Citation: LAO Guo-Hong, SHAO Hai-Bo, FAN Yu-Qian, WANG Jian-Ming, ZHANG Jian-Qing, CAO Chu-Nan. Catalytic Oxidation of Sulfide Ion over a Spherular-Co₃O₄ Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 627-632. doi: 10.3866/PKU.WHXB20110240 shu

Catalytic Oxidation of Sulfide Ion over a Spherular-Co₃O₄ Electrode

1.
1. Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China;
2. S. tate Key Laboratory for Corrosion and Protection of Metal, Institute of Metal Research, Chinese Academy of Sciences, Shengyang 110016, P. R. China

Received Date: 13 October 2010
Available Online: 17 January 2011
Fund Project: 浙江省自然科学基金(Y406192) (Y406192)高等学校博士学科点专项科研基金(20070335157)资助项目 (20070335157)

Spherular-Co₃O₄ particles were synthesized on graphite electrode surface by ammonia-evaporation-induction. Its electrooxidation catalytic behavior for sulfide ions in an alkaline solution was investigated by electrochemical measurements such as potentiodynamic scanning and potentiostatic polarization. We found that high catalytic activity and the highest current density of 580 mA·cm^-2 were obtained at -0.40 V. In addition, its catalytic performance was stable during potentiostatic polarization. Electrochemical impedance spectroscopy (EIS) indicated a low charge transfer resistance, which explained the high catalytic activity from the viewpoint of electrochemical kinetics.
- Co₃O₄ electrode,
- Sulfide ion,
- Electrocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Catalytic Oxidation of Sulfide Ion over a Spherular-Co₃O₄ Electrode