Citation: LONG Jin-Xing, GUO Bin, LI Xue-Hui, WANG Fu-Rong, WANG Le-Fu. Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 995-999. doi: 10.3866/PKU.WHXB20110506 shu

Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids

1.
School of Chemistry and Chemical Engineering, Pulp & Paper Engineering State Key Laboratory of China, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 12 January 2011
Available Online: 25 March 2011
Fund Project: 国家自然科学基金(20876055, 21076085) (20876055, 21076085)

Cellulose, the abundant and cost-ineffective resource, is considered to be a perfect alternative for the alleviation of energy crisis and environmental pollution. However, most processes for the treatment of cellulose are ri r currently as it is insoluble in water and conventional organic solvents due to its strong intra and inter-molecular hydrogen bonds, where the phase problem hampers its utilization widely. Here, we built a novel and efficient cooperative ionic liquid pairs system for the low temperature catalytic conversion of cellulose, which was constructed through the combination of an acidic ionic liquid catalyst and a cellulose soluble ionic liquid solvent. The catalytic decomposition behavior of microcrystal cellulose in this vi rous catalytic system was studied intensively by thermogravimetry (TG). Results show that the decomposition temperature of cellulose decreases greatly in all cooperative ionic liquid pairs, cellulose dissolved in ionic liquid solvents can be in situ catalytic decomposed by acidic ionic liquids. Furthermore, the decomposition temperature is dependent on the acidic strength of the ionic liquid catalysts, stronger acidity results in a lower decomposition temperature of the cellulose. Moreover, we found that cellulose can be decomposed at lower temperature when the ionic liquid with higher solubility of cellulose is used.
- Cooperative ionic liquid,
- Cellulose,
- Catalytic decomposition,
- Thermogravimetry,
- Acidic strength
1. [1]
  
