Citation: CONG Ye, QIN Yun, LI Xuan-Ke, DONG Zhi-Jun, YUAN Guan-Ming, CUI Zheng-Wei. Preparation and Visible Light Photocatalytic Activity of Titanium Dioxide Coated Multiwalled Carbon Nanotubes[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1509-1515. doi: 10.3866/PKU.WHXB20110624 shu

Preparation and Visible Light Photocatalytic Activity of Titanium Dioxide Coated Multiwalled Carbon Nanotubes

1.
Hubei Key Laboratory of Coal Conversion and New Carbon Materials, College of Chemical Engineering and Technology, Wuhan University of Science and Technology, Wuhan 430081, P. R. China

Received Date: 14 January 2011
Available Online: 5 May 2011
Fund Project: 国家自然科学基金(20803054, 50972110)资助项目 (20803054, 50972110)

Titanium dioxide coated multiwalled carbon nanotubes (MWCNTs) composite photocatalysts were prepared by the controllable oxidation of titanium carbide coated MWCNTs obtained by the molten salt method using MWCNTs as a reaction template and metal titanium powder as a titanium source. The effects of the molten salt reaction temperature, the molar ratio of MWCNTs to titanium powder, and the oxidation temperature on the structure and morphology of the products were investigated. The samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The photodegra- dation of a methylene blue (MB) solution was used to evaluate the photocatalytic activity of the catalyst under visible light irradiation (λ>420 nm). The results suggest that the TiO₂ coated MWCNTs keep the similar fibred morphology with the pristine MWCNTs. Uniform and fine well-dispersed TiO₂ coatings on the surface of MWCNTs closely contact with the MWCNTs support and Ti－O－C chemical bonds form between them. The prepared TiO₂/MWCNTs photocatalyst shows higher visible light photocatalytic activity because the MWCNTs increase the adsorption of methylene blue on the photocatalyst and an impurity state is formed close to the valence band of titanium dioxide, which can enhance the absorption and utilization of solar energy.
- Carbon nanotube,
- Titanium dioxide,
- Carbon doping,
- Coating,
- Photocatalysis
1. [1]
  
