Citation: ZHANG Xiao-Hong, GUO Hong-Rui, JIAO Zhi, YAN Wei-Wei, RUAN Wen-Juan, ZHU Zhi-Ang. Weak Interactions in Asymmetric Porphyrin Systems[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 774-780. doi: 10.3866/PKU.WHXB20110432 shu

Weak Interactions in Asymmetric Porphyrin Systems

1.
College of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 27 December 2010
Available Online: 14 March 2011
Fund Project: 国家自然科学基金(20671053)资助项目 (20671053)

The weak interactions of 5-imidazolylmethylphenyl-10,15,20-tri-tert-butylphenylporphyrin (1) and 5-imidazolylmethylphenyl-10,15,20-triphenylporphyrin (2) were investigated in chloroform by ¹H NMR, UV-Vis and fluorescence spectroscopies, and molecular modeling simulation. The ¹H NMR chemical shifts of imidazole in compounds 1 and 2 move upfield compared with that of free imidazole and this shows that intramolecular or intermolecular weak interactions exist in both compounds. Compared with the UV-Vis spectra of compounds 1 and 2 in acetone, their spectra in chloroform show a split Soret band for compound 1, which indicates a weak intramolecular interaction and a red shift of 27 nm for compound 2, which also suggests a weak intermolecular interaction. The fluorescence data supports these results and the data obtained from the molecular simulation are consistent with those of the spectral analyses.
- Weak interaction,
- Asymmetric porphyrin,
- ¹H NMR,
- UV-Vis spectrum,
- Conformation analysis
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沈阳化工大学材料科学与工程学院沈阳 110142