Citation: WU Xiao-Lin, SUN Rong, ZHU Peng-Li, DU Ru-Xu. Near Infrared Spectrum Analysis of Organic/Inorganic Composite Microcapsule Phase Change Materials[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1039-1044. doi: 10.3866/PKU.WHXB20110424 shu

Near Infrared Spectrum Analysis of Organic/Inorganic Composite Microcapsule Phase Change Materials

WU Xiao-Lin ^1,2 ,
SUN Rong ^1, ,
ZHU Peng-Li ¹ ,
DU Ru-Xu ³

1.
1. Shenzhen Institutes of Advanced?Technology, Chinese Academy of Sciences, Shenzhen 518055, Guandong Province, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. The Chinese University of Hong Kong, Hong Kong, P. R. China

Received Date: 27 October 2010
Available Online: 11 March 2011
Fund Project: 国家自然科学基金(20971089)资助项目 (20971089)

Using Fourier transform near infrared (FT-NIR) spectroscopy, the characteristics and phase change mechanism of the phase change process for PMMA-SiO₂@PCM microcapsules were explored. We investigated changes in the microstructure of the microcapsules as well. The results show that the melting of paraffin molecules in the microcapsules is a process wherein the －CH₂ symmetric stretching vibration gradually increases and the asymmetric stretching vibration changes randomly. During the paraffin phase change process, the change in absorbance intensity is only half that of the shell materials. Additionally, NIR spectroscopy was used to analyze the core-shell structure and to monitor the phase change process for the microcapsules. The application of NIR spectroscopy to study the phase change process for microcapsule phase change materials has scientific significance and is of value to study the phase change mechanism for the determination of the most efficient phase change materials.
- Microcapsule,
- Fourier transform near infrared,
- Phase change material,
- Phase change,
- Organic/inorganic composite material
1. [1]
  
