Citation: LONG Jun-Ying, MA Lan, HE De-Hua. 1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts[J]. Acta Physico-Chimica Sinica, ;2010, 26(10): 2719-2725. doi: 10.3866/PKU.WHXB20101022 shu

1-Octene Hydroformylation Using Supported Amorphous Co-B Catalysts

LONG Jun-Ying ¹ ,
MA Lan ^1,2 ,
HE De-Hua ^1,

1.
1. Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;
2. Institute of Chemical Defence, Beijing 102205, P. R. China

Received Date: 26 April 2010
Available Online: 27 September 2010
Fund Project: 国家自然科学基金(20921001)资助项目 (20921001)

Co-B catalysts supported on ZrO₂ (prepared by alcogel nitrogen thermo-treatment method), carbon nanotubes (CNTs), and mesoporous SBA-15 as supports were prepared by chemical reduction method and characterized by X-ray diffraction (XRD), nitrogen physisorption, transmission electron microscopy (TEM), inductively coupled plasma -atomic emission spectrometry (ICP-AES) and X-ray photoelectron spectroscopy (XPS). Hydroformylation of 1-octene was used as a probe reaction to investigate the catalytic performance and stability of the catalysts in recycles. The as-prepared Co-B catalysts showed amorphous characteristics and the support structures were unchanged. The reaction results reveal that the catalytic activities of Co-B/CNTs, Co-B/ZrO₂ and Co-B/SBA-15 in the hydroformylation of 1-octene were comparatively high. However, the catalytic activities decreased upon recycling. Nevertheless, the Co-B/ CNTs and Co-B/SBA-15 were relatively stable compared with Co-B/ZrO₂.
- Amorphous Co-B catalyst,
- Support,
- Hydroformylation,
- Catalytic property
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