Citation: YANG Wei-Ben, REN Li. Adsorption Mechanism of Nonylphenol Polyethoxylate onto Hypercrosslinked Resins[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2182-2188. doi: 10.3866/PKU.WHXB20100805 shu

Adsorption Mechanism of Nonylphenol Polyethoxylate onto Hypercrosslinked Resins

YANG Wei-Ben ,
REN Li

1.
College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210097, P. R. China

Received Date: 22 February 2010
Available Online: 7 June 2010
Fund Project: 国家自然科学基金(50978137) (50978137)江苏省自然科学基金(BK2008436)资助项目 (BK2008436)

The aim of this study was to determine the behaviors and mechanism of three hypercrosslinked polymers during the adsorption of nonylphenol ethoxylated decylether (NPEO-10) from aqueous solutions. The polymers were characterized to determine their specific surface areas, pore sizes, and elemental contents. The adsorption isotherms of NPEO-10 on the three polymers fit the Langmuir and double Langmuir models better than the Freundlich model, and the isotherm curves had similar shapes on a lg-lg scale. The amount of adsorbed NPEO-10 depends on the specific surface area, the pore size of the polymer, and the temperature of the solution. Thermodynamic analysis indicated that the adsorption process was characterized by an interaction of the hydrophobic part of the surfactant molecule with the surface of the polymer and by the formation of micelle-like aggregates on the surface of the polymer. A two-dimensional mixture consists of singly dispersed surfactant molecules and monolayered or bi-layered aggregates on the surface of the polymers. Adsorption dynamics confirmed that the adsorption process involved two plateaus which were related to the formation of a monolayer and a bi-layer. Finally, the elution processes were investigated to further establish the appropriate adsorption conditions for the purification of water containing NPEO-10.
- Elution,
- Nonylphenol polyethoxylate,
- Isotherm,
- Resin,
- Temperature
1. [1]
  
  [1]. Hou, S. G.; Sun, H. W.; Gao, Y. Chemosphere, 2006, 63: 31
2. [2]
  [2]. Gioiaa, D. D.; Sciubbaa, L.; Bertina, L. Water Res., 2009, 43: 2977
3. [3]
  [3]. Hu, J. Y.; Chen, X.; Tao, G. Environ. Sci. Technol., 2007, 41: 4097
4. [4]
  [4]. Ike, M.; Asano, M.; Belkada, F. D. Water Sci. Technol., 2002, 46: 127
5. [5]
  [5]. John, D. M.; House, W. A.; White, G. F. Environ. Toxicol. Chem., 2000, 19: 293
6. [6]
  [6]. Misra, K. P.; Dash, U.; Somasundaran, P. Ind. Eng. Chem. Res., 2009, 48: 3403
7. [7]
  [7]. Caruso, F.; Serizawa, T.; Furlong, D. N. Langmuir, 1995, 11: 1546
8. [8]
  [8]. Espantaleón, A. G.; Nieto, J. A.; Fernández, M. Appl. Clay Sci., 2003, 24: 105
9. [9]
  [9]. Nevskaia, D. M.; Sepulveda-Escribano, A.; Guerrero-Ruiz, A. Phys. Chem. Chem. Phys., 2001, 3: 463
10. [10]
  [10]. Streat, M.; Sweetland, L. A. React. Funct. Polym., 1997, 35: 99
11. [11]
  [11]. Penner, N. A.; Nesterenko, P. N. J. Chromatogr. A, 2000, 884: 41
12. [12]
  [12]. Valderrama, C.; Cortina, J. L.; Farran, A. J. Colloid Interface Sci., 2007, 310: 35
13. [13]
  [13]. Tsyurupa, M. P.; Davankov, V. A. React. Funct. Polym., 2002, 53: 193
14. [14]
  [14]. Ahn, J. H.; Jang, J. E.; Oh, C. G. Macromolecules, 2006, 39: 627
15. [15]
  [15]. Yang, W. B.; Li, A. M.; Fan, J. Chemosphere, 2006, 64: 984
16. [16]
  [16]. Valderrama, C.; Gamisans, X.; de las Heras, F. X. React. Funct. Polym., 2007, 67: 1515
17. [17]
  [17]. Streat, M.; Sweetland, L. A. Trans IChemE B, 1998, 76: 115
18. [18]
  [18]. Per, W.; Bengt, J. Langmuir, 1994, 10: 3268
19. [19]
  [19]. Misra, P. K.; Mishra, B. K.; Somasunduran, P. J. Colloid Interface Sci., 2003, 265: 1
20. [20]
  [20]. Shalaby, M. N. Polym. Adv. Technol., 2004, 15: 533
21. [21]
  [21]. Marcel, R. B.; Luuk, K. K. Langmuir, 1992, 8: 2649
22. [22]
  [22]. Li, B. Q.; Eli, R. Langmuir