  (1) Lu, W. Z. Modern Near Infrared Spectroscopy Analytical Technology, 2nd ed.; China Petrochemical Press: Beijing, 2007; pp 16-345.
2. [2]
  [陆婉珍. 现代近红外光谱分析技术(第二版). 北京: 中国石化出版社, 2007: 16-345.]
3. [3]
  (2) Wurster, D. E.; Werawatganone, P. J. Pharm. Sci. 2010, 99, 1440.
4. [4]
  (3) Green, B. K.; Lowell, S. Oil-Containing Microscopic Capsules and Method of Making Them. USA Pat. Appl. 2800457, 1957.
5. [5]
  (4) Rau, G. C. Science 1950, 111, 229.
6. [6]
  (5) David, S. E.; Daniels, E. S.; El-Aasser, M. S. ACS Symposium Series 1992, 492, 1.
7. [7]
  (6) Su, J. F.; Wang, L. X.; Ren, L. Colloid Polym. Sci. 2005, 284, 224.
8. [8]
  (7) Wang, J. P.; Zhao, X. P; Guo, H. L. Langmuir 2004, 20, 10845.
9. [9]
  (8) Frere, Y.; Danicher, L.; Gramain, P. Eur. Polym. J. 1998, 34, 193.
10. [10]
  (9) Kim, E. Y.; Do, K. H. J. Appl. Polym. Sci. 2005, 96, 1596.
11. [11]
  (10) Hawlader, M. N. A.; Uddin, M. S.; Khin, M. M. Appl. Energy 2003, 74, 195.
12. [12]
  (11) Loxley, A.; Vincent, B. J. Colloid Interf. Sci. 1998, 208, 49.
13. [13]
  (12) Jorge, L. C.; Jeffrey, L. W.; Randolph, S. D. Langmuir 2008, 24, 2064.
14. [14]
  (13) Brinker, C. J. Advances in chemistry 1994, 234, 361.
15. [15]
  (14) Ogawa, K.; Chemburu, S.; Lopez, G. P.; Whitten, D. G.; Schanze, K. S. Langmuir 2007, 23, 4541.
16. [16]
  (15) Joncheray, T. J.; Audebert, P.; Schwartz, E.; Jovanovic, A. V.; Ishaq, O.; Chávez, J. L.; Pansu, R.; Duran, R. S. Langmuir 2006, 22, 8684.
17. [17]
  (16) Zhang, H. Z.; Wang, X. D.; Wu, D. Z. J. Colloid Interface Sci. 2010, 343, 246.
18. [18]
  (17) Wu, X. L.; Wang, Y. H.; Sun, R.; Lai, M. B.; Du, R. X.; Zhang, Z. J. Journal of Physics-Conference Series 2009, 188, 012046.
19. [19]
  (18) Mercedes, P.; Matias, J.; Mariana, B. M.; Susana, C. G.; Sara, A. B. Chem. Mater. 2008, 20, 3015.
20. [20]
  (19) Chang, C. C.; Tsai, Y. L.; Chiu, J. J.; Chen, H. Journal of Applied Polymer Science 2009, 112, 1850.
21. [21]
  (20) Chang, K. C.; Chen, Y. K.; Chen, H. Journal of Applied Polymer Science 2008, 107, 1530.
22. [22]
  (21) Zou, H.; Wu, S. S.; Shen, J. Chem. Rev. 2008, 108, 3893.
23. [23]
  (22) Reikichi, I.; Toshihiko, M. Anal. Chem. 2007, 79, 3455.
24. [24]
  (23) Matsushita, A.; Ren, Y. Z.; Matsukawa, K.; Inoue, H.; Minami, Y.; Noda, I.; Ozaki, Y. Vibrational Spectroscopy 2000, 24, 171.
25. [25]
  (24) Chung, H.; Ku, M. S. Applied Spectroscopy 2003, 57, 545.
26. [26]
  (25) Lu, W. Z.; Yuan, H. F.; Xu, G. T.; Qiang, D. M. Modern Near Infrared Spectroscopy Analytical Technology, 1st ed.; China Petrochemical Press: Beijing, 2000; pp 20-26.
27. [27]
  [陆婉珍, 袁洪福, 徐广通, 强冬梅. 现代近红外光谱分析技术(第一版). 北京: 中国石化出版社, 2000: 20-26.]
1. [1]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
2. [2]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
3. [3]
  Ruonan Li , Shijie Liang , Yunhua Xu , Cuifen Zhang , Zheng Tang , Baiqiao Liu , Weiwei Li . Chlorine-Substituted Double-Cable Conjugated Polymers with Near-Infrared Absorption for Low Energy Loss Single-Component Organic Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(8): 2307037-0. doi: 10.3866/PKU.WHXB202307037
4. [4]
  Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
5. [5]
  Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
6. [6]
  Lina Feng , Guoyu Jiang , Xiaoxia Jian , Jianguo Wang . Application of Organic Radical Materials in Biomedicine. University Chemistry, 2025, 40(4): 253-260. doi: 10.12461/PKU.DXHX202405171
7. [7]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
8. [8]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072
9. [9]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
10. [10]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
11. [11]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
12. [12]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
13. [13]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
14. [14]
  Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe_0.95S_1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006
15. [15]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 2310024-0. doi: 10.3866/PKU.WHXB202310024
16. [16]
  Yang Wang , Yunpeng Fu , Xiaoji Liu , Guotao Zhang , Guobin Li , Wanqiang Liu , Jinglun Wang . Structural Analysis of Nitrile Solutions Based on Infrared Spectroscopy Probes. University Chemistry, 2025, 40(4): 367-374. doi: 10.12461/PKU.DXHX202406113
17. [17]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
18. [18]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
19. [19]
  Wei Li , Jinfan Xu , Yongjun Zhang , Ying Guan . 共价有机框架整体材料的制备及食品安全非靶向筛查应用——推荐一个仪器分析综合化学实验. University Chemistry, 2025, 40(6): 276-285. doi: 10.12461/PKU.DXHX202406013
20. [20]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

Get Citation

PDF

XML

Metrics

PDF Downloads(1448)
Abstract views(2644)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142