Citation: ZHANG Xuan-Zhou, YANG Jun-Zhi, SONG Ping, TIAN Wen-Huai, LI Xing-Guo. Synthesis and Cyclic Hydrogenation Properties of Magnesium Ultrafine Nanoparticles Prepared by Acetylene Plasma[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1707-1711. doi: 10.3866/PKU.WHXB20110622 shu

Synthesis and Cyclic Hydrogenation Properties of Magnesium Ultrafine Nanoparticles Prepared by Acetylene Plasma

1.
1. Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 9 March 2011
Available Online: 4 May 2011
Fund Project: 国家自然科学基金(20971009, 20821091, 51071003) (20971009, 20821091, 51071003)国家重点基础研究发展规划(973) (2009CB939902, 2010CB631301)资助项目 (973) (2009CB939902, 2010CB631301)

Ultrafine Mg nanoparticles of around 40 nm in size were prepared by an acetylene plasma metal reaction, which is a revised approach of the traditional hydrogen plasma metal reaction. The morphology and the cyclic hydrogenation properties were investigated by transmission electron microscopy (TEM), X-ray diffraction (XRD), specific surface area (BET) tests, and the kinetics of hydrogenation and dehydrogenation. Because of the short diffusion distance and the large specific surface area, the kinetics of hydrogenation and dehydrogenation of the small Mg nanoparticles improved. The nanostructured carbon cover on the Mg nanoparticles decreased the amount of Mg nanoparticle oxidation and also prevented the growth of Mg nanoparticles during the hydrogenation and dehydrogenation process. Therefore, the Mg ultrafine nanoparticles exhibited excellent cycling stability. Cycling tests showed little loss in hydrogen storage capacity after 30 cycles.
- Magnesium,
- Nanoparticle,
- Hydrogen storage material,
- Acetylene plasma,
- Cyclic property
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