Citation: WEN Sheng, NG Chun-Li, TSAI Fang-Chang, YEH Jen-Taut. Properties of SPES/AlOOH Composite Proton Exchange Membranes[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1886-1892. doi: 10.3866/PKU.WHXB20110737 shu

Properties of SPES/AlOOH Composite Proton Exchange Membranes

  • Received Date: 1 March 2011
    Available Online: 8 June 2011

    Fund Project: 湖北省自然科学基金(2010CDB00301)资助项目 (2010CDB00301)

  • Novel sulfonated polyether sulfone (SPES)/AlOOH organic/inorganic composite membranes were prepared by doping SPES with AlOOH, which lowered the methanol crossover and increased the proton conductivity at high temperatures. The structure and performance of the obtained membranes were characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) etc. Compared with the pure SPES membrane the composite membranes had higher thermal stability and water uptake. The morphology of the composite membranes indicated that AlOOH was uniformly distributed throughout the SPES matrix. The network-like structure began to form when the AlOOH content was around 10%. The proton conductivity was still ca 0.014 S·cm-1 even at a temperature as high as 120 °C. Additionally, the methanol resistance improved greatly as the content of AlOOH increased. The SPES/AlOOH composite membrane is a promising candidate for direct methanol fuel cell (DMFC) applications.

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