  (1) Christensen, C. H.; Rass-Hansen, J.; Marsden, C. C.; Taarning, E.; Egeblad, K. Chemsuschem 2008, 1, 283.
2. [2]
  (2) Himmel, M. E.; Ding, S. Y.; Johnson, D. K.; Adney, W. S.; Nimlos, M. R.; Brady, J. W.; Foust, T. D. Science 2007, 315, 804.
3. [3]
  (3) Hoffert, M. I.; Caldeira, K.; Benford, G.; Criswell, D. R.; Green, C.; Herzog, H.; Jain, A. K.; Kheshgi, H. S.; Lackner, K. S.; Lewis, J. S.; Lightfoot, H. D.; Manheimer, W.; Mankins, J. C.; Mauel, M. E.; Perkins, L. J.; Schlesinger, M. E.; Volk, T.; Wigley, T. M. L. Science 2002, 298, 981.
4. [4]
  (4) Corma, A.; Iborra, S.; Velty, A. Chem. Rev. 2007, 107, 2411.
5. [5]
  (5) Huber, G. W.; Iborra, S.; Corma, A. Chem. Rev. 2006, 106, 4044.
6. [6]
  (6) Alonso, D. M.; Bond, J. Q.; Dumesic, J. A. Green Chem. 2010, 12, 1493.
7. [7]
  (7) Zou, S. P.; Wu, Y. L.; Yang, M. D.; Li, C.; Tong, J. M. Energy Fuels 2009, 23, 3753.
8. [8]
  (8) Balat, M. Energy Sources Part A. 2008, 30, 649.
9. [9]
  (9) Klemm, D.; Heublein, B.; Fink, H. P.; Bohn, A. Angew. Chem. Int. Edit. 2005, 44, 3358.
10. [10]
  (10) Lee, S. H.; Doherty, T. V.; Linhardt, R. J.; Dordick, J. S. Biotechnol. Bioeng. 2009, 102, 1368.
11. [11]
  (11) Swatloski, R. P.; Spear, S. K.; Holbrey, J. D.; Rogers, R. D. J. Am. Chem. Soc. 2002, 124, 4974.
12. [12]
  (12) Li, X. H.; Zhang, L.; Li, Q.; Geng, W. G.; Ye, Y. J.; Wang, L. F. Acta Phys. -Chim. Sin. 2004, 20, 1465.
13. [13]
  [李雪辉, 张磊, 李琼, 耿卫国, 叶玉嘉, 王乐夫. 物理化学学报, 2004, 20, 1465.]
14. [14]
  (13) Zhao, W. T.; Chen, H. X.; Zhou, J. J.; Liu, N. A. Acta Phys. -Chim. Sin. 2009, 25, 1756.
15. [15]
  [赵伟涛, 陈海翔, 周建军, 刘乃安. 物理化学学报, 2009, 25, 1756.]
16. [16]
  (14) Feng, J. L.; Zhang, J. G.; Zhang, T. L.; Cui, Y. Acta Phys. -Chim. Sin. 2010, 26, 2410.
17. [17]
  [冯金玲, 张建国, 张同来, 崔燕. 物理化学学报, 2010, 26, 2410.]
18. [18]
  (15) Meng, G. G.; Kong, D. J.; Qi, X. L.; Xu, Z. Q. Acta Phys. -Chim. Sin. 2010, 26, 3017.
19. [19]
  [蒙根, 孔德金, 祁晓岚, 许中强. 物理化学学报, 2010, 26, 3017.]
20. [20]
  (16) Lin, Y. C.; Cho, J.; Tompsett, G. A.; Westmoreland, P. R.; Huber, G. W. J. Phy. Chem. C 2009, 113, 20097.
21. [21]
  (17) Zhang, H.; Zhao, F. Q.; Yi, J. H.; Zhang, X. H.; Hu, R. Z.; Xu, S. Y.; Ren, X. N. Acta Phys. -Chim. Sin. 2008, 24, 2263.
22. [22]
  [张衡, 赵凤起, 仪建华, 张晓宏, 胡荣祖, 徐司雨, 任晓宁. 物理化学学报, 2008, 24, 2263.]
23. [23]
  (18) Chattopadhyay, J.; Kim, C.; Kim, R.; Pak, D. J. Ind. Eng. Chem. 2009, 15, 72.
24. [24]
  (19) Yu, Z. S.; Ma, X. Q.; Liu, A. Energy Convers. Manage. 2009, 50, 561.
25. [25]
  (20) Gui, J. Z.; Cong, X. H.; Liu, D.; Zhang, X. T.; Hu, Z. D.; Sun, Z. L. Catal. Commun. 2004, 5, 473.
26. [26]
  (21) Wang, W.; Shao, L.; Cheng, W.; Yang, J.; He, M. Catal. Commun. 2008, 9, 337.
27. [27]
  (22) Fei, Z. F.; Zhao, D. B.; Geldbach, T. J.; Scopelliti, R.; Dyson, P. J. Chem. Eur. J. 2004, 10, 4886.
28. [28]
  (23) Wasserscheid, P.; Sesing, M.; Korth, W. Green Chem. 2002, 4, 134.
29. [29]
  (24) Bonhote, P.; Dias, A. P.; Papageorgiou, N.; Kalyanasundaram, K.; Grätzel, M. Inorg. Chem. 1996, 35, 1168.
30. [30]
  (25) Cole, A. C.; Jensen, J. L.; Ntai, I.; Tran, K. L. T.; Weaver, K. J.; Forbes, D. C.; Davis, J. H. J. Am. Chem. Soc. 2002, 124, 5962.
31. [31]
  (26) Adamovsky, O.; Kopp, R.; Hilscherova, K.; Babica, P.; Palikova, M.; Paskova, V.; Navratil, S.; Marsalek, B.; Blaha, L. Environ. Toxicol. Chem. 2007, 26, 2687.
32. [32]
  (27) Handy, S. T.; Okello, M.; Dickenson, G. Org. Lett. 2003, 5, 2513.
33. [33]
  (28) Yoshizawa-Fujita, M.; Johansson, K.; Newman, P.; MacFarlane, D. R.; Forsyth, M. Tetrahedron Lett. 2006, 47, 2755.
34. [34]
  (29) Li, X. H.; Duan, H. L.; Pan, J. T.; Wang, L. F. Chin. J. Anal. Chem. 2006, 34(Suppl. 1) , 192.
35. [35]
  [李雪辉, 段红丽, 潘锦添, 王乐夫. 分析化学, 2006, 34(Suppl. 1), 192.]
36. [36]
  (30) Thornazeau, C.; Olivier-Bourbi u, H.; Magna, L.; Luts, S.; Gilbert, B. J. Am. Chem. Soc. 2003, 125, 5264.
37. [37]
  (31) Kosan, B.; Michels, C.; Meister, F. Cellulose 2008, 15, 59.
38. [38]
  (32) Pinkert, A.; Marsh, K. N.; Pang, S. S.; Staiger, M. P. Chem. Rev. 2009, 109, 6712.
39. [39]
  (33) Ciolacu, D.; Popa, V. I. Cellul. Chem. Technol. 2006, 40, 445.
40. [40]
  (34) Fredlake, C. P.; Crosthwaite, J. M.; Hert, D. G.; Aki, S. N. V. K.; Brennecke, J. F. J. Chem. Eng. Data 2004, 49, 954.
41. [41]
  (35) Vitz, J.; Erdmenger, T.; Haensch, C.; Schubert, U. S. Green Chem. 2009, 11, 417.
1. [1]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
4. [4]
  Yan'e LIU , Shengli JIA , Yifan JIANG , Qinghua ZHAO , Yi LI , Xinshu CHANG . MoO₃/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054
5. [5]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010
6. [6]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
7. [7]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
8. [8]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
9. [9]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
10. [10]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
11. [11]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Accelerating the reconstruction of NiSe₂ by Co/Mn/Mo doping for enhanced urea electrolysis. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-0. doi: 10.1016/j.actphy.2025.100083
12. [12]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
13. [13]
  Yongqing Xu , Yuyao Yang , Mengna Wu , Xiaoxiao Yang , Xuan Bie , Shiyu Zhang , Qinghai Li , Yanguo Zhang , Chenwei Zhang , Robert E. Przekop , Bogna Sztorch , Dariusz Brzakalski , Hui Zhou . Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels. Acta Physico-Chimica Sinica, 2024, 40(4): 2304003-0. doi: 10.3866/PKU.WHXB202304003
14. [14]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-0. doi: 10.3866/PKU.WHXB202310013
15. [15]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
16. [16]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . Catalytic Effect of H₃PW₁₂O₄₀ on Hydrogen Storage of MgH₂. Acta Physico-Chimica Sinica, 2025, 41(1): 100001-0. doi: 10.3866/PKU.WHXB202308032
17. [17]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
18. [18]
  Qi Wu , Changhua Wang , Yingying Li , Xintong Zhang . Enhanced photocatalytic synthesis of H₂O₂ by triplet electron transfer at g-C₃N₄@BN van der Waals heterojunction interface. Acta Physico-Chimica Sinica, 2025, 41(9): 100107-0. doi: 10.1016/j.actphy.2025.100107
19. [19]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
20. [20]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102

Get Citation

PDF

XML

Metrics

PDF Downloads(1730)
Abstract views(2954)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142