Citation: ZHAO Xing, ZHUANG Quan-Chao, QIU Xiang-Yun, XU Shou-Dong, SHI Yue-Li, CUI Yong-Li. Electrochemical Performance of Cr₂O₃/TiO₂ Composite Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1666-1672. doi: 10.3866/PKU.WHXB20110715 shu

Electrochemical Performance of Cr₂O₃/TiO₂ Composite Material for Lithium Ion Batteries

1.
Li-ion Batteries Laboratory, School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China

Received Date: 24 February 2011
Available Online: 23 May 2011
Fund Project: 中央高校基本科研业务费专项资金(2010LKHX03、2010QNB04、2010QNB05) (2010LKHX03、2010QNB04、2010QNB05)中国矿业大学科技攀登计划(ON090237)资助项目 (ON090237)

The Cr₂O₃/TiO₂ composite material was prepared by a high-temperature solid-state reaction and its structure, morphology, and electrochemical performance were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), charge-discharge test, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). We found that TiO₂ doping significantly improved the cyclic performance of Cr₂O₃ and the reversible capacity of the Cr₂O₃/TiO₂ composite material was 454 mAh·g^-1 after 22 charge-discharge cycles, therefore, it has a capacity retention of 73.6% and this is mainly due to TiO₂ doping that significantly increases the conductivity of Cr₂O₃. Our results revealed that the initial large irreversible capacity and the capacity fading could be attributed to an increase in the thickness of the solid electrolyte interface (SEI) film and a reduction in the conductivity of the materials. This was caused by a volume expansion of the Cr₂O₃/TiO₂ electrode during the first discharge process.
- Lithium ion battery,
- Cr₂O₃/TiO₂ composite material,
- Conversion reaction,
- Conductivity,
- Solid electrolyte interface film
1. [1]
  
