Citation: LIU Shu-Ping, YUE Ming-Bo, WANG Yi-Meng. One-Step Synthesis of Mesoporous Beta Zeolite Using Phosphate[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2224-2228. doi: 10.3866/PKU.WHXB20100806 shu

One-Step Synthesis of Mesoporous Beta Zeolite Using Phosphate

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062, P. R. China

Received Date: 7 January 2010
Available Online: 9 June 2010
Fund Project: 国家自然科学基金(20873042, 20890122)资助项目 (20873042, 20890122)

The addition of sodium phosphate monobasic (NaH₂PO₄) to a synthetic mixture allows a one-step synthesis of mesoporous Beta zeolite. Aggregation of the nanosized Beta zeolites allows the filtration difficulties to be overcome while the intercrystalline mesopores reduce the diffusion limitation and thus enhance the catalytic activity. The obtained Beta zeolite samples were characterized by X-ray diffraction, scanning electron microscopy, N₂ adsorption-desorption, and temperature-programmed desorption of ammonia. The amount of phosphate strongly influenced the mesopore volume of the Beta zeolites. When the molar ratio of NaH₂PO₄/SiO₂ was 0.1, the sample had od textural and acidic properties and exhibited the best catalytic activity for the alkylation of phenol with tert-butanol.
- Hydrothermal synthesis,
- Beta zeolite,
- Mesoporous,
- Alkylation,
- Phosphate
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