Citation: YUE Jun-Pei, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min. Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1446-1450. doi: 10.3866/PKU.WHXB20110620 shu

Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 16 December 2010
Available Online: 4 May 2011
Fund Project: 国家自然科学基金(20873114, 20833005) (20873114, 20833005)国家重点基础研究发展计划(2009CB930703)资助项目 (2009CB930703)

Using the Scharifker and Hills model and Heerman and Tarallo model, cyclic voltammetry and chronoamperometry were used to study the nucleation mechanism upon the electrodeposition of a Pd-Ni alloy from an electrolyte. The results show that the electrodeposition of the Pd-Ni alloy onto glassy carbon electrode consisted of nucleation and growth, and the nucleation process according to the Scharifker and Hills model follows three dimension-progressive nucleation, which is controlled by the diffusion of the electroactive species. By applying the Heerman and Tarallo model, the kinetic parameters associated with the crystal nucleation and growth processes were obtained. The nucleation rate constant and the density of active nucleation sites increased from 0.83 to 7.71 s^-1 and from 2.77×10⁴ to 7.09×10⁴ cm^-2, respectively, as the step potential was changed from -0.85 to -0.92 V (vs SCE).
- Pd-Ni alloy,
- Electrocrystallization,
- Cyclic voltammetry,
- Chronoamperometry
1. [1]
  
