Citation: MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui. Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 893-899. doi: 10.3866/PKU.WHXB20110431 shu

Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide

1.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Received Date: 17 November 2010
Available Online: 14 March 2011
Fund Project: 教育部新世纪优秀人才计划(NCET-08-0075)资助项目 (NCET-08-0075)

Manganese dioxide (MnO₂) was synthesized using a fluid phase method with potassium permanganate and manganous acetate as precursors. The obtained MnO₂ was treated thermally at different temperatures. The structural transformation of MnO₂, its electrochemical behavior as an electrode material for use in a supercapacitor were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 physical adsorption, thermogravimetry (TG), cyclic voltammetry, and galvanostastic charge-discharge. The results indicate that the synthesized MnO₂ can be assigned to its α phase and that it possesses a mesoporous feature with a high surface area of up to 253 m²·g^-1. After a low temperature thermal treatment (<350 °C), the manganese oxide retained its α-MnO₂ crystal structure and its specific surface area was found to be approximately 170 m²·g^-1. The specific capacitance of the single electrode increased from 267 F·g^-1 for untreated MnO₂ to 286 F·g^-1 for the sample treated at 250 °C. However, high temperature thermal treatment (>450 °C) results in a transformation of the manganese oxide structure to α-Mn₂O₃ and then to α-Mn₃O₄. Additionally, the surface area reduced to ca 30 m²·g^-1 and this lead to a dramatic decrease in the specific capacitance of manganese oxide. The electrochemical cycling stability of manganese oxide improved noticeably after low temperature thermal treatment and the electrode retained a od rate performance at a scan rate of 50 mV·s^-1.
- Manganese dioxide,
- Supercapacitor,
- Electrode material,
- Thermal treatment
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沈阳化工大学材料科学与工程学院沈阳 110142