Citation: TANG Rui-Zhi, ZHANG Peng, LI Hai-Xia, LIU Yan-Cheng, WANG Wen-Feng. Pulse Radiolysis Study of the Reactions between Phenothiazine and CCl₃OO^·, ^·OH[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1975-1978. doi: 10.3866/PKU.WHXB20110825 shu

Pulse Radiolysis Study of the Reactions between Phenothiazine and CCl₃OO^·, ^·OH

TANG Rui-Zhi ^1,2 ,
ZHANG Peng ^1,2 ,
LI Hai-Xia ^1,2 ,
LIU Yan-Cheng ^1,2 ,
WANG Wen-Feng ^1,

1.
1. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049

Received Date: 26 April 2011
Available Online: 22 June 2011
Fund Project: 国家自然科学基金(10675158)资助项目 (10675158)

The kinetics and mechanisms of the reactions between phenothiazine and CCl₃OO^·, ^·OH were evaluated and the related rate constants were determined using nanosecond pulse radiolysis technique. The experimental results indicate that the maximum absorption of the transient product from the reaction between phenothiazine and CCl₃OO^·, ^·OH was located at 380 nm, which is attributed to CCl₃OO^· and ^·OH abstracting hydrogen from phenothiazine to generate a phenothiazine radical. The rate constants of the reactions between phenothiazine and CCl₃OO^·, ^·OH were determined to be 1.1×10⁹, 4.0×10⁹ L·mol^-1·s^-1, respectively. These results provide a theoretical foundation for the further study of the antioxidant activity of phenothiazine.
- Antioxidant,
- Phenothiazine,
- Trichloromethylperoxyl radical,
- Hydroxide radical,
- Pulse radiolysis
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Pulse Radiolysis Study of the Reactions between Phenothiazine and CCl3OO·, ·OH

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Pulse Radiolysis Study of the Reactions between Phenothiazine and CCl₃OO^·, ^·OH