  (1) Fleischmann, M.; Liler, M. Trans. Faraday Soc. 1958, 54, 1370.
2. [2]
  (2) Fleischmann, M.; Thirsk, H.R. Trans. Faraday Soc. 1955, 51, 71.
3. [3]
  (3) Fleischmann, M.; Thirsk, H.R. Electrochim. Acta 1958, 1, 146.
4. [4]
  (4) Gunawardena, G.A.; Hills, G.; Montenegro, I.; Scharifker, B. J. Electroanal. Chem. 1982, 138, 225.
5. [5]
  (5) Scharifker, B.; Hills, G. Electrochim. Acta 1983, 28, 879.
6. [6]
  (6) Scharifker, B.; Mostany, J. J. Electroanal. Chem. 1984, 177, 13.
7. [7]
  (7) Sluyters-Rehbach, M.;Wijenberg, J. H. O. J.; Bosco, E.; Sluyters, J. H. J. Electroanal. Chem. 1987, 236, 1.
8. [8]
  (8) Heerman, L.; Tarallo, A. J. Electroanal. Chem. 1999, 470, 70.
9. [9]
  (9) Hyde, M. E.; Compton, R. G. J. Electroanal. Chem. 2003, 549, 1.
10. [10]
  (10) Franz, S.; Yasumura, K. Galvanotechnik 2002, 93, 1210.
11. [11]
  (11) Hiramoto, O. ECS Transactions 2008, 3, 11.
12. [12]
  (12) Abys, J. A.; Straschil, H. K.; Kadija, I. V.; Kudrak, E. J.; Blee, J. J. Metal Finish. 1991, 89, 43.
13. [13]
  (13) Valcarcel, A.; Morfin, F.; Piccolo, L. J. Catal. 2009, 263, 315.
14. [14]
  (14) Lou, Y.; Shao, Y.T .; Li, P.; Li, Z. L.; Niu, Z. J. J. Electroanal. Chem. 2008, 624, 33.
15. [15]
  (15) Du, C. Y.; Chen, M.;Wang,W. G.; Yin, G. P.; Shi, P. F. Electrochem. Commun. 2010, 12, 843.
16. [16]
  (16) Qiu, C. C.; Shang, R.; Xie, Y. F. ; Bu, Y. R. ; Li, C. Y. ; Ma, H. Y. Mater. Chem. Phys. 2010, 120, 323.
17. [17]
  (17) Shobha, T.; Aravinda, C. L.; Parthasarathi, B.; mathi, D. L.; Mayanna, S. M. Mater. Chem. Phys. 2003, 80, 656.
18. [18]
  (18) Yang, F. Z.; Huang, L.; Xu, S. K.; Zhou, S. M. Acta. Phys.-Chim. Sin. 2004, 20,463.
19. [19]
  [杨防祖, 黄令, 许书楷, 周绍民. 物理化学学报, 2004, 20,463.]
20. [20]
  (19) Danaee, I.; Shoghi, F.; Dehghani, M. M.; Kameli, M. J. Solid State Electrochem. 2010, 14, 57.
21. [21]
  (20) Safonova, T. Y. ; Khairullin, D. R.; Tsirlina, G. A.; Petrii, O. A.; Vassiliev, S. Y. Electrochim. Acta 2005, 50, 4752.
22. [22]
  (21) Fletcher, S. Electrochim. Acta 1983, 28, 917.
23. [23]
  (22) Fletcher, S.; Halliday, C. S.; Gates, D.;Westcott, M.; Lwin, T.; Nelson, G. J. Electroanal. Chem. 1983, 159, 267.
24. [24]
  (23) Alvarez, A. E.; Salinas, D. R. Electrochim. Acta 2010, 55, 3714.
25. [25]
  (24) Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamental and Applications, 2nd ed.; JohnWiley: New York, 2001; pp 228-239.
26. [26]
  (25) Feng, G.; Xiong, Y.;Wang, H.; Yang, Y. Electrochim. Acta 2008, 53, 8253.
27. [27]
  (26) Heerman, L.; Tarallo, A. J. Electroanal. Chem. 1998, 451, 101.
28. [28]
  (27) Michailova, E.; Milchev, A. J. Appl. Electrochem. 1991, 21, 170.
1. [1]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
2. [2]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
3. [3]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
4. [4]
  Na Li , Limin Shao . Deduction of the General Formula of the Inverse Function of the Titration Curve. University Chemistry, 2025, 40(3): 390-401. doi: 10.12461/PKU.DXHX202409134
5. [5]
  Shanying Chen , Kangning Huo , Ke Qi , Jingyi Li , Shuxin Li , Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067
6. [6]
  Yan Xiao , Shuling Li , Yifan Li , Jianing Fan , Linlin Shi . Discovering the Beauty of Life: Adding Some “Ingredients” to Crystals. University Chemistry, 2024, 39(6): 366-372. doi: 10.3866/PKU.DXHX202312025
7. [7]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
8. [8]
  Xuewei Qian , Xingwen Sun , Houjin Li , Zhanxiang Liu , Yuan Zheng , Lin Wu , Shuanglian Cai , Ying Xiong , Guangao Yu , Qingwen Liu , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Shuyong Zhang , Jianrong Zhang . Basic Operations and Specification Suggestions for Organic Chemical Recrystallization Experiments. University Chemistry, 2025, 40(5): 66-75. doi: 10.12461/PKU.DXHX202503126
9. [9]
  Chengshan Yuan , Xiaolong Li , Xiuping Yang , Xiangfeng Shao , Zitong Liu , Xiaolei Wang , Yongwen Shen . Standardized Operational Guidelines for Mixed-Solvent Recrystallization in Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 122-127. doi: 10.12461/PKU.DXHX202504073
10. [10]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
11. [11]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
12. [12]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
13. [13]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
14. [14]
  Xueting Cao , Shuangshuang Cha , Ming Gong . Interfacial Electrical Double Layer in Electrocatalytic Reactions: Fundamentals, Characterizations and Applications. Acta Physico-Chimica Sinica, 2025, 41(5): 100041-0. doi: 10.1016/j.actphy.2024.100041
15. [15]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043
16. [16]
  Jie WU , Zhihong LUO , Xiaoli CHEN , Fangfang XIONG , Li CHEN , Biao ZHANG , Bin SHI , Quansheng OUYANG , Jiaojing SHAO . Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 948-958. doi: 10.11862/CJIC.20240400
17. [17]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
18. [18]
  Kai PENG , Xinyi ZHAO , Zixi CHEN , Xuhai ZHANG , Yuqiao ZENG , Jianqing JIANG . Progress in the application of high-entropy alloys and high-entropy ceramics in water electrolysis. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1257-1275. doi: 10.11862/CJIC.20240454
19. [19]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
20. [20]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016

Get Citation

PDF

XML

Metrics

PDF Downloads(1175)
Abstract views(2319)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142