Citation: CHEN Jin-Yi, LI Nian, LI Jing, ZHU Liang, PENG Chang-Jun. Synthesis and Visible Light Photocatalytic Activity of Cross-Linked Sodium Rectorite/Cu₂O Nanocomposites[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 932-938. doi: 10.3866/PKU.WHXB20110329 shu

Synthesis and Visible Light Photocatalytic Activity of Cross-Linked Sodium Rectorite/Cu₂O Nanocomposites

CHEN Jin-Yi ^1,2, ,
LI Nian ¹ ,
LI Jing ¹ ,
ZHU Liang ¹ ,
PENG Chang-Jun ¹

1.
1. School of Environment and Civil Engineering, Wuhan Institute of Technology, Wuhan 430073, P. R. China;
2. Engneering Research Center for Exploitation and Utilization of Phosphorous Resources, Ministry of Education, Wuhan 430073, P. R. China

Received Date: 14 September 2010
Available Online: 17 February 2011
Fund Project: 国家自然科学基金(50804035)，湖北省自然科学基金(2008CDB375) (50804035)，湖北省自然科学基金(2008CDB375) 武汉市青年科技晨光计划(200950431194) (200950431194)武汉工程大学青年基金(Q0806)资助项目 (Q0806)

CN-REC/Cu₂O nanocomposites were synthesized with Cu(CH3COO)2·H₂O as a copper source and cross-linked sodium rectorite (CN-REC) as a carrier and template. The obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and ultraviolet visible diffuse reflectance spectrum (UV-Vis DRS). The results indicate that the regulatory effects of CN-REC on Cu₂O are significant. Cu₂O is dispersed in the interlayer and on the surface of?the lamellar structure of CN-REC. A Si―O―Cu bond was formed between the cuprous oxide crystal and the CN-REC crystal, which established a bridge for the transfer of photogenerated charge. The energy band gap of the nanocomposites became wider and the photoresponse properties of the nanocomposites became stronger. To study the visible light photocatalytic activity of the nanocomposites, reactive brilliant red (X-3B) was selected as a target contaminant. The photocatalytic degradation rate of X-3B with the nanocomposites is more than 80%, which is better than that with Cu₂O. The degradation progress accorded with the L-H kinetics equations.
- Cross-linked sodium rectorite,
- Cu₂O,
- Nanocomposites,
- Visible light photocatalytic activity
1. [1]
  
