Citation: YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling, CAO Dian-Xue. Supercapacitance of NiCo₂O₄ Nanowire Arrays Grown on Nickel Foam[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 615-619. doi: 10.3866/PKU.WHXB20110317 shu

Supercapacitance of NiCo₂O₄ Nanowire Arrays Grown on Nickel Foam

1.
College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, P. R. China

Received Date: 15 October 2010
Available Online: 28 January 2011
Fund Project: 国家自然科学基金(20973048) (20973048)中央高校基金(HEUCF101004)资助项目 (HEUCF101004)

We prepared an electrode consisting of NiCo₂O₄ nanowire arrays that stand freely on nickel foam by a template-free growth method. Its morphology was determined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The phase structure of the nanowires was analyzed by X-ray diffraction (XRD). The supercapacitance of the electrode was investigated by cyclic voltammetry, galvanostatic charge-discharge testing, and electrochemical impedance spectroscopy. The results showed that the nanowires were nearly vertical grow on and densely cover the nickel foam substrate. The nanowires have diameters around 500-1000 nm and lengths up to around 10 μm. The NiCo₂O₄ nanowire arrays have a specific capacitance of 741 F·g^-1 and this value is 655 F·g^-1 after 420 charge-discharge cycles. Electrochemical impedance spectroscopy measurements showed that the charge transfer resistance was only 0.33 Ω and this increased by only 0.06 Ω after 420 cycles.
- NiCo₂O₄,
- Nanowire array,
- Template-free growth method,
- Nickel foam,
- Surpercapacitor
1. [1]
  
  1 Burke, A. Electrochim. Acta 2007, 53, 1083.
2. [2]
  2 Kotz, R.; Carlen, M. Electrochim. Acta 2000, 45, 2483.
3. [3]
  3 Burke, A. J. Power Sources 2000, 91, 37.
4. [4]
  4 Zhang, Y.; Feng, H.; Wu, X.; Wang, L.; Zhang, A.; Xia, T.; Dong, H.; Li, X.; Zhang, L. Inter. J. Hydrog. Energy 2009, 34, 4889.
5. [5]
  5 Simon, P.; tsi, Y. Nat. Mater. 2008, 7, 845.
6. [6]
  6 Tian, Y.; Yan, J. W.; Liu, X. X.; Xu, R.; Yi, B. L. Acta Phys. -Chim. Sin. 2010, 26, 2151.
7. [7]
  [田颖, 阎景旺, 刘小雪, 薛荣, 衣宝廉. 物理化学学报, 2010, 26, 2151].
8. [8]
  7 Nam, K. T.; Kim, D. W.; Yoo, P. J.; Chiang, C. Y.; Meethong, N.; Hammond, P. T.; Chiang, Y. M.; Belcher, A. M. Science 2006, 312, 885.
9. [9]
  8 Li, Y.; Tan, B.; Wu, Y. J. Am. Chem. Soc. 2006, 128, 14258.
10. [10]
  9 Li, Y.; Tan, B.; Wu, Y. Nano Lett. 2008, 8, 265.
11. [11]
  10 Gao, Y. Y.; Chen, S. L.; Cao, D. X.; Wang, G. L.; Yin, J. L. J. Power Sources 2010, 195, 1757.
12. [12]
  11 Wang, G.; Cao, D.; Yin, C.; Gao, Y.; Yin, J.; Cheng, L. Chem. Mater. 2009, 21, 5112.
13. [13]
  12 Li, Y.; Tan, B.; Wu, Y. Chem. Mater. 2008, 20, 2602.
14. [14]
  13 Li, Y.; Hasin, P.; Wu, Y. Adv. Mater. 2010, 22, 1926.
15. [15]
  14 Wu, G.; Li, N.; Zhou, D. R.; Mitsuo, K.; Xu, B. Q. J. Solid State Chem. 2004, 177, 3682.
16. [16]
  15 Hu, C. C.; Lee, Y. S.; Wen, T. C. Mater. Chem. Phys. 1997, 48, 246.
17. [17]
  16 Cui, B.; Lin, H.; Li, J.B.; Li, X.; Yang, J.; Tao, J. Adv. Funct. Mater. 2008, 18, 1441.
18. [18]
  17 Singh, R. N.; Koenig, J. F.; Poillerat, G.; Chartier, P. J. Electrochem. Soc. 1990, 137, 1408.
19. [19]
  18 Chi, B.; Lin, H.; Li, J.; Wang, N.; Yang, J. Inter. J. Hydrog. Energy 2006, 31, 1210.
1. [1]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
2. [2]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
3. [3]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
4. [4]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-0. doi: 10.1016/j.actphy.2025.100063
5. [5]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
6. [6]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
7. [7]
  Huimin Liu , Kezhi Li , Xin Zhang , Xuemin Yin , Qiangang Fu , Hejun Li . SiC Nanomaterials and Their Derived Carbons for High-Performance Supercapacitors. Acta Physico-Chimica Sinica, 2024, 40(2): 2304026-0. doi: 10.3866/PKU.WHXB202304026
8. [8]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
9. [9]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
10. [10]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
11. [11]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . Preparation of High Density Activated Carbon by Mechanical Compression of Precursors for Compact Capacitive Energy Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-0. doi: 10.3866/PKU.WHXB202406009
12. [12]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
13. [13]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
14. [14]
  Jun Huang , Pengfei Nie , Yongchao Lu , Jiayang Li , Yiwen Wang , Jianyun Liu . 丝光沸石负载自支撑氮掺杂多孔碳纳米纤维电容器及高效选择性去除硬度离子. Acta Physico-Chimica Sinica, 2025, 41(7): 100066-0. doi: 10.1016/j.actphy.2025.100066
15. [15]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
16. [16]
  Qing Xue , Shengyi Li , Yanan Zhao , Peng Sheng , Li Xu , Zhengxi Li , Bo Zhang , Hui Li , Bo Wang , Libin Yang , Yuliang Cao , Zhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na_0.44MnO₂ towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Jianqiao ZHANG , Yang LIU , Yan HE , Yaling ZHOU , Fan YANG , Shihui CHENG , Bin XIA , Zhong WANG , Shijian CHEN . Ni-doped WP₂ nanowire self-standingelectrode: Preparation and alkaline electrocatalytic hydrogen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1610-1616. doi: 10.11862/CJIC.20240444
19. [19]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
20. [20]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008

Get Citation

PDF

XML

Metrics

PDF Downloads(2415)
Abstract views(3172)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam

Metrics

通讯作者: 陈斌, bchen63@163.com

Supercapacitance of NiCo₂O₄ Nanowire Arrays Grown on Nickel Foam