  (1) Fujishima, A.; Honda, K. Nature 1972, 238, 37.
2. [2]
  (2) Xiao, Y.; Dang, L. Q.; An, L. Z.; Bai, S. Y.; Lei, Z. B. Chin. J. Catal. 2008, 29, 31.
3. [3]
  [肖义, 党利琴, 安丽珍, 白士英, 雷志斌. 催化学报, 2008, 29, 31.]
4. [4]
  (3) Xu, P. C.; Liu, Y.;Wei, J. H.; Xiong, R.; Pan, C. X.; Shi, J. Acta Phys. -Chim. Sin. 2010, 26, 2261.
5. [5]
  [许平昌, 柳阳, 魏建红, 熊锐, 潘春旭, 石兢. 物理化学学报, 2010, 26, 2261.]
6. [6]
  (4) Takata, T.; Domen, K. J. Phys. Chem. C 2009, 113, 19386.
7. [7]
  (5) Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes, C. A. Nano Lett. 2005, 5, 191.
8. [8]
  (6) Morishita, M.; Shiraishi, Y.; Hirai, T. J. Phys. Chem. B 2006, 110, 17898.
9. [9]
  (7) Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes, C. A. Nano Lett. 2006, 6, 215.
10. [10]
  (8) Li, Y. X.;Wang, T. H.; Peng, S.Q.; Lü, G. X.; Li, S. B. Acta Phys. -Chim. Sin. 2004, 20, 1434.
11. [11]
  [李越湘, 王添辉, 彭绍琴, 吕功煊, 李树本. 物理化学学报, 2004, 20, 1434.]
12. [12]
  (9) Yu, H.; Quan, X.; Chen, S.; Zhao, H.; Zhang, Y. J. Photochem. Photobio. A- Chem. 2008, 200, 301.
13. [13]
  (10) Liu, Y.;Wang, S.;Wang, T.; Xu, Z. L.; Chen,W. X.; Jiang, J.; Wei, J. H. Chin. J. Catal. 2010, 31, 485.
14. [14]
  [刘阳, 王晟, 王騊, 许章栋, 陈文兴, 蒋杰, 韦坚红. 催化学报, 2010, 31, 485.]
15. [15]
  (11) Cong, Y.; Zhang, J. L.; Chen, F.; Anpo, M. J. Phys. Chem. C 2007, 111, 6976.
16. [16]
  (12) Zhang, X.; Liu, Q. Appl. Surf. Sci. 2008, 254, 4780.
17. [17]
  (13) Xiao, X. Y.; Yang, Q. S. Journal of South China University of Technology (Natural Science Edition) 2010, 38, 29.
18. [18]
  [肖新颜, 杨青山. 华南理工大学学报(自然科学版), 2010, 38, 29.]
19. [19]
  (14) Li, Y.; Zhang, S.; Yu, Q.; Yin,W. Appl. Surf. Sci. 2007, 253, 9254.
20. [20]
  (15) Wu, Y. C.; Liu, X. L.; Ye, M.; Xie, T.; Huang, X. M. Acta Phys. -Chim. Sin. 2008, 24, 97.
21. [21]
  [吴玉程, 刘晓璐, 叶敏, 解挺, 黄新民. 物理化学学报, 2008, 24, 97.]
22. [22]
  (16) Rincón, M. E.; Trujillo-Camacho, M. E.; Cuentas -Galle s, A. K. Catal. Today 2005, 107-108, 606.
23. [23]
  (17) Williams G.; Seger, B.; Kamat, P. V. ACS Nano 2008, 2, 1487.
24. [24]
  (18) Wang,W. D.; Serp, P.; Faria, J. L. Appl. Catal. B-Environ. 2005, 56, 305.
25. [25]
  (19) Yu, H.; Quan, X.; Chen, S.; Zhao, H. J. Phys. Chem. C 2007, 111, 12987.
26. [26]
  (20) Dai, K.; Peng, T.; Ke, D.;Wei, D. Nanotechnology 2009, 20, 125603.
27. [27]
  (21) Cho, J.; Schaab, S.; Roether, J.; Boccaccini, A. J. Nanopart. Res. 2008, 10, 99.
28. [28]
  (22) Dong, Z. J.; Li, X. K.; Li, N.; Jiang, Z. Y.; Hu, Z. J. Aerospace Materials & Technology 2009, 39, 58.
29. [29]
  [董志军, 李轩科, 李楠, 姜召阳, 胡子君. 宇航材料工艺, 2009, 39, 58.]
30. [30]
  (23) Akhavan, O.; Abdolahad, M.; Abdi, Y.; Mohajerzadeh, S. Carbon 2009, 47, 3280.
31. [31]
  (24) An, G.; Ma,W.; Sun, Z.; Liu, Z.; Han, B.; Miao, S.; Miao, Z.; Ding, K. Carbon 2007, 45, 1795.
32. [32]
  (25) Jitianu, A.; Cacciaguerra, T.; Berger, M. H.; Benoit, R.; Béguin, F.; Bonnamy S. Journal of Non-Crystalline Solids 2004, 345-346, 596.
33. [33]
  (26) Ohno, T.; Tsubota, T.; Nishijima, K.; Miyamoto, Z. Chem. Lett. 2004, 33, 750.
34. [34]
  (27) Sakthivel, S.; Kisch, H. Angew. Chem. Int. Edit. 2003, 42, 4908.
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
4. [4]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
5. [5]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
6. [6]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
7. [7]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
8. [8]
  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
9. [9]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
10. [10]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
11. [11]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
12. [12]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
13. [13]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
14. [14]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
15. [15]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
16. [16]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
17. [17]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
18. [18]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-0. doi: 10.1016/j.actphy.2025.100086
19. [19]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
20. [20]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398

Get Citation

PDF

XML

Metrics

PDF Downloads(1596)
Abstract views(3435)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142