Citation: MIN Shi-Xiong, Lü ng-Xuan. Preparation of CdS/Graphene Composites and Photocatalytic Hydrogen Generation from Water under Visible Light Irradiation[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2178-2184. doi: 10.3866/PKU.WHXB20110904 shu

Preparation of CdS/Graphene Composites and Photocatalytic Hydrogen Generation from Water under Visible Light Irradiation

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

Received Date: 22 April 2011
Available Online: 4 July 2011
Fund Project: 国家重点基础研究发展规划项目(973) (2007CB613305, 2009CB22003) (973) (2007CB613305, 2009CB22003) 国家高技术研究发展计划项目(863) (2009AA05Z117) (863) (2009AA05Z117)中国科学院太阳能行动计划(KGCX2-YW-390-1, KGCX2-YW-390-3)资助 (KGCX2-YW-390-1, KGCX2-YW-390-3)

CdS/graphene composite photocatalysts were prepared by photocatalytically reducing graphene oxide with CdS nanoparticles in an aqueous ethanol solution. The structure and photoelectrical properties of the resulted materials were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and transient photocurrent measurements. The photocatalytic activities of the CdS/graphene composites for hydrogen evolution were evaluated under visible light irradiation (λ≥420 nm). The results show that the graphene oxide can be efficiently reduced by the photogenerated electrons of CdS and thus CdS/graphene composite is formed and it shows strong interactions between CdS and graphene. Compared with CdS, the enhanced photocurrent generation and photocatalytic activity toward hydrogen evolution for the CdS/ graphene composite photocatalysts could be attributed to the ability of graphene to capture and transport electrons, and to promote charge separation.
- CdS,
- Graphene,
- Photoelectrical property,
- Hydrogen generation,
- Visible light
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