Citation: ZHANG Min, LI Jing-Jian, PAN Mu, XU Dong-Sheng. Catalytic Performance of Pt Nanowire Arrays for Oxygen Reduction[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1685-1688. doi: 10.3866/PKU.WHXB20110726 shu

Catalytic Performance of Pt Nanowire Arrays for Oxygen Reduction

ZHANG Min ^1,2 ,
LI Jing-Jian ² ,
PAN Mu ^1, ,
XU Dong-Sheng ^2,

1.
1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China;
2. Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 15 April 2011
Available Online: 30 May 2011
Fund Project: 武汉理工大学材料复合新技术国家重点实验室自主创新研究基金, 国家自然科学基金(21073007, 50821061) (21073007, 50821061)国家重点基础研究发展计划项目(973) (2007CB936201)资助 (973) (2007CB936201)

Platinum nanowire arrays (Pt NWs) catalyst was fabricated by electrodepositing with anodic aluminum oxide (AAO) as a template. The morphology and oxygen reduction reaction (ORR) electrocatalytic properties of the as-prepared platinum nanowire array catalysts were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical measurements. The cyclic voltammetry (CV) showed that the specific electrochemical surface area (ECSA) of the Pt NWs was much higher than the geometric area. The half wave potential in the oxygen reduction reaction curves of the Pt NWs was more positive than that of Pt/C from the rotating disk electrode (RDE) measurements. Moreover, Pt NWs catalysts give higher limiting diffusion current by comparison with that of conventional Pt/C catalyst.
- AAO template,
- Platinum nanowire array,
- Oxygen reduction reaction,
- Proton exchange membrane fuel cell
1. [1]
  
  (1) Appleby, A. J. J. Power Sources 1996, 58, 153.
2. [2]
  (2) Ralph, T. R. Platinum Metal Rev. 1999, 43, 14.
3. [3]
  (3) Ralph, T. R. Platinum Metal Rev. 1997, 41, 102.
4. [4]
  (4) Mallouk, T. E. Nature 1990, 343, 515.
5. [5]
  (5) Steele, B. C. H.; Heinzel, A. Nature 2001, 414, 345.
6. [6]
  (6) Perry, M. L.; Fuller, T. F. J. Electrochem. Soc. 2002, 149, S59.
7. [7]
  (7) Lim, B. K.; Jiong, M. J.; Camar , P. H. C.; Cho, E. C.; Tao, J.; Lu, X. M.; Zhu, Y. M.; Xia, Y. N. Science 2009, 324, 1302.
8. [8]
  (8) Shih, Y. H.; Sagar, G. V.; Lin, S. D. J. Phys. Chem. C 2008, 112, 123.
9. [9]
  (9) Gancs, L.; Kobayashi, T.; Debe, M. K.; Atanasoski, R.; Wieckowski, A. Chem. Mater. 2008, 20, 2444.
10. [10]
  (10) Bonakdarpour, A.; Stevens, K.; Vernstrom, G. D.; Atanasoski, R.; Schmoeckel, A. K.; Debe, M. K.; Dahn, J. R. Electrochimica Acta 2007, 53, 688.
11. [11]
  (11) Debe, M. K.; Schmoeckel, A. K.; Vernstrom, G. D.; Atanasoski, R. J. Power Sources 2006, 161, 1002.
12. [12]
  (12) Zhang, X. Y.; Lu,W.; Da, J. Y.;Wang, H. T.; Zhao, D. Y.; Webley, P. A. Chem. Commun. 2009, 195.
13. [13]
  (13) Chen, Z.W.;Waje, M.; Li,W. Z.; Yan, Y. S. Angew. Chem. Int. Edit. 2007, 46, 4060.
14. [14]
  (14) Masuda, H.; Asoh, H.;Watanabe, M. Adv. Mater. 2001, 13, 189.
15. [15]
  (15) Pozio, A.; Francesco, M. D.; Cemmi, A.; Cardellini, F.; Giorgi, L. J. Power Sources 2002, 13, 105.
16. [16]
  (16) Yu, J.; Matsuura, T.; Yoshikawa, Y.; Islam, M. N.; Hori, M. Electrochem. Solid-State Lett. 2005, 8, A156.
17. [17]
  (17) Mayrhofer, K. J. J.; Blizanac, B. B.; Arenz, M.; Stamenkovic, V. R.; Ross, P. N.; Markovic, N. M. J. Phys. Chem. B 2005, 109, 14433.
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
3. [3]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
4. [4]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
7. [7]
  Pengzi Wang , Wenjing Xiao , Jiarong Chen . Copper-Catalyzed C―O Bond Formation by Kharasch-Sosnovsky-Type Reaction. University Chemistry, 2025, 40(4): 239-244. doi: 10.12461/PKU.DXHX202406090
8. [8]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
9. [9]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
10. [10]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
11. [11]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
12. [12]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
13. [13]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
14. [14]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
15. [15]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
16. [16]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
17. [17]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
18. [18]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
19. [19]
  Yu Dai , Xueting Sun , Haoyu Wu , Naizhu Li , Guoe Cheng , Xiaojin Zhang , Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, 2025, 40(5): 351-356. doi: 10.12461/PKU.DXHX202407052
20. [20]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094

Get Citation

PDF

XML

Metrics

PDF Downloads(1164)
Abstract views(2839)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142