Citation: YU Yan-Jie, ZHANG Shuan-Qin, KONG Ling-Dong, LIN Li, CHENG Tian-Tao, CHEN Jian-Min. Effects of Nitrates on the Heterogeneous Reaction of Carbonyl Sulfide on Model Aerosols[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2275-2281. doi: 10.3866/PKU.WHXB20110912 shu

Effects of Nitrates on the Heterogeneous Reaction of Carbonyl Sulfide on Model Aerosols

1.
Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, P. R. China

Received Date: 15 May 2011
Available Online: 7 July 2011
Fund Project: 国家自然科学基金(40775079, 40875073, 40728006, 40533017) (40775079, 40875073, 40728006, 40533017)

The heterogeneous reaction of carbonyl sulfide (COS) on hematite particles in the presence of nitrate was investigated by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). For sodium nitrate-containing samples, the hematite sample containing NaNO₃ with mass fraction of 4% gave the highest reaction rate, which was about 5 times higher than that of hematite. For the particles containing nitrate at the same mass fraction (24%) the reactivity in descending order was α-Fe₂O₃/KNO₃, α-Fe₂O₃/NaNO₃, α-Fe₂O₃/NH₄NO₃ and α-Fe₂O₃. No uptake of COS was observed for the pure NaNO₃, KNO₃ and NH₄NO₃ samples. These results indicate that the added nitrate increased the COS conversion ability of α-Fe₂O₃ particles.
- Carbonyl sulfide,
- Aerosol,
- Nitrate,
- Heterogeneous reaction
1. [1]
  (1) Satheesh, S. K.; Ramanathean, V. Nature 2000, 405, 60.
2. [2]
  (2) Anderson, T. L.; Charlson, R. J.; Schwartz, S. E.; Knutti, R.; Boucher, O.; Rodhe, H.; Heintzenberg, J. Science 2003, 300, 1103.
3. [3]
  (3) Schwartz, S. E.; Andreae, M. O. Science 1996, 272, 1121.
4. [4]
  (4) Jacob, D. J. Atmos. Environ. 2000, 34, 2131.
5. [5]
  (5) Gard, E. E.; Kleeman, M. J.; Gross, D. S.; Hughes, L. S.; Allen, J. O.; Morrical, B. D.; Fergenson, D. P.; Dienes, T.; Gälli, M. E.; Johnson, R. J.; Cass, G. R.; Prather, K. A. Science 1998, 279, 1184.
6. [6]
  (6) Seinfeld, J. H.; Pandis, S. N. Atmospheric chemistry and physics: From air pollution to climate change. JohnWiley & Sons, Inc.: New York, 2006; pp 32-33.
7. [7]
  (7) Hofmann, D. J. Science 1990, 248, 996.
8. [8]
  (8) Thomason, L.W.; Kent, G. S.; Trepte, C. R.; Poole, L. R. J. Geophys. Res. 1997, 102, 3611.
9. [9]
  (9) Turco, R. P.; Whitten, R. C.; Toon, O. B.; Pollack, J. B.; Hamill, P. Nature 1980, 283, 283.
10. [10]
  (10) Ramanthan, V.; Crutzen, P. J.; Kiehl, J. T.; Rosenfeld, D. Science 2001, 294, 2119.
11. [11]
  (11) Watts, S. F. Atmos. Environ. 2000, 34, 761.
12. [12]
  (12) Wu, H. B.;Wang, X.; Chen, J. M.; Yu, H. K.; Xue, H. X.; Pan, X. X.; Hou, H. Q. Chinese Sci. Bull. 2004, 49 (12), 1231.
13. [13]
  [吴洪波, 王晓, 陈建民, 俞宏坤, 薛华欣, 潘循皙, 侯惠奇. 科学通报, 2004, 49 (8), 739.]
14. [14]
  (13) He, H.; Liu, J. F.; Mu, Y. J.; Yu, Y. B.; Chen, M. X. Environ. Sci. Technol. 2005, 39, 9637.
15. [15]
  (14) Liu, J. F.; Yu, Y. B.; Mu, Y. J.; He, H. J. Phys. Chem. B 2006, 110, 3225.
16. [16]
  (15) Liu, Y. C.; He, H.; Xu,W. Q.; Yu, Y. B. J. Phys. Chem. A 2007, 111, 4333.
17. [17]
  (16) Liu, Y. C.; He, H. J. Phys. Chem. A 2009, 113, 3387.
18. [18]
  (17) Chen, H.; Kong, L.; Chen, J.; Zhang, R.;Wang, L. Environ. Sci. Technol. 2007, 41, 6484.
19. [19]
  (18) Liu, Y.; Yang, Z.; Desyaterik, Y.; Gassman, P. L.;Wang, H.; Laskin, A. Anal. Chem. 2008, 80, 633.
20. [20]
  (19) Hoffman, R. C.; Laskin, A.; Finlayson-Pitts, B. J. J. Aerosol Sci. 2004, 35, 869.
21. [21]
  (20) Ullerstam M., Vogt R., Langer, S.; Ljungström, E. Phys. Chem. Chem. Phys. 2002, 4, 4694.
22. [22]
  (21) Amenomiya, Y.; Morikawa, Y.; Pleizier, G. J. Catal. 1977, 46, 431.
23. [23]
  (22) Fu, H.;Wang, X.;Wu, H.; Yin, Y.; Chen, J. J. Phys. Chem. C 2007, 111, 6077.
24. [24]
  (23) Ullerstam, M.; Johnson, M. S.; Vogt, R.; Ljungström, E. Atmos. Chem. Phys. 2003, 3, 2043.
25. [25]
  (24) Dohrmann, J.; Glebov, A.; Toennies, J. P.;Weiss, H. Surf. Sci. 1996, 368, 118.
1. [1]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
2. [2]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
3. [3]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)₂₇团簇用于硝酸盐电还原制氨：一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008
4. [4]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
5. [5]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
6. [6]
  Yiming Liang , Ziyan Pan , Kin Shing Chan . One Drink, Two Tears in the Central Nervous System: The Perils of Disulfiram-Like Reactions. University Chemistry, 2025, 40(4): 322-325. doi: 10.12461/PKU.DXHX202406016
7. [7]
  Honghong Zhang , Zhen Wei , Derek Hao , Lin Jing , Yuxi Liu , Hongxing Dai , Weiqin Wei , Jiguang Deng . Recent advances in synergistic catalytic valorization of CO₂ and hydrocarbons by heterogeneous catalysis. Acta Physico-Chimica Sinica, 2025, 41(7): 100073-. doi: 10.1016/j.actphy.2025.100073
8. [8]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
9. [9]
  Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide：Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104
10. [10]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
11. [11]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
12. [12]
  Qiuyu Xiang , Chunhua Qu , Guang Xu , Yafei Yang , Yue Xia . A Journey beyond “Alum”. University Chemistry, 2024, 39(11): 189-195. doi: 10.12461/PKU.DXHX202404094
13. [13]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN modified PP separator for high-stability and high-efficiency lithium-sulfur batteries. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-. doi: 10.1016/j.actphy.2025.100082
14. [14]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
15. [15]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
16. [16]
  Zhongbin Pan , Shijie Huang , Yunjie Luo , Hongzhen Xie . Design of a Comprehensive Experiment for Determining Permanganate Index (COD_Mn) in Drinking Water. University Chemistry, 2024, 39(7): 354-360. doi: 10.12461/PKU.DXHX202311040
17. [17]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
18. [18]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
19. [19]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
20. [20]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation

PDF

XML

Metrics

PDF Downloads(1014)
Abstract views(2213)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142