Citation: LIU Yun-Long, WANG Wen-Jun, GAO Xue-Xi, XU Jian-Hua. Second Harmonic Generation Properties of Centrosymmetric Bisphthalocyaninato Thulium in Langmuir-Blodgett Films[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1985-1989. doi: 10.3866/PKU.WHXB20110818 shu

Second Harmonic Generation Properties of Centrosymmetric Bisphthalocyaninato Thulium in Langmuir-Blodgett Films

1.
1. School of Physical Science & Information Technology, Liaocheng University, Liaocheng 252059, Shandong Province, P. R. China;
2. State Key Laboratory of Precision Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062, P. R. China

Received Date: 6 April 2011
Available Online: 20 June 2011
Fund Project: 国家自然科学基金(10874063) (10874063) 山东省科技攻关项目(2010GGX10127) (2010GGX10127)山东省高等学校科技计划项目(J10LA60)资助 (J10LA60)

The second order nonlinear optical properties of sandwich thulium bisphthalocyanine (TmPc₂) molecule Langmuir-Blodgett (LB) films were investigated using the second harmonic generation (SHG)method. The dependence of the second harmonic intensity on the incident angle of the fundamental beam was measured and the mechanisms of nonlinearity were discussed briefly. The experimental results indicated that the second harmonic signal intensity was very strong and its maximum was obtained at an incident angle of 45°. The second order nonlinear optical susceptibility χ⁽²⁾ was about 1.152×10^-8 esu and the hyperpolarizability β was about 1.905×10^-30 esu. By measuring the polarization properties of the second harmonic signal for the LB film and comparing this with the theoretical analysis, we found that the origin of the second harmonic generation was attributed to the electric quadrupole mechanism for the TmPc₂ molecule.
- Terbium bisphthalocyanine,
- Langmuir-Blodgett film,
- Nonlinear optics,
- Second harmonic generation,
- Electric quadrupole mechanism
1. [1]
  
  (1) Ho, Z. Z.; Ju, C. Y.; Hetherington,W. M., III. J. Appl. Phys. 1987, 62, 716.
2. [2]
  (2) Liu, Y. Q.; Xu, Y.; Zhu, D. B.;Wada, T.; Sasabe, H.; Zhao, X. S.; Xie, X. M. J. Phys. Chem. 1995, 99, 6957.
3. [3]
  (3) Dennis, K. P. Ng; Jiang, J. Z. Chem. Soc. Rev. 1997, 26, 433.
4. [4]
  (4) He, Y.; Xiong, Y. J.; Zhu, Q. H.; Kong, F. A. Acta Phys. -Chim. Sin. 1999, 15, 636. [何勇, 熊轶嘉, 朱起鹤, 孔繁敖. 物理化学学报, 1999, 15, 636.]
5. [5]
  (5) Diaz-Garcia, M. A.; Ledoux, I.; Duro, J. A.; Torres, T.; Agullo-Lopez, F.; Zyss, J. J. Phys. Chem. 1994, 98, 8761.
6. [6]
  (6) Wang, Y. F.; Zhang, X. R.; Ye, Y. C.; Liang, D. J.;Wang, Y.;Wu, K. Acta Phys.-Chim. Sin. 2010, 26, 933. [王永峰, 张鑫然, 叶迎春, 梁德建, 王远, 吴凯. 物理化学学报, 2010, 26, 933.]
7. [7]
  (7) Souto, J.; De Saja, J. A.; Aroca, R.; Rodriguez, M. L. Synth. Met. 1993, 54, 229.
8. [8]
  (8) Shirk, J. S.; Lindle, J. R.; Bartoli, F. J.; Hoffman, C. A.; Kafafi, Z. H.; Snow, A.W. Appl. Phys. Lett. 1989, 55, 1287.
9. [9]
  (9) Kanbara, H.; Maruno, T.; Yamashita, A.; Matsumoto, S.; Hayashi, T.; Konami, H.; Tanaka, N. J. Appl. Phys. 1996, 80, 3674.
10. [10]
  (10) Feng, J. K.; Li, J.; Sun, J. Z. Acta Chim. Sin. 1994, 52, 539. [封继康, 李君, 孙家钟. 化学学报, 1994, 52, 539.]
11. [11]
  (11) Sastre, A.; Díaz-García, M. A.; Del-Rey, B.; Dhenaut, C.; Zyss, J.; Ledoux, I.; Agulló-López, F.; Torres, T. J. Phys. Chem. A 1997, 101, 9773.
12. [12]
  (12) Kumagai, K.; Mizutani, G.; Tsukioka, H.; Yamauchi, T.; Ushioda, S. Phys. Rev. B 1993, 48, 14488.
13. [13]
  (13) Hoshi, H.; Yamada, T.; Ishikawa, K.; Takezoe, H.; Fukuda, A. Phys. Rev. B 1995, 52, 12355.
14. [14]
  (14) Yamada, T.; Hoshi, H.; Manaka, T.; Ishikawa, K.; Takezoe, H.; Fukuda, A. Phys. Rev. B 1996, 53, 13314.
15. [15]
  (15) Liu, Y. L.;Wang,W. J.; Gao, X. X.; Li, S. H. Spectroscopy and Spectral Analysis 2008, 28, 422. [刘云龙, 王文军, 高学喜, 李淑红. 光谱学与光谱分析, 2008, 28, 422.]
16. [16]
  (16) Ashwell, G. J.; Hargreaves, R. C.; Baldwin, C. E.; Bahra, G. S.; Brown, C. R. Nature 1992, 357, 393.
17. [17]
  (17) Jerphagnon, J.; Kurtz, S. K. Phys. Rev. B 1970, 1, 1739.
18. [18]
  (18) Liu, Y. Q.; Shigehara, K.; Hara, M.; Yamada, A. J. Am. Chem. Soc. 1991, 113, 440.
19. [19]
  (19) Lupo, D.; Prass,W.; Scheunemann, U.; Laschewsky, A.; Ringsdorf, R.; Ledoux, I. J. Opt. Soc. Am. B 1988, 5, 300.
20. [20]
  (20) Jiang, J. Z.; Liu,W.; Lin, J. M.;Wu, J. P. Chemistry 1997, 7, 14. [姜建壮, 刘伟, 林吉茂, 吴基培. 化学通报, 1997, 7, 14.]
21. [21]
  (21) Liu, Y. L.;Wang,W. J.; Gao, X. X.; Li, S. H.; Li, Y. Spectroscopy and Spectral Analysis 2008, 28, 2375. [刘云龙, 王文军, 高学喜, 李淑红, 李云. 光谱学与光谱分析, 2008, 28, 2375.]
22. [22]
  (22) Pershan, P. S. Phys. Rev. 1963, 130, 919.
23. [23]
  (23) Bloembergen, N.; Chang, R. K.; Jha, S. S.; Lee, C. H. Phys. Rev. 1968, 174, 813.
24. [24]
  (24) Yamada, T.; Hoshi, H.; Ishikawa, K.; Takezoe, H.; Fukuda, A. Jpn. J. Appl. Phys. 1995, 34, L299.
25. [25]
  (25) Adler, E. Phys. Rev. 1964, 134, A728.
26. [26]
  (26) Qin, S. J.; You,W. M.; Su, Z. B. Phys. Rev. B 1993, 48, 17562.
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