Citation: LI Jin-Hua, LIU Bao-Zhong, HAN Shu-Min, HU Lin, ZHU Xi-Lin, WANG Ming-Zhi. Phase Structure and Hydrogen Storage Properties of LaMg_8.40Ni_2.34 Alloy[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 403-407. doi: 10.3866/PKU.WHXB20110206 shu

Phase Structure and Hydrogen Storage Properties of LaMg_8.40Ni_2.34 Alloy

LI Jin-Hua ¹ ,
LIU Bao-Zhong ^1,3 ,
HAN Shu-Min ^1,2, ,
HU Lin ² ,
ZHU Xi-Lin ² ,
WANG Ming-Zhi ¹

1.
1. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei Province, P. R. China;
2. College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, Hebei Province, P. R. China;
3. School of Material Science and Engineering, Henan Polytechenical University, Jiaozuo 454000, Henan Province, P. R. China

Received Date: 20 October 2010
Available Online: 21 December 2010
Fund Project: 国家高技术研究发展计划(863)(2007AA05Z117) (863)(2007AA05Z117) 国家自然科学基金(50971112, 51001043) (50971112, 51001043) 博士后科学基金(20100470990) (20100470990)河北省自然科学基金(E2010001170)资助项目 (E2010001170)

The LaMg_8.40Ni_2.34 alloy was prepared by vacuum induction melting and subsequent heating treatment. The phase structure, morphology, and hydrogen storage properties were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and pressure-composition-temperature (PCT) measurements. The LaMg_8.40Ni_2.34 alloy was composed of La₂Mg₁₇, LaMg₂Ni, and Mg₂Ni phases. The alloy can be activated in the first hydriding/dehydriding process. Its reversible hydrogen storage capacity was 3.01% (mass fraction) at 558 K. PCT curves showed two hydriding plateaus corresponding to the formation of MgH₂ and Mg₂NiH₄ and only one dehydriding plateau, which is due to the synergetic effect of hydrogen desorption between MgH₂ and Mg₂NiH₄. The activation energy values of LaMg_8.40Ni_2.34 alloy were (52.4±0.4) and (59.2±0.1) kJ·mol^-1 for the hydriding and dehydriding processes, respectively, and these were lower than that of the Mg₂Ni alloy. The LaMg_8.40Ni_2.34 alloy exhibited od activation behavior, hydrogen adsorption and desorption reversibility, and kinetic properties.
- Hydrogen storage material,
- La-Mg-Ni alloy,
- Pressure-composition-temperature curve,
- Multiphase structure
1. [1]
  
  (1) Schlapbach, L.; Zuettel, A. Nature 2001, 414, 353.
2. [2]
  (2) Zhu, M.; Peng, C. H.; Ouyang, L. Z.; Tong, Y. Q. J. Alloys. Compd. 2006, 426, 316.
3. [3]
  (3) Chio, M. D.; Ziggiotti, A.; Baricco, M. Intermetallics 2008, 16, 02.
4. [4]
  (4) Song, X. P.; Zhang, P. L.; Pei, P.; Liu, J.; Li, R. C.; Chen, G. L. Int. J. Hydrog. Energy 2010, 35, 8080.
5. [5]
  (5) Palade, P.; Sartori, S.; Maddalena, A.; Principi, G.; S. Russo, L.; azarescu, M.; Schinteie, G.; Kuncser, V.; Filoti, G. J. Alloys. Compd. 2006, 415, 170.
6. [6]
  (6) Liu, Z. Y.;Wang, E.; Lei, Z. L. J. Alloy. Compd. 2007, 431, 212.
7. [7]
  (7) Muthukumara, P.; Maiya, M. P.; Murthy, S. S.; Vijay, R.; undaresan, R. J. Alloy Compd. 2008, 452, 456.
8. [8]
  (8) Sakintunaa, B.; Lamari-Darkimb, F.; Hirscherc, M. Int. J. Hydrog. Energy 2007, 32, 1121.
9. [9]
  (9) Friedlmeie, R. G.; Arakawa, M.; Hirai, T.; Akiba, E. J. Alloy. Compd. 1999, 292, 101.
10. [10]
  (10) Zhang, Y.; Li, B.; Ren, H.; Guo, S.;Wu, Z.;Wang, X. Int. J. Hydrog. Energy 2009, 34, 2684.
11. [11]
  (11) Li, Q.; Chou, K. C.; Xu, K.; Jiang, L. J.; Lin, Q.; Lin, G.; Lu, X.; Zhang, J. Int. J. Hydrog. Energy 2006, 31, 497.
12. [12]
  (12) Ouyang, L. Z.; Yao, L.; Dong, H.W.; Li, L. Q.; Zhu, M. J. Alloy. Compd. 2009, 485, 507.
13. [13]
  (13) Hu, L.; Han, S. M.; Li, J. H.; Yang, C.; Li, Y.;Wang, M. Z. Mater. Sci. Eng. B 2010, 166, 209.
14. [14]
  (14) Ren, H.; Zhang, Y.; Li, B.; Zhao, D.; Guo, S.;Wang, X. Int. J. Hydrog. Energy 2009, 34, 1429.
15. [15]
  (15) Xie, D. H.; Li, P.; Zeng, C. X.; Sun, J.W.; Qu, X. H. J. Alloy. Compd. 2009, 478, 96.
16. [16]
  (16) Zaluska, A.; Zaluski, L.; Str?m-Olsen, J. O. J. Alloys Compd., 1999, 289, 197.
17. [17]
  (17) Blomqvist, H.; R?nnebro, E.; Noréus, D.; Kuji, T. J. Alloy. Compd. 2002, 330-332, 286.
18. [18]
  (18) Taizhang, D. The Properties and Application on Metal-Hydride. Jap. Pat. ISBN4-900041-72-6, 1999.
19. [19]
  (19) Ouyang, L. Z.; Yang, X. S.; Dong, H.W.; Zhu, M. Scripta Mater. 2009, 61, 339.
20. [20]
  (20) Li, Q.; Chou, K. C.; Lin, Q.; Jiang, L. J.; Zhan, F. Int. J. Hydrog. Energy, 2004, 29, 843.
21. [21]
  (21) Li, Q.; Chou, K. C.; Lin, Q.; Jiang, L. J.; Zhan, F. Int. J. Hydrog. Energy 2004, 29, 1383.
22. [22]
  (22) Cui, X. Y.; Li, Q.; Chou, K. C.; Chen, S. L.; Lin, G.W.; Xu, K. D. Intermetallics 2008, 16, 662.
23. [23]
  (23) Mi, J.; Liu, X. P.; Li, Y.; Jiang, L. J.; Li, Z. N.; Huang, Z.;Wang, S. M. J. Rare Earths 2009, 27, 154.
24. [24]
  (24) Kalinichenka, S.; Rontzsch, L.; Kieback, B. Int. J. Hydrog. Energy 2009, 34, 7749.
25. [25]
  (25) Li, Z. N.; Jiang, L. J.; Liu, X. P.;Wang, S. M.; Li, H. L.; Zhan, F. J. Chin. Rare Earth Soc. 2008, 26, 624.
26. [26]
  [李志念, 蒋利军, 晓鹏, 王树茂, 李华玲, 詹峰. 中国稀土学报, 2008, 26, 24.]
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Phase Structure and Hydrogen Storage Properties of LaMg8.40Ni2.34 Alloy

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通讯作者: 陈斌, bchen63@163.com

Phase Structure and Hydrogen Storage Properties of LaMg_8.40Ni_2.34 Alloy