Citation: PENG Kai-Mei, SHAO Wen-Li, WANG Hua-Hua, YING Xiao, WANG Hui, JI Liang-Nian, LIU Hai-Yang. Effects of Solvents on the Spectral Properties of Gallium Corrole[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 199-206. doi: 10.3866/PKU.WHXB20110129 shu

Effects of Solvents on the Spectral Properties of Gallium Corrole

1.
1. Depatment of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China;
2. State Key Laboratory of Optoelectronics Materials and Technologies, Sun Yat-Sen University, Guangzhou 510275, P. R. China;
3. Department of Applied Physics, South China University of Technology, Guangzhou 510641, P. R. China

Received Date: 20 July 2010
Available Online: 10 December 2010
Fund Project: 国家自然科学基金(20771039, 20871122, 20971046)资助项目 (20771039, 20871122, 20971046)

A series of peripherally substituted free base corroles (1, 2, 3, 4) and their gallium complexes 1-Ga(Py), 2-Ga(Py), 3-Ga(Py), 4-Ga(Py) were synthesized and characterized by proton nuclear magnetic resonance (¹H NMR), UV-visible (UV-Vis) spectroscopy and electrospray ionization mass spectra (ESI-MS). The UV-visible spectra, steady state fluorescence spectra，and time resolved fluorescence spectra of the free base corroles and their gallium complexes were recorded in different solvents. Fluorescence lifetimes were obtained by fitting fluorescence decay kinetics curves using a single exponential simulation. The effects of non or weak polar solvents on the UV spectrum of gallium corrole were fitted to the Bayliss equation and the non-radiative energy loss hc(ν¹_A-ν_F) of gallium corrole and F(n) showed a linear correlation.
- Corrole,
- Gallium,
- Florescence,
- Solvent effect
1. [1]
  
  1 Gross, Z.; Galili, N.; Saltsman, I. Angew. Chem., Int. Edit., 1999, 38: 1427
2. [2]
  2 Paolesse, R.; Jaquinod, L.; Nurco, D. J.; Mini, S.; Sa ne, F.; Boschi, T.; Smith, K. M. Chem. Commun., 1999, 999: 1307
3. [3]
  3 Gross, Z.; Gray, H. B. Adv. Synth. Catal., 2004, 346: 165
4. [4]
  4 Mahammed, A.; Gross, Z. Angew. Chem, Int. Edit., 2006, 45: 6544
5. [5]
  5 Liu, H. Y.; Yam, F.; Xie, Y. T.; Li, X. Y.; Chang, C. K. J. Am. Chem. Soc., 2009, 131: 12890
6. [6]
  6 Kowalska, D.; Liu, X.; Tripathy, U.; Mahammed, A.; Gross, Z.; Hirayama, S.; Steer, R. P. Inorg. Chem., 2009, 48: 2670
7. [7]
  7 Simkhovich, L.; ldberg, I.; Gross, Z. J. Inorg. Biochem., 2000, 80: 235
8. [8]
  8 Bendix, J.; Dmochowski, I. J.; Gray, H. B.; Mahammed, A.; Simkhovich, L.; Gross, Z. Angew. Chem. Int. Edit., 2000, 39: 4048
9. [9]
  9 Liu, X.; Mahammed, A.; Tripathy, U.; Gross, Z.; Steer, R. P. Chem. Phys. Lett., 2008, 459: 113
10. [10]
  10 Ventura, B.; Esposti, A. D.; Koszarna, B.; Gryko, D. T.; Flamigni, L. New J. Chem., 2005, 29: 1557
11. [11]
  11 Saltman, I.; Mahammed, A.; ldberg, I.; Tkachenko, E.; Botoshansky, M.; Gross, Z. J. Am. Chem. Soc., 2002, 124: 7411
12. [12]
  12 Tripathy, U.; Steer, R. P. J. Porphyrins Phthalocyanines, 2007, 11: 228
13. [13]
  13 Aviv, I.; Gross, Z. Chem. Commun., 2007: 1987
14. [14]
  14 Agadjanian, H.; Ma, J.; Rentsendorj, A.; Valluripalli, V. ; Hwang, Y. J.; Mahammed, A. ; Farkas, D. L.; Gray, H. B. ; Gross, Z.; Medina-Kauwe, L. K. Proceedings of the National Academy of Sciences, 2009, 106: 6105
15. [15]
  15 Mahammed, A.; Gross, Z. Dalton Trans., 2010, 39: 2998
16. [16]
  16 Nardis, S.; Monti, D.; Paolesse, R. Mini-Rev. Org. Chem., 2005, 2: 355
17. [17]
  17 Lian, P.; Liu, H. Y.; Chen, L.; Yam, F.; Chang, C. K. Chinese Journal of Inorganic Chemistry, 2009, 25: 1420
18. [18]
  [练萍, 刘海洋, 陈玲, 任飞, 张启光. 无机化学学报, 2009, 25: 1420]
19. [19]
  18 Jin, Z. P.; Peng, X. J.; Sun, L. C. Chemistry Online, 2003, 7: 464
20. [20]
  [金志平, 彭孝军, 孙立成. 化学通报, 2003, 7: 464]
21. [21]
  19 Hu, Z. Z.; Yang, S. J.; Lu, J. L. Journal of Hubei University, 1994, 14: 90
22. [22]
  [胡珍珠, 杨水金, 陆江林. 湖北学院学报, 1994, 14: 90]
23. [23]
  20 Strat, G.; Strat, M.; Grecu, I. Spectros. Lett., 1994, 27: 177
24. [24]
  21 Bayliss, N. S. J. Chem. Phys., 1950, 18: 292
25. [25]
  22 Smith, K. M.; Porphyrins and metalloporphyrins. New York: Elserier, 1975: 667-700
26. [26]
  23 Gao, F.; Pu, B. S. Chemical Reagents, 1988, 10: 328
27. [27]
  [高福, 蒲宝珊. 化学试剂, 1988, 10: 328]
28. [28]
  24 Ghosh, A.; Jynge, K. Chem. Eur. J., 1997, 3: 823
29. [29]
  25 Liu,W. Y.; Zhang, F. S.; Tang, Y.W.; Song, X. Q. Acta Phys. -Chim. Sin., 1986, 1: 12
30. [30]
  [刘文渊, 张复实, 唐应武, 宋心琦. 物理化学学报, 1986, 1: 12]
31. [31]
  26 Haber, A.; Agadjanian, H.; Medina-Kauwe, L. K.; Gross, Z. J. Inorg. Biochem., 2008, 102: 446
32. [32]
  27 Kowalska, D.; Liu, X.; Tripathy, U.; Maham med, A.; Gross, Z.; Hirayama, S.; Steer R. P. Inorg. Chem., 2009, 48: 2670
33. [33]
  28 Prochorow, J.; Deperasinska, I.; Dresner, J.; Sobolewski, A. J. Mol. Struct., 1978, 45: 471
34. [34]
  29 Reiser, A.; Leyshon, L. J. J. Chem. Phys., 1972, 56: 1011
35. [35]
  30 Mahammed, A.; Gross, Z. J. Inorg. Biochem., 2002, 88: 305
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