Citation: WANG Zhi-Jun, YANG Zhi-Ping, GUO Qing-Lin, LI Pan-Lai. Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3317-3321. doi: 10.3866/PKU.WHXB20101226 shu

Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor

1.
College of Physics Science & Technology, Hebei University, Baoding 071002, Hebei Province, P. R China

Received Date: 2 August 2010
Available Online: 10 November 2010
Fund Project: 国家自然科学基金(50902042) (50902042) 河北省自然科学基金(E2009000209, E2010000283) (E2009000209, E2010000283) 河北省教育厅基金(2009313) (2009313)发光与光信息技术教育部重点实验室研究基金(2010LOI12)资助项目 (2010LOI12)

We synthesized a kind of green phosphor, NaBaPOM₄:Tb³⁺, by the high temperature solid-state method, and investigated its luminescent characteristics. NaBaPO₄:Tb³⁺ has several emission peaks, and these are located at 437, 490, 543, 587, and 624 nm, which correspond to the ⁵D₃→⁷D₄ and ⁵D₄→⁷F_{J=6. 5, 4, 3} transitions of Tb³⁺, respectively. The main peak is at 543 nm. The excitation spectrum (monitored at an emission wavelength of 543 nm) consists of several bands, and the main peak is located at 380 nm. The effect of amount of Tb³⁺ doping content, the compensators (Li⁺, Na⁺, K⁺, or Cl^-), and the sensitizer activator Ce³⁺ on the emission intensity of the NaBaPOM₄:Tb³⁺ phosphor were also studied. The results show that the emission intensity can be controlled by the above factors, and the intensity can be enhanced by selecting the prime optimum conditions.
- Luminescent characteristics,
- NaBaPOM₄：Tb³⁺,
- Green phosphor
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沈阳化工大学材料科学与工程学院沈阳 110142

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Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor