Appl. Surf. Sci. 2009, 255, 7115.
26. [26]
  (22) Soni, R. K.; Dutt, K.; Jain, A.; Soam, S.; Singh, S. J. Appl. Polym. Sci. 2009, 113, 1090.
27. [27]
  (23) Fink, D.; Rojas-Chapana, J.; Petrov, A.; Tributsch, H.; Friedrich, D.; K?ppers, U.;Wilhelm, M.; Apel, P. Y.; Zrineh, A. Sol. Energy Mater. Sol. Cells 2006, 90, 1458.
28. [28]
  (24) Duartea, L. T.; Silva, E. M. P.; Brancoc, J. R. T.; Lins, V. F. C. Surf. Coat. Technol, 2004, 182, 261.
29. [29]
  (25) Acute toxicity test (GB 15193.3-2003).
30. [30]
  (26) Lv, G. H.; Chen, H.; Gu,W. C.; Li, L.; Niu, E.W.; Zhang, X. H.; Yang, S. Z. J. Mater. Process. Technol. 2008, 208, 9.
31. [31]
  (27) Wu, C. S.; Zhang, Z.; Cao, F. H.; Zhang, J. Q.; Cao, C. N. Appl. Surf. Sci. 2007, 253, 3893.
32. [32]
  (28) Barchiche, C. E.; Rocca, E.; Juers, C.; Hazan, J.; Steinmetz. J. Electrochim. Acta 2007, 53, 417.
33. [33]
  (29) Li, M. J.; Tamura, T.; Omura, N.; Miwa. K. J. Alloy. Compd. 2009, 487, 187.
34. [34]
  (30) Duan, H. P.; Yan, C.W.;Wang, F. H. Electrochim. Acta 2007, 52, 5002.
35. [35]
  (31) Chang, L. M. J. Alloy. Compd. 2009, 468, 465.
36. [36]
  (32) Guo, H. F.; An, M. Z.; Xu, S.; Huo, H. B. Thin Solid Films 2005, 485, 3.
37. [37]
  (33) Wu, H. L.; Cheng,Y. L.; Li, L. L.; Chen, Z. H.;Wang, H. M.; Zhang, Z. Appl. Surf. Sci. 2004, 253, 9387.
38. [38]
  (34) Liang, J.; Hu, L. T.; Hao, J. C. Appl. Surf. Sci. 2007, 253, 6939.
39. [39]
  (35) Bala Srinivasan, P.; Liang, J.; Blawert, C.; St?rmer, M.; Dietzel, W. Appl. Surf. Sci. 2009, 255, 4212.
40. [40]
  (36) Khaselev, O.;Weiss, D.; Yahalom, J. Corrosion Sci. 2001, 43, 1295.
41. [41]
  (37) Guo, H. F.; An, M. Z.; Xu, S.; Huo, H. B. Thin Solid Films 2005, 485, 53.
42. [42]
  (38) Wang, Y. H.;Wang, J.; Zhang, J. B.; Zhang, Z. Mater. Lett. 2006, 60, 474.
43. [43]
  (39) Lee, Y. K.; Lee, K. S.; Jung, T. Electrochem. Commun. 2008, 10, 1716.
44. [44]
  (40) Chai, L. Y.; Yu, X.; Yang, Z. H.;Wang, Y. Y.; Okido, M. Corrosion Sci. 2008, 50, 3274.
45. [45]
  (41) Cao, F. H.; Zhang, Z.; Zhang, J. Q.; Cao, C. N. Mater. Corros. 2007, 58, 696.
46. [46]
  (42) Zhang, Y. J.; Yan, C.W.;Wang, F. H.; Lou, H. Y.; Cao, C. N. Surf. Coat. Technol. 2002, 161, 36.
47. [47]
  (43) Zhang, R. F.; Shan, D. Y.; Chen, R. S.; Han, E. H. Mater. Chem. Phys. 2008, 107, 356.
48. [48]
  (44) Verdier, S.; Boinet, M.; Maximovitch, S.; Dalard, F. Corrosion Sci. 2005, 47, 1429.
49. [49]
  (45) Boinet, M.; Verdier, S.; Maximovitch, S.; Dalard, F. Surf. Coat. Technol. 2005, 199, 141.
50. [50]
  (46) Shi, Z.; Song, G.; Atrens, A. Corrosion Sci. 2006, 48, 1939.
51. [51]
  (47) Guo, H. F.; An, M. Z. Appl. Surf. Sci. 2005, 246, 229.
52. [52]
  (48) Xia, S. J.; Yue, R.; Rateick, R. G.; Briss, V. I. J. Electrochem. Soc. 2004, 151, B179.
53. [53]
  (49) Khaselev, O.;Weiss, D.; Yahalom, J. Corrosion Sci. 2001, 43, 1295.
54. [54]
  (50) Hussein, R. O.; Nie, X.; Northwood, D. O. Surf. Coat. Technol. 2010, 205, 1659.
1. [1]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
2. [2]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012
3. [3]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
4. [4]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
5. [5]
  Rui Yang , Hui Li , Qingfei Meng , Wenjie Li , Jiliang Wu , Yongjin Fang , Chi Huang , Yuliang Cao . Influence of PC-based Electrolyte on High-Rate Performance in Li/CrO_x Primary Battery. Acta Physico-Chimica Sinica, 2024, 40(9): 2308053-0. doi: 10.3866/PKU.WHXB202308053
6. [6]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106
7. [7]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
8. [8]
  Kai PENG , Xinyi ZHAO , Zixi CHEN , Xuhai ZHANG , Yuqiao ZENG , Jianqing JIANG . Progress in the application of high-entropy alloys and high-entropy ceramics in water electrolysis. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1257-1275. doi: 10.11862/CJIC.20240454
9. [9]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
10. [10]
  Zhi Dou , Huiyu Duan , Yixi Lin , Yinghui Xia , Mingbo Zheng , Zhenming Xu . High-Throughput Screening Lithium Alloy Phases and Investigation of Ion Transport for Solid Electrolyte Interphase Layer. Acta Physico-Chimica Sinica, 2024, 40(3): 2305039-0. doi: 10.3866/PKU.WHXB202305039
11. [11]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
12. [12]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
13. [13]
  Hao Chen , Dongyue Yang , Gang Huang , Xinbo Zhang . Progress on Liquid Organic Electrolytes of Li-O₂ Batteries. Acta Physico-Chimica Sinica, 2024, 40(7): 2305059-0. doi: 10.3866/PKU.WHXB202305059
14. [14]
  Xin Feng , Kexin Guo , Chunguang Jia , Bowen Liu , Suqin Ci , Junxiang Chen , Zhenhai Wen . Hydrogen Generation Coupling with High-Selectivity Electrocatalytic Glycerol Valorization into Formate in an Acid-Alkali Dual-Electrolyte Flow Electrolyzer. Acta Physico-Chimica Sinica, 2024, 40(5): 2303050-0. doi: 10.3866/PKU.WHXB202303050
15. [15]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
16. [16]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
17. [17]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
18. [18]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
19. [19]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
20. [20]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398

Get Citation

PDF

XML

Metrics

PDF Downloads(1048)
Abstract views(2479)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142