Citation: HAN Ling, NI Ji-Peng, ZHANG Liang-Miao, YUE Bao-Hua, SHEN Shan-Shan, ZHANG Hao, LU Wen-Cong. Controlled Synthesis of Mesoporous MnO₂ Nanospindles[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 743-748. doi: 10.3866/PKU.WHXB20110318 shu

Controlled Synthesis of Mesoporous MnO₂ Nanospindles

1.
Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China

Received Date: 27 September 2010
Available Online: 28 January 2011
Fund Project: 上海市纳米技术项目(0852nm00700) (0852nm00700)上海大学创新项目(A.10-0101-09-023)资助 (A.10-0101-09-023)

We synthesized mesoporous MnO₂ nanospindles by a one-step hydrothermal process in an aqueous solution of KMnO₄ and glucose. The structure, morphology, purity, and size of the products were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption (BET) measurements. The reaction time and concentrations of glucose influenced the final structures and shapes of the MnO₂ nanospindles. The length to diameter ratio of the MnCO₃ precursor nanospindles can be easily tuned from 1.35:1 to 2.89:1. A possible formation mechanism for the mesoporous MnO₂ nanospindles is proposed and discussed.
- Hydrothermal method,
- Spindle,
- MnO₂,
- Mesoporous
1. [1]
  
