Citation: LIU Jia, YANG Hao-Tian, ZHANG Jing-Bo, ZHOU Xiao-Wen, LIN Yuan. Room Temperature Synthesis of Rutile TiO₂ and Its Application in Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 408-412. doi: 10.3866/PKU.WHXB20110237 shu

Room Temperature Synthesis of Rutile TiO₂ and Its Application in Dye-Sensitized Solar Cells

LIU Jia ^1,2 ,
YANG Hao-Tian ^1,2 ,
ZHANG Jing-Bo ¹ ,
ZHOU Xiao-Wen ¹ ,
LIN Yuan ^1,

1.
1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 15 October 2010
Available Online: 12 January 2011
Fund Project: 国家重点基础研究发展规划项目(973) (2006CB202605) (973) (2006CB202605) 国家高技术研究发展规划(863)(2007AA05Z439) (863)(2007AA05Z439)国家自然科学基金(20973183)资助 (20973183)

We prepared rutile TiO₂ powders of od crystallinity by hydrolyzing a Ti(OC4H9)4 precursor at room temperature and by reprecipitation. X-ray diffraction (XRD) revealed that higher acidity, lower temperature, and specific amounts of Cl^- as a medium result in rutile TiO₂. This rutile TiO₂ has an irregular rice-like structure. After adding the P105 (EO₃₇PO₅₆EO₃₇) tri-block copolymer as a structural agent, the rutile TiO₂ aggregated to form rough 350 nm spheres. These rough spheres have a greatly enhanced light harvesting efficiency and improved energy conversion efficiency in dye-sensitized solar cells. This is due to their high light scattering effect and larger surface area (109.5 m²·g^-1). By adding these large rutile spheres at a mass fraction of 25% to the over-layer of a TiO₂ film composed of ~20 nm TiO₂ particles as light scattering centers, the energy conversion efficiency of the dye-sensitized solar cells (DSSC) was 7.27%. This is a 17% increase in conversation efficiency compared with the DSSC based on a TiO₂ photoanode without these rough rutile spheres.
- Dye-sensitized solar cell,
- TiO₂,
- Rutile,
- Scattering layer
1. [1]
  
  (1) Carp, O.; Huisman, C. L.; Reller, A. Prog. Solid State Chem. 2004, 32, 33.
2. [2]
  (2) Linsebigler, A. L.; Lu, G. Q.; Yates, J. T. Chem. Rev. 1995, 95, 735.
3. [3]
  (3) Diebold, U. Surf. Sci. Rep. 2003, 48, 53.
4. [4]
  (4) Cao, Y. Q.; Long, H. J.; Chen, Y. M.; Cao, Y. Acta Phys. -Chim. Sin. 2009, 25, 1088.
5. [5]
  [曹永强, 龙绘锦, 陈咏梅, 曹亚安. 物理化学学报, 2009, 25, 1088.]
6. [6]
  (5) Gribb, A. A.; Banfield, J. F. Am. Mineral. 1997, 82, 717.
7. [7]
  (6) Park, N. G.; van de Lagemaat, J. J. Phys. Chem. B 2000, 104, 8989.
8. [8]
  (7) Eiji, H.; Shinobu, F.; Keita, K.; Hiroaki, I. J. Am. Chem. Soc. 2004, 126, 7790.
9. [9]
  (8) Terabe, K.; Kato, K.; Miyazaki, H.; Yamaguchi, S.; Imai, A.; Iguchi, Y. J. Mater. Sci. 1994, 29, 1617.
10. [10]
  (9) Slunecko, J.; Kosec, M.; Holc, J.; Drazic, G. J. J. Am. Ceram. Soc. 1998, 81, 1121.
11. [11]
  (10) Zhao, W. K.; Fang, Y. L.; Dong, Q. H. Acta Phys. -Chim. Sin. 1998, 14, 424.
12. [12]
  [赵文宽, 方佑龄, 董庆华. 物理化学学报, 1998, 14, 424.]
13. [13]
  (11) Yin, S.; Hasegawa, H.; Sato, T. Chem. Lett. 2002, 15, 564.
14. [14]
  (12) Wang, C. C.; Ying, J. Y. Chem. Mater. 1999, 11, 3113.
15. [15]
  (13) Fang, J. X.; Ding, B. J.; Yang, Z. M. Solid State Phenom. 2007, 121-123, 311.
16. [16]
  (14) Bao, X. W.; Zhang, J. L.; Liang, X. H.; Huang, J. Z., Zhang, L. Z. Acta Phys. -Chim. Sin. 2005, 21, 69.
17. [17]
  [鲍兴旺, 张金龙, 梁学海, 黄家祯, 张利中. 物理化学学报, 2005, 21, 69.]
18. [18]
  (15) Zhao, W. K.; Fang, Y. L. Acta Phys. -Chim. Sin. 2002, 18, 368.
19. [19]
  [赵文宽, 方佑龄. 物理化学学报, 2002, 18, 368.]
20. [20]
  (16) Wu, L. Z.; Zhi, J. F. Acta Phys. -Chim. Sin. 2007, 23, 1173.
21. [21]
  [吴良专, 只金芳. 物理化学学报, 2007, 23, 1173.]
22. [22]
  (17) Sarmimala, H.; Carmen, V.; Rainer, K.; Herman, S.; Andreas, H. Solar Energy Materials & Solar Cells 2006, 90, 1176.
23. [23]
  (18) Liu, J.; Yang, H. T.; Tan, W. W.; Zhou, X. W.; Lin, Y. Electrochim. Acta 2010, 56, 396.
24. [24]
  (19) Zhou, Y. F.; Xiang, W. C.; Chen, S.; Fang, S. B.; Zhou, X. W.; Zhang, J. B.; Lin, Y. Chem. Commun. 2009, No. 26, 3895.
25. [25]
  (20) Xiang, W. C.; Zhou, Y. F.; Yin, X.; Zhou, X. W.; Fang, S. B.; Lin, Y. Electrochim. Acta 2009, 54, 4186.
26. [26]
  (21) Wu, M. M.; Lin, G.; Chen, D. H.; Wang, G. G.; He, D.; Feng, S. H.; Xu, R. R. Chem. Mater. 2002, 14, 1974.
27. [27]
  (22) Cheng, H.; Ma, J.; Zhao, Z.; Qi, L. Chem. Mater. 1995, 7, 663.
28. [28]
  (23) Yin, S.; Hasegawa, H.; Maeda, D.; Ishitsuka, M.; Sato, T. J. Photochem. Photobio. A: Chem. 2004, 163, 1.
29. [29]
  (24) Li, G.; Gray, K. A. Chem. Mater. 2007, 19, 1143.
30. [30]
  (25) Yang, L.; Lin, Y.; Jia, J. J. Power. Sources 2008, 182, 370.
31. [31]
  (26) Soler-Illia, G. J. D. A.; Crepaldi, E. L.; Grosso, D.; Sanchez, C. Curr. Opin. Colloid Interface Sci. 2003, 8, 109.
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Room Temperature Synthesis of Rutile TiO2 and Its Application in Dye-Sensitized Solar Cells

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Room Temperature Synthesis of Rutile TiO₂ and Its Application in Dye-Sensitized Solar Cells