Citation: JIN Jing, NG Yuan-Yuan, WU Han-Qing, LI Lei, NIU Shu-Yun. Crystal Structure and Surface Photoelectric Property of Mn(II) Coordination Complexes[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1587-1594. doi: 10.3866/PKU.WHXB20110705 shu

Crystal Structure and Surface Photoelectric Property of Mn(II) Coordination Complexes

1.
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China

Received Date: 3 March 2011
Available Online: 16 May 2011
Fund Project: 国家自然科学基金(20571037) (20571037)辽宁省创新团队项目(2007T092)资助 (2007T092)

Three Mn(II) complexes [Mn(SO₄)(H₂O)₃]_n (1), [Mn2.5(HPO₄)(PO₄)(H₂O)₂]_n (2), [Mn(phen)₂(H₂O)₂]?(C₄H₄O₄)?4H₂O (3) (phen=1,10-phenanthroline) were synthesized by a hydrothermal method and characterized by infrared spectrum (IR), ultraviolet-visible spectrum (UV-Vis), electron paramagnetic resonance spectrum (EPR), single crystal X-ray diffraction and surface photovoltage spectrum (SPS). The structural analyses indicate that complex 1 is a 2D coordination polymer and hydrogen bonds link the polymer to a 3D infinite structure. Complex 2 is a 3D coordination polymer. Complex 3 is a mononuclear complex and diverse hydrogen bonds connect the complex to the 3D supramolecule. SPS results indicate that the three complexes exhibit obvious surface photovoltage responses between 300-800 nm, which reveals that they possess a definite photoelectric conversion property. The structure of the complex, its dimensions and the coordination environment of the central metal affect obviously SPS: the intensity of the surface photovoltage (SPV) response bands become larger with increasing of dimensions and regularity of structure; differences in the species of direct coordination atoms and the strength of the crystal field around the central metal ions lead to the change of number and position of the response bands. Additionally, the association between SPS and UV-Vis were discussed.
- Mn(II) complex,
- Synthesis,
- Crystal structure,
- Hydrogen bond,
- Photoelectric property
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沈阳化工大学材料科学与工程学院沈阳 110142