Citation: LI Ya-Juan, ZHAN Hui, LIU Su-Qin, HUANG Ke-Long, ZHOU Yun-Hong. Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2387-2391. doi: 10.3866/PKU.WHXB20100818 shu

Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte

1.
1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China

Received Date: 15 January 2010
Available Online: 23 June 2010
Fund Project: 中国博士后基金(20080440989) (20080440989)高等学校博士学科点专项科研基金(20090162120011)资助项目 (20090162120011)

We prepared nanosized hydroxide magnesium (Mg(OH)₂) as a plasticizer and a flame-retarding additive for a poly(ethylene-oxide) (PEO) based polymer electrolyte. We characterized the prepared compound using transition electron microscopy (TEM), X-ray diffraction (XRD), and thermogravimetry (TG). The prepared hydroxide magnesium particles are hexa nal crystals with sizes of 50-80 nm. The decomposition of the prepared nanosized hydroxide magnesium started at 340 ℃. Electrochemical measurements shows that the ionic conductivity of the Mg(OH)₂/PEO composite polymer electrolytes (CPEs) increases initially and then decreases with an increase in hydroxide magnesium content. It reaches a maximum when the hydroxide magnesium mass fraction is between 5% and 10%. The anodic decomposition potential of the CPEs increases to a certain extent as the hydroxide magnesium content increases. Hydroxide magnesiumhas a positive influence on the electrochemical stability of PEO.
- Lithiumion battery,
- Nanosized hydroxide magnesium,
- Flame-retarding,
- Poly(ethylene-oxide),
- Polymer electrolyte
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