  (1) Yu, F.; Zhang, J. J.;Wang, C. Y.; Yuan, J.; Yang, Y. F.; Song, G. Z. Progress in Chemistry 2010, 22 (1), 9. [于锋, 张敬杰, 王昌胤, 袁静, 杨岩峰, 宋广智. 化学进展, 2010, 22 (1), 9.]
2. [2]
  (2) Zhou, H. H.; Ci, Y. X.; Liu, C. Y. Progress in Chemistry 1998, 10(1), 85. [周恒辉, 慈云祥, 刘昌炎. 化学进展, 1998, 10 (1), 85.]
3. [3]
  (3) Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nature 2000, 407, 496.
4. [4]
  (4) Pereira, N.; Dupont, L.; Tarascon, J. M.; Klein, L. C.; Amatucci, G. G. J. Electrochem. Soc. 2003, 150 (9), A1273.
5. [5]
  (5) Pereira, N.; Klein, L. C.; Amatucci, G. G. J. Electrochem. Soc. 2002, 149 (3), A262.
6. [6]
  (6) Débart, A.; Dupont, L.; Patrice, R.; Tarascon, J. M. Solid State Sci. 2006, 8, 640.
7. [7]
  (7) Souza, D. C. S.; Pralong, V.; Jacobson, A. J.; Nazar, L. F. Science 2002, 296 (5575), 2012.
8. [8]
  (8) Mauvernay, B.; Doublet, M. L.; Monconduit, L. J. Phys. Chem. Solids 2006, 67, 1252.
9. [9]
  (9) Silva, D. C. C.; Crosnier, O.; Ouvrard, G.; Greedan, J.; Safa- Sefat, A.; Nazar, L. F. Electrochem. Solid-State Lett. 2003, 6 (8), A162.
10. [10]
  (10) Xue, M. Z.; Fu, Z.W. Electrochem. Commun. 2006, 8 (12), 1855.
11. [11]
  (11) Badway, F.; Cosandey, F.; Pereira, N.; Amatucci, G. G. J. Electrochem. Soc. 2003, 150 (10), A1318.
12. [12]
  (12) Li, H.; Balaya, P.; Maier, J. J. Electrochem. Soc. 2004, 151, A1878.
13. [13]
  (13) Hu, J.; Li, H.; Huang, X. J.; Chen, L. Q. Solid State Ionics 2006, 177, 2791.
14. [14]
  (14) Jamnik, J.; Maier, J. Phys. Chem. Chem. Phys. 2003, 5, 5215.
15. [15]
  (15) Hu, J.; Li, H.; Huang, X. J. Electrochem. Solid State Lett. 2005, 8 (1), A66.
16. [16]
  (16) Chou, S. L.;Wang, J. Z.; Zhong, C.; Rahman, M. M.; Liu, H. K.; Dou, S. X. Electrochimica Acta 2009, 54, 7519.
17. [17]
  (17) Hassan, M. F.; Rahman, M. M.; Guo, Z. P.; Chen, Z. X.; Liu, H. K. Electrochimica Acta 2010, 55, 5006.
18. [18]
  (18) Wagemaker, M.; Kearley, G. J. J. Am. Chem. Soc. 2003, 125, 840.
19. [19]
  (19) He, B. L.; Dong, B.; Li, H. L. Electrochem. Commun. 2007, 9, 425.
20. [20]
  (20) An, L. P.; Gao, X. P.; Li, G. R.; Yan, T. Y.; Zhu, H. Y.; Shen, P. W. Electrochimica Acta 2008, 53, 4573.
21. [21]
  (21) Xu, J.;Wang, Y.; Li, Z. J. Power Sources 2008, 175, 903.
22. [22]
  (22) Balaya, P.; Li, H.; Kienle, L.; Maier, J. Adv. Funct. Mater. 2003, 13, 621.
23. [23]
  (23) Laruelle, S.; Grugeon, S.; Poizot, P.; Dollé, M.; Dupont, L.; Tarascon, J. M. J. Electrochem. Soc. 2002, 149 (5), A627.
24. [24]
  (24) Zhukovskii, Y. F.; Kotomin, E. A.; Balaya, P.; Maier, J. Solid State Sci. 2008, 10, 491.
25. [25]
  (25) Zhuang, Q. C.;Wei, T.; Du, L. L. J. Phys. Chem. C 2010, 114, 8614.
26. [26]
  (26) Mitra, S.; Poizot, P.; Finke, A.; Tarascon, J. M. Adv. Funct. Mater. 2006, 16 (17), 2281.
27. [27]
  (27) Li, H.;Wang, Z. X.; Chen, L. Q.; Huang, X. J. Adv. Mater. 2009, 21 (45), 4593.
28. [28]
  (28) Zhuang, Q. C.; Xu, S. D.; Qiu, X. Y. Progress in Chemistry 2010, 22 (6), 1044. [庄全超, 徐守冬, 邱祥云. 化学进展, 2010, 22 (6), 1044.]
29. [29]
  (29) Zhuang, Q. C.; Chen, Z. F.; Dong, Q. F.; Jiang, Y. X.; Huang, L.; Sun, S. G. Chinese Science Bulletin 2006, 51 (9), 1055.
1. [1]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
2. [2]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
5. [5]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
6. [6]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
7. [7]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
8. [8]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
9. [9]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-0. doi: 10.3866/PKU.WHXB202309028
10. [10]
  Ying Li , Yushen Zhao , Kai Chen , Xu Liu , Tingfeng Yi , Li-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007
11. [11]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
12. [12]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
13. [13]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
14. [14]
  Zhi Dou , Huiyu Duan , Yixi Lin , Yinghui Xia , Mingbo Zheng , Zhenming Xu . High-Throughput Screening Lithium Alloy Phases and Investigation of Ion Transport for Solid Electrolyte Interphase Layer. Acta Physico-Chimica Sinica, 2024, 40(3): 2305039-0. doi: 10.3866/PKU.WHXB202305039
15. [15]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
16. [16]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . Nucleation Regulation and Mechanism of Precursors for Nickel Cobalt Manganese-based Cathode Materials in Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100009-0. doi: 10.3866/PKU.WHXB202404042
17. [17]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
18. [18]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-0. doi: 10.1016/j.actphy.2025.100101
19. [19]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
20. [20]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022

Get Citation

PDF

XML

Metrics

PDF Downloads(1471)
Abstract views(3033)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Performance of Cr2O3/TiO2 Composite Material for Lithium Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Electrochemical Performance of Cr₂O₃/TiO₂ Composite Material for Lithium Ion Batteries