Citation: ZHOU Yan-Li, ZHI Jin-Fang, ZHANG Xiang-Fei, XU Mao-Tian. Comparative Study of Electrochemical Performances of Three Carbon-Based ElectrodeMaterials[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2405-2409. doi: 10.3866/PKU.WHXB20100841 shu

Comparative Study of Electrochemical Performances of Three Carbon-Based ElectrodeMaterials

1.
1. Department of Chemistry, Shangqiu Normal University, Shangqiu 476000, Henan Province, P. R. China;
2. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 18 April 2010
Available Online: 2 July 2010
Fund Project: 国家自然科学基金(20775047) (20775047)河南省科技厅国际合作项目基金(084300510075) (084300510075)商丘师范学院青年基金(009QN08)资助 (009QN08)

The electrochemical properties of three carbon-based electrodes including boron-doped nanocrystalline diamond (BDND), boron-doped microcrystalline diamond (BDMD), and glassy carbon (GC) were compared. We used scanning electron microscopy to characterize the two diamond electrodes and the grain sizes of the BDMD and BDND films were 1-5 μm and 20-100 nm, respectively. The phase composition was characterized by Raman spectroscopy and high-quality BDMD and BDND films were formed by hot-filament chemical vapor deposition. Cyclic votammograms for 0.5 mol·L^-1 H₂SO₄ showed that the potential windows for the BDND and BDMD electrodes were 3.3 and 3.0 V, respectively. The potential windows were much wider than that of the GC electrode (2.5 V). The cyclic voltammograms and Nyquist plots of the impedance measurements for [Fe(CN)₆]³-/[Fe(CN)₆]⁴- show peak to peak separations (ΔE_p) of 73, 92, and 112 mV and electron transfer resistances (R_et) of (98依5), (260依19), and (400依25) Ωfor the BDND, BDMD, and GC electrodes, respectively. We also investigated the oxidation of 0.1 mmol·L-1 bisphenol A (BPA) on the three carbon-based electrodes. The above-mentioned electrochemical results reveal that the two diamond electrodes have wider potential windows, better reversibility, faster electron transfer, and higher stability than the GC electrode. Additionally, the BDND electrode shows better electrochemical properties than the BDMD electrode.
- Electrochemical property,
- Boron-doped nanocrystalline diamond,
- Boron-doped microcrystalline diamond,
- Glassy carbon,
- Electrode
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