Citation: WEN Sheng, NG Chun-Li, TSAI Fang-Chang, YEH Jen-Taut. Properties of SPES/AlOOH Composite Proton Exchange Membranes[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1886-1892. doi: 10.3866/PKU.WHXB20110737 shu

Properties of SPES/AlOOH Composite Proton Exchange Membranes

1.
1. Faculty of Material Science and Engineering, Hubei University, Wuhan 430062, P. R. China;
2. Faculty of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430073, P. R. China;
3. Faculty of Chemistry and Materials Science, Xiaogan University, Xiaogan 432000, Hubei Province, P. R. China

Received Date: 1 March 2011
Available Online: 8 June 2011
Fund Project: 湖北省自然科学基金(2010CDB00301)资助项目 (2010CDB00301)

Novel sulfonated polyether sulfone (SPES)/AlOOH organic/inorganic composite membranes were prepared by doping SPES with AlOOH, which lowered the methanol crossover and increased the proton conductivity at high temperatures. The structure and performance of the obtained membranes were characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) etc. Compared with the pure SPES membrane the composite membranes had higher thermal stability and water uptake. The morphology of the composite membranes indicated that AlOOH was uniformly distributed throughout the SPES matrix. The network-like structure began to form when the AlOOH content was around 10%. The proton conductivity was still ca 0.014 S·cm^-1 even at a temperature as high as 120 °C. Additionally, the methanol resistance improved greatly as the content of AlOOH increased. The SPES/AlOOH composite membrane is a promising candidate for direct methanol fuel cell (DMFC) applications.
- Sulfonated poly(ether sulfone),
- AlOOH,
- Composite membrane,
- Direct methanol fuel cell
1. [1]
  
  (1) Fu, X. Z.; Li, J.; Lu, C. H.; Liao, D.W. Progress in Chemistry 2004, 16 (1), 77. [符显珠, 李俊, 卢成慧, 廖代伟. 化学进展, 2004, 16 (1), 77.]
2. [2]
  (2) ng, C. L.; Zhou, Y.; Yan, L. C.;Wen, S.; Zheng, G.W. Acta Phys.-Chim. Sin. 2010, 26 (11), 2967. [龚春丽, 周毅, 闫礼成, 文胜, 郑根稳. 物理化学学报, 2010, 26 (11), 2967.]
3. [3]
  (3) Deng, H. N.; Li, L.; Xu, L.;Wang, Y. X. Acta Phys. -Chim. Sin. 2007, 23 (8): 1235. [邓会宁, 李磊, 许莉, 王宇新. 物理化学学报, 2007, 23 (8), 1235.]
4. [4]
  (4) Rhee, C. H.; Kim, H. K.; Chang, H.; Lee, J. S. Chem. Mater. 2005, 17, 1691.
5. [5]
  (5) Yang, S. F.; ng, C. L.; Guan, R.; Zou, H.; Dai, H. Polym. Adv. Technol. 2006, 17, 360.
6. [6]
  (6) Yi, B. L. Fuel Cells-Principle Technology Application: Chemical Industry Press: Beijing, 2003; p 351. [衣宝廉. 燃料电池-原理·技术·应用. 北京: 化学工业出版社, 2003: 351.]
7. [7]
  (7) Nolte, R.; Ledjeff, K.; Bauer, M.;Mülhaupt, R. J. Membr. Sci. 1993, 83, 211.
8. [8]
  (8) Guan, R.; Dai, H.; Li, C.; Liu, J.; Xu, J. J. Membr. Sci. 2006, 277, 148.
9. [9]
  (9) Kopitzke, R.W.; Linkous, C. A.; Anderson, H. R.; Nelson, G. L. J. Electrochem. Soc. 2000, 147, 1677.
10. [10]
  (10) Dai, H.; Guan, R.; Li, C.; Liu, J. Solid State Ionics 2007, 178, 339.
11. [11]
  (11) Tsai, J. C.; Kuo, J. F.; Chen, C.Y. J. Power Sources 2007, 174, 103.
12. [12]
  (12) Su, Y. H.; Liu, Y. L.; Sun, Y. M.; Lai, J. Y.;Wang, D. M.; Gao, Y.; Liu, B.; Guiver, M. D. J. Membr. Sci. 2007, 296, 21.
13. [13]
  (13) Nunes, S. P.; Ruffmann, B.; Rikowski, E.; Vetter, S.; Richau, K. J. Membr. Sci. 2002, 203, 215.
14. [14]
  (14) Jin, H.; Xie, X. F.; Shang, Y. M.; Feng, S. G.; Lv, Y. F. Chemical Industry and Engineering Progress 2007, 26 (4), 507. [靳豪, 谢晓峰, 尚玉明, 冯少广, 吕亚非. 化工进展, 2007, 26 (4), 507.]
15. [15]
  (15) Shen, J.; Xi, J. Y.; Zhu,W. T.; Chen, L. Q.; Qiu, X. P. J. Power Sources 2006, 159, 894.
16. [16]
  (16) Yan, J. S.; Long, J.; Tian, H. P. Petroleum Processing and Petrochemicals 2004, 35 (9), 38. [严加松, 龙军, 田辉平. 石油炼制与化工, 2004, 35 (9), 38.]
17. [17]
  (17) Ye, T. X.; Liu, J.Y.; Zhang, B.; Ma, X. N. Chinese Journal of Applied Chemistry 2009, 26 (9), 1114. [叶天旭, 刘京燕, 张斌, 马雪妮. 应用化学, 2009, 26 (9), 1114.]
18. [18]
  (18) Lv, J. G.; Zhang, J.; Ding,W. P.; Shen, B.; Guo, X. F. Chinese Journal of Inorganic Chemistry 2007, 23 (5), 897. [吕建刚, 张娟, 丁维平, 沈彬, 郭学峰. 无机化学学报, 2007, 23 (5), 897.]
19. [19]
  (19) Liu, C. H.; Liao, H. D.; Long, X. Y. Journal of Southwest China Normal University 2003, 28 (2), 263. [刘昌华, 廖海达, 龙翔云. 西南师范大学学报(自然科学版, 2003, 28 (2), 263.]
20. [20]
  (20) Zheng, G.W.; ng, C. L.;Wen, S.; Zhou, H. B.; Xie, X. L. Acta Phys.-Chim. Sin., 2009, 25 (3), 575. [郑根稳, 龚春丽, 文胜, 周环波, 解孝林. 物理化学学报, 2009, 25 (3), 575.]
21. [21]
  (21) Shu, Y. C.; Chuang, F. S.; Tsen,W. C.; ng, C. L.;Wen, S. J. Appl. Polym. Sci. 2008, 108, 1783.
1. [1]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
2. [2]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
3. [3]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
4. [4]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
5. [5]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
6. [6]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
7. [7]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
8. [8]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
9. [9]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
10. [10]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
11. [11]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
12. [12]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
13. [13]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
14. [14]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
15. [15]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . 基于稳态电热法的石墨烯膜导热系数的精确可靠测量. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-. doi: 10.1016/j.actphy.2025.100045
16. [16]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
17. [17]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
18. [18]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
19. [19]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . Efficient capacitive desalination over NCQDs decorated FeOOH composite. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-. doi: 10.1016/j.actphy.2025.100072
20. [20]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation

PDF

XML

Metrics

PDF Downloads(1173)
Abstract views(3017)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142