  (1) Zhang, L. S. The study on the photocatalytic activity of nano Cu₂O nanocomposites and semiconductor-type carbon nano-tubes. Master degree Dissertation. Central China Normal University, Wuhan, 2005.
2. [2]
  [张丽莎. 纳米氧化亚铜复合材料及半导体型碳纳米管的光催化活性研究
3. [3]
  [D]. 武汉: 华中师范大学, 2005.]
4. [4]
  (2) Wood, B. J.; Wise, H.; Yolles, R. S. J. Catalys. 1969, 15, 355.
5. [5]
  (3) Zhen, K. J.; Wang, G. J.; Li, R. S.; Bi, Y. L.; Han, Q. B. Foundation of Catalysis, 3rd ed; Science Press: Beijing, 2005; pp 226-227.
6. [6]
  [甄开吉, 王国甲, 李荣生, 毕颖丽, 阚秋斌. 催化作用基础(第三版). 北京: 科学出版社, 2005: 226-227.]
7. [7]
  (4) Wu, P. X.; Ye, D. Q.; Ming, C. B. Bull. Mineral Petrol Geochem. 2002, 21, 228.
8. [8]
  [吴平霄, 叶代启, 明彩兵. 矿物岩石地球化学通报, 2002, 21, 228.]
9. [9]
  (5) Li, Z. H.; Jiang; W. T.; Hong, H. L. Spectrochimica Acta Part A 2008, 71, 1525.
10. [10]
  (6) Xiao, J. R.; Peng, T, Y.; Ke, D. N.; Cai, P.; Peng, Z. H. J. Func. Mater. 2007, 38, 1110.
11. [11]
  [肖江蓉, 彭天右, 柯丁宁, 蔡苹, 彭正合. 环境功能材料, 2007, 38, 1110.]
12. [12]
  (7) Yu, Y.; Du, F. P.; Yu, J. C.; Zhuang, Y. Y.; Wong, P. K. J. Solid State Chem. 2004, 177, 4640.
13. [13]
  (8) Xu, Z. Y.; Huang, B. L.; Yan, G. Q. The Technical Manual for Material Characterization and Detection; Chemical Industry Press: Beijing, 2009; pp 890-893.
14. [14]
  [徐祖耀, 黄本立, 鄢国强. 材料表征与检测技术手册; 北京: 化学工业出版社, 2009; 890-893.]
15. [15]
  (9) Zhu, Y. H. The Influences of Grain Size of Several Nanocrystallite to Lattice Constant and Magnetic Property. Master degree Dissertation. Hebei Normal University, Shijiazhuang, 2003.
16. [16]
  [祝玉华. 几种纳米晶的晶粒线度对其晶格常数和磁性的影响
17. [17]
  [D]. 石家庄: 河北师范大学, 2003.]
18. [18]
  (10) Sun, Z. Y.; Hu, C.; Ni, M. F.; ng, W. Q. Polym. Mater. Sci. Eng. 2006, 22, 213.
19. [19]
  [孙振亚, 胡纯, 黎明发, 龚文琪. 高分子材料科学与工程, 2006, 22; 213.]
20. [20]
  (11) Mei, C. S.; Zhong, S. H. Chin. J. Chem. Phys. 2005, 18, 821.
21. [21]
  [梅长松, 钟顺和. 化学物理学报, 2005, 18, 821.]
22. [22]
  (12) Li, C. Y.; Liu, S. X.; Ma, Y. Acta Phys. Chim. -Sin. 2009, 25, 1555.
23. [23]
  [李长玉, 刘守新, 马跃. 物理化学学报, 2009, 25, 1555.]
24. [24]
  (13) Luo, Y. S.; Li, S. Q.; Ren, Q. F. Cryst. Growth Des. 2007, 7, 87.
25. [25]
  (14) Chen, J. Y.; Li, W. Y.; Hai, T. T.; Li, N.; Li, W. Preparation of Immobilized Fenton Reagent with H₂O₂ Generated by Solar Light-Illuminated Cuprous oxide/Chitosan nanocomposites at Neutral pH Value. In Bioinformatics and Biomedical Engineering (iCBBE), the 4th International Conference on Digital Object Identifier, Chengdu, China, June 21-23, 2010; Scientifical Research Publishing, USA . 2010; 1-3.
26. [26]
  (15) Zhang, Y.; Chen, A. P.; Luo, M. F.; Li, C. Z.; Xu, Z. L. J. Chin. Process Eng. 2010, 10, 367.
27. [27]
  [张颖, 陈爱平, 罗美芳, 李春忠, 许振良. 过程工程学报, 2010, 10, 367.]
28. [28]
  (16) Peng, T. Y.; Xiao, J. R.; Ke, D. N.; Dai, K. Synthesis and Visible Light Photocatalytic Activity of CdS-TiO₂/Rectorite Nanocomposites. In Symposium for the 11th National Youth Congress on Catalysis, the 11th National Youth Congress on Catalysis, China University of Petroleum, Aug. 19-23, 2007.
29. [29]
  [彭天右, 肖江蓉, 柯丁宁, 戴珂. CdS-TiO₂/累托石复合材料的制备及其光催化性能研究. 第十一届全国青年催化会议论文集, 第十一届全国青年催化会议, 中国石油大学, 2007, 8, 19-23.]
30. [30]
  (17) Shangguan, W. F.; Yoshida, A. Sol. Energy Mater. Sol. Cells 2001, 16, 189.
31. [31]
  (18) Kim, S. H.; N , H. H.; Shon, H. K.; Vigneswaran, S. Sep. Purif. Technol. 2008, 58, 335.
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1.
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Synthesis and Visible Light Photocatalytic Activity of Cross-Linked Sodium Rectorite/Cu2O Nanocomposites

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Synthesis and Visible Light Photocatalytic Activity of Cross-Linked Sodium Rectorite/Cu₂O Nanocomposites