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Citation: LI Jian-Sheng, GU Juan, LING Xiao-Feng, SUN Xiu-Yun, SHEN Jin-You, HAN Wei-Qing, WANG Lian-Jun. Synthesis of Ordered Mesoporous Carbon Loaded Fe, Co, Ni Nanocrystals by the Soft Templating Route and Their Characterization[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1772-1776. doi: 10.3866/PKU.WHXB20110613 shu

Synthesis of Ordered Mesoporous Carbon Loaded Fe, Co, Ni Nanocrystals by the Soft Templating Route and Their Characterization

  • 1.

    School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

  • Received Date: 27 December 2010
    Available Online: 27 April 2011

    Fund Project: 国家自然科学基金(51078184) (51078184) 高等学校科技创新工程重大项目培育项目(708049) (708049) 江苏省自然科学基金(BK2009392) (BK2009392)南京理工大学自主科研专项计划项目(2010ZDJH03)资助 (2010ZDJH03)

  • We report a one-step method for the synthesis of M(Fe, Co, Ni) nanocrystals supported by ordered mesoporous carbon (OMC) materials. M/OMC composites were obtained by the soft templating route under acidic conditions using resorcinol and formaldehyde as carbon precursors, triblock copolymer Pluronic F127 as a template and Fe, Co, Ni nitrates as metal precursors. The as-synthesized materials were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and N2 adsorption. Characterization revealed that the as-synthesized materials possessed an ordered hexa nal mesoporous structure similar to SBA-15. The specific surface areas of the Fe/OMC, Co/OMC, and Ni/OMC composites were found to be 586, 626, and 698 m2·g-1, respectively. The fact that the metal species were present as highly dispersed nanocrystals in the OMC matrix was confirmed by XRD and high-resolution TEM.

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    1. [1]

      (1) Chen, T.;Wang, T.;Wang, D. J.; Zhao, J. Q.; Ding, X. C.;Wu, S. C.; Xue, H. R.; He, J. P. Acta Phys. -Chim. Sin. 2010, 26, 3249. [陈田, 王涛, 王道军, 赵建庆, 丁晓春, 吴士超, 薛海荣, 何建平. 物理化学学报, 2010, 26, 3249.]

    2. [2]

      (2) Ariga, K.; Vinu, A.; Ji, Q. M.; Ohmori, O.; Hill, J. P.; Acharya, S.; Koike, J.; Shiratori, S. Angew Chem. Int. Edit. 2008, 47, 7254.  

    3. [3]

      (3) Yoshimune, M.; Yamamoto, T.; Nakaiwa, M.; Haraya, K. Carbon 2008, 46, 1031.  

    4. [4]

      (4) Wang, D. J.;Wang, T.; Zhou, J. H.; Sun, D.; Di, Z. Y.; He, J. P. Chin. J. Inorg. Chem. 2010, 26, 305. [王道军, 王涛, 周建华, 孙盾, 狄志勇, 何建平. 无机化学学报, 2010, 26, 305.]

    5. [5]

      (5) (a) Ryoo, R.; Joo, S. H.; Jun, S. J. Phys. Chem. B 1999, 103, 7743.  

    6. [6]

      (b) Liang, C.; Li, Z.; Dai, S. Angew Chem. Int. Edit. 2008, 47, 3696.

    7. [7]

      (6) Zhang, F. Q.; Meng, Y.; Gu, D.; Yan, Y.; Yu, C. Z.; Tu, B.; Zhao, D. Y. J. Am. Chem. Soc. 2005, 127, 13508.  

    8. [8]

      (7) Liang, C. D.; Dai. S. J. Am. Chem. Soc. 2006, 128, 5316.  

    9. [9]

      (8) Liu, R.; Ren, Y.; Shi, Y.; Zhang, F.; Zhang, L.; Tu, B.; Zhao, D. Y. Chem. Mater. 2008, 20, 11406.

    10. [10]

      (9) Gao, P.;Wang, A. Q.;Wang, X.; Zhang, T. Chem. Mater. 2008, 20, 1881.  

    11. [11]

      (10) Gao, P.;Wang, A. Q.;Wang, X.; Zhang, T. Catal. Lett. 2008, 125, 289.  

    12. [12]

      (11) Zhao, D. Y.; Feng, J.; Huo, Q. S.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.  

    13. [13]

      (12) Liu, S.; Zhu, J.; Mastai, Y. Chem. Mater. 2000, 12, 2205.  

    14. [14]

      (13) Xu, P.; Han, X.;Wang, C. J. Phys. Chem. B 2008, 112, 10443.  

    15. [15]

      (14) Sevilla, M.; Fuertes, A. B. Carbon 2006, 44, 468.  

    16. [16]

      (15) Zhai, Y. P.; Dou, Y. Q.; Liu, X. X.; Park, S. S.; Ha, C. S.; Zhao, D. Y. Carbon 2011, 49, 545.  


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    沈阳化工大学材料科学与工程学院 沈阳 110142

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