  (1) Carreon, M. A.; Guliants, V. V. Chem. Mater. 2002, 14, 2670.
2. [2]
  (2) Schuth, F. Chem. Mater. 2001, 13, 3184.
3. [3]
  (3) Yang, P. D.; Zhao, D. Y.; Mar lese, D. I.; Chmelka, B. F.; Stucky, G. D. Nature 1998, 396, 152.
4. [4]
  (4) Yang, P. D.; Zhao, D. Y.; Mar lese, D. I.; Chmelka, B. F.; Stucky, G. D. Chem. Mater. 1999, 11, 2813.
5. [5]
  (5) He, X.; Antonelli, D. Angew. Chem. Int. Edit. 2001, 41, 214.
6. [6]
  (6) Kresge, C.; Leonowicz, M.; Roth,W.; Vartuli, J.; Beck, J. Nature 1992, 359, 710.
7. [7]
  (7) Gu, F.; Li, C. Z.;Wang, S. F.; Lu, M. K. Langmuir 2006, 22, 1329.
8. [8]
  (8) Espinal, L.; Suib, S. L.; Rusling, J. F. J. Am. Chem. Soc. 2004, 126, 7676.
9. [9]
  (9) Armstrong, A. R.; Bruce, P. G. Nature 1996, 381, 499.
10. [10]
  (10) Song, X. C.; Zheng, Y. F.; Lin, S.;Wang, Y. Acta Phys.-Chim. Sin. 2007, 23, 258.
11. [11]
  [宋旭春, 郑遗凡, 林深, 王芸. 物理化学学报, 2007, 23, 258.]
12. [12]
  (11) Winter, M.; Brodd, R. J. Chem. Rev. 2004, 104, 4245.
13. [13]
  (12) Toupin, M.; Brousse, T.; Belanger, D. Chem. Mater. 2002, 14, 3946.
14. [14]
  (13) Wang, T.; Zhou, J. H.;Wang, D. J.; Sun, D.; Di, Z. Y.; He, J. P. Acta Phys-Chim. Sin. 2009, 25, 2155.
15. [15]
  [王涛, 周建华, 王道军, 孙盾, 狄志勇, 何建平. 物理化学学报, 2009, 25, 2155.]
16. [16]
  (14) Wills, A. S.; Raju, N. P.; Greedan, J. E. Chem. Mater. 1999, 11,1510.
17. [17]
  (15) Segal, S. R.; Park, S. H.; Suib, S. L. Chem. Mater. 1997, 9, 98.
18. [18]
  (16) Greedan, J. E.; Raju, N. P.;Wills, A. S.; Morin, C.; Shaw, S. M.; Reimers, J. N. Chem. Mater. 1998, 10, 3058.
19. [19]
  (17) Wang, F.;Wang, Y. M.;Wen, Y. X.; Su, H. F.; Li, B. Acta Phys.-Chim. Sin. 2010, 26, 521.
20. [20]
  [王凡, 王岩敏, 文衍宣, 粟海峰, 李斌. 物理化学学报, 2010, 26, 521.]
21. [21]
  (18) Deng, J. G.; Zhang, L.; Dai, H. X.; Xia, Y. S.; Jiang, H. Y.; Zhang, H.; He, H. J. Phys. Chem. C 2010, 114, 2694.
22. [22]
  (19) Cheng, F. Y.; Zhao, J. Z.; Song,W.; Li, C. S.; Ma, H.; Chen, J.; Shen, P.W. Inorg. Chem. 2006, 45, 2038.
23. [23]
  (20) Wang, X.; Li, Y. D. J. Am. Chem. Soc. 2002, 124, 2880.
24. [24]
  (21) Wang, X.; Li, Y. D. Chem-Eur. J. 2003, 9, 300.
25. [25]
  (22) Xiong, Y. J.; Xie, Y.; Li, Z. Q.;Wu, C. Z. Chem-Eur. J. 2003, 9, 1645.
26. [26]
  (23) Wei, M.; Konishi, Y.; Zhou, H.; Sugihara, H.; Arakawa, H. Nanotechnology 2005, 16, 245.
27. [27]
  (24) Yuan, Z. Y.; Ren, T. Z.; Du, G. H.; Su, B. L. Appl. Phys. A-Mater.2005, 80, 743.
28. [28]
  (25) Song, X. C.; Zhao, Y.; Zheng, Y. F. Cryst. Growth. Des. 2007, 7, 159.
29. [29]
  (26) Xiong, Y. J.; Xie, Y.; Li, X. X.; Li, Z. Q. Carbon 2004, 42, 1447.
30. [30]
  (27) Wong,W. K.; Li, C. P.; Au, F. C. K.; Fung, M. K.; Sun, X. H.; Lee, C. S.; Lee, S. T.; Zhu,W. J. Phys. Chem. B 2003, 107, 1514.
31. [31]
  (28) Chowdhury, A. K. M. S.;Cameron, D. C.;Hashmi, M. S. J. Thin Solid Films 1998, 332, 62.
32. [32]
  (29) Ho, C. M.; Yu, J. C.; Kwong, T.; Mak, A. C.; Lai, S. Y. Chem. Mater. 2005, 17, 4514.
33. [33]
  (30) Ananth, M. V.; Pethkar, S.; Dakshinamurthi, K. J. Power Sources 1998, 75, 278.
34. [34]
  (31) Liu, Z. H.; Yang, X. J.; Makita, Y.; Ooi, K. Chem. Mater. 2002, 14, 4800.
35. [35]
  (32) Wang, X. L.; Yuan, A. B.;Wang, Y. Q. J. Power Sources 2007, 172, 1007.
1. [1]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
2. [2]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
3. [3]
  Haoting Wang , Mengfan Luo , Yuzhong Wang , Jialong Yin , Heng Zhang , Jia Zhao , Bo Lai . Mn(Ⅱ) enhanced permanganate oxidation of trace organic pollutants in water: Critical role of in situ formation of colloidal MnO₂. Chinese Chemical Letters, 2025, 36(6): 110348-. doi: 10.1016/j.cclet.2024.110348
4. [4]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
5. [5]
  Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO₂ Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028
6. [6]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
7. [7]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
10. [10]
  Kun Chen , Huimin Lin , Xin Peng , Ziying Wu , Jingyue Dai , Yi Sun , Yaxuan Feng , Ziyi Huang , Zhiqiang Yu , Meng Yu , Guangyu Yao , Jigang Wang . In situ synthesis of MnO₂ micro/nano-adjuvants for enhanced immunotherapy of breast tumors. Chinese Chemical Letters, 2025, 36(5): 110045-. doi: 10.1016/j.cclet.2024.110045
11. [11]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010
12. [12]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
13. [13]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
14. [14]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
15. [15]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
16. [16]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
17. [17]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
18. [18]
  Yongqing Xu , Yuyao Yang , Mengna Wu , Xiaoxiao Yang , Xuan Bie , Shiyu Zhang , Qinghai Li , Yanguo Zhang , Chenwei Zhang , Robert E. Przekop , Bogna Sztorch , Dariusz Brzakalski , Hui Zhou . Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels. Acta Physico-Chimica Sinica, 2024, 40(4): 2304003-0. doi: 10.3866/PKU.WHXB202304003
19. [19]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
20. [20]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021

Get Citation

PDF

XML

Metrics

PDF Downloads(1375)
Abstract views(2771)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Controlled Synthesis of Mesoporous MnO2 Nanospindles

Metrics

通讯作者: 陈斌, bchen63@163.com

Controlled Synthesis of Mesoporous MnO₂ Nanospindles