Citation: JIA Li-Hui, LIU An-Chang, MU Zong-E, CHEN Yun-Feng. Magnetostructural Correlation Study of a Novel Strong Antiferromagnetic Dimer Copper(II) Coordination Complex with Mono-Methyl Phthalate[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1595-1599. doi: 10.3866/PKU.WHXB20110736 shu

Magnetostructural Correlation Study of a Novel Strong Antiferromagnetic Dimer Copper(II) Coordination Complex with Mono-Methyl Phthalate

1.
1. Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Chemical and Technology, Wuhan 430074, P. R. China;
2. School of Physics, Huazhong University of Science and Technology, Wuhan 430074, P. R. China

Received Date: 29 March 2011
Available Online: 3 June 2011
Fund Project: 国家自然科学基金(21002076)资助项目 (21002076)

We prepared and obtained a novel dinuclear copper(II) coordination complex [Cu₂(mMP)₂(H₂O)₂]₂·2H₂O (1) using mono-methyl phthalate as a ligand (mMP is a mono-methyl phthalate or 1,2- benzenedicarboxylate monomethyl ester). The crystal structure of complex 1 was characterized by elemental analysis, IR spectroscopy, and X-ray analysis. This tetra-carboxylato-bridged dinuclear complex adopts a dimeric paddle-wheel cage structure and the coordination configuration around each copper(II) cation is square-pyramidal with four oxygen atoms of the carboxylate groups from four different mono- methyl phthalate ligands and one oxygen atom of water at the apical position. Intermolecular hydrogen bonds are found between the hydrogen atoms of the coordinated or uncoordinated water and the oxygen atoms of the carboxyl from the adjacent molecules and it forms a three-dimensional (3D) network structure. The magnetic data for complex 1 indicate a strong intramolecular antiferromagnetic interaction between the two paramagnetic metal ions with a magnetic coupling constant of 2J=-324 cm^-1. In this paper, we analyzed the magnetostructural correlation of complex 1 in detail and discuss the main factor that determines the strong antiferromagnetic interaction in dimeric copper(II) carboxylates. Compared with the structure and the magnetic property of other related complexes, the main factor that determines the strong antiferromagnetic interaction in the dimeric copper(II) carboxylate is an electronic structure of the bridging O－C－O moiety.
- Magnetostructural correlation,
- Strong antiferromagnetic interaction,
- tetra-carboxylato-bridged dinuclear copper(II),
- Mono-methyl phthalate,
- Electronic structure
1. [1]
  
  (1) Kahn, O. Molecular Magnetism;Weinheim: VCH, 1993.
2. [2]
  (2) Gatteschi, D.; Kahn, O.; Miller, J. S. Magnetic Molecualr Materials, NATO ASI Series E198; Dordrecht: Kluwer, 1991.
3. [3]
  (3) Mroziński, J. Coord. Chem. Rev. 2005, 249, 2534.
4. [4]
  (4) Steel, P. J. Coord. Chem. Rev. 1990, 106, 227.
5. [5]
  (5) Kahn, O. Angew. Chem. Int. Edit. 1985, 24, 834.
6. [6]
  (6) Carlin, R. L. Magnetochemistry; Springer-Verlag: Berlin, 1986; pp 34-126.
7. [7]
  (7) Mortensen, G. K.; Main, K. M.; Andersson, A. M.; Leffers, H.; Skakkeb?k, N. E. Anal. Bioanal. Chem. 2005, 382, 1084.
8. [8]
  (8) Main, K. M.; Mortensen, G. K.; Kaleva, M. M.; Boisen, K. A.; Damgaard, I. N.; Chellakooty, M.; Schmidt, I. M.; Suomi, A. M.; Virtanen, H. E.; Petersen, J. H.; Andersson, A. M.; Toppari, S.; Niels, E. Environmental Health Perspectives 2006, 114 (2), 270.
9. [9]
  (9) Alfonso, L.; Zimnik, S.; Heinz, N. Toxicology and Applied Pharmacology 2003, 188 (1), 14.
10. [10]
  (10) Sussanne, J.; Anders, B. Environmental Toxicology and Chemistry 2003, 22 (12), 3037.
11. [11]
  (11) Jia, L. H.; Liu, Z. L.; Liu,W.; Gu, Y. F.; Yao, K. L. Chin. J. Inorg. Chem. 2008, 24 (2), 289. [贾丽慧, 刘祖黎, 刘蔚, 谷云飞, 姚凯伦. 无机化学学报, 2008, 24 (2), 289.]
12. [12]
  (12) Mulay, L. N.; Boudreaux, E. A. Theroy and Applications of Molecular Diamagnetism;Wiley: New York, 1976.
13. [13]
  (13) Sheldrick, G. M. SHELXL-97; Program zur Verfeinerung von Kristallstrukturen: Göttingen, 1997.
14. [14]
  (14) Sheldrick, G. M. SHELXS-97; Program zur Lösung von Kristallstrukturen: Göttingen, 1997.
15. [15]
  (15) Melnik, M.; Kabešová, M.; Koman, M.; Macášková, L?.; Garaj, J.; Holloway, C. E.; Valent, A. J. Coord. Chem. 1988, 45, 147.
16. [16]
  (16) Kato, M.; Muto, Y. Coord. Chem. Rev. 1988, 92, 45
17. [17]
  (17) Doedens, R. J. Prog. Inorg. Chem. 1976, 21, 209.
18. [18]
  (18) Erre, L. S.; Micera, G.; Piu, P.; Cariati, F.; Ciani, G. Inorg. Chem. 1985, 24, 2297.
19. [19]
  (19) Brown, G. M.; Chidambaram, R. Acta Cryst. B 1973, 29, 2393.
20. [20]
  (20) Meester, P.; Fletcher, S. R.; Skapski, A. C. J. Chem. Soc. Dalton Trans. 1973, 2575.
21. [21]
  (21) Harrison,W.; Rettig, S.; Trotter, J. J. Chem. Soc. Dolton Trans. 1972, 1852.
22. [22]
  (22) Koh, Y. B.; Christoph, G. G. Inorg. Chem. 1979, 18, 1122.
23. [23]
  (23) Brian, R. F.; White, D. H. Acta Cryst. B 1982, 38, 1014.
24. [24]
  (24) Bleaney, B.; Bowers, K. D. Proc. R. Soc. A 1952, 214, 451.
25. [25]
  (25) Agterberg, P. F.; Kluit, J. H.; Driessen,W. L.; Reedijk, J. Inorg. Chim. Acta 1998, 267, 183.
26. [26]
  (26) Kawata, T.; Uekusa, H.; Ohba, S.; Furukawa, T.; Tokii, T.; Muto, Y.; Kato, M. Acta Cryst. B 1992, 48, 253.
27. [27]
  (27) Kahn, O. Magnetostructural Correlations in Exchange Coupled Systems; Dordrecht: Reidel, 1985; pp 35-56.
28. [28]
  (28) (a) odenough, J. B. Phys. Rev. 1955, 100, 564; J. Phys. Chem. Solids 1958, 6, 287.(b) odenough, J. B. Magnetism and the Chemical Bond; Interscience: New York, 1963.(c) Kanamori, J. J. Phys. Chem. Solids 1959, 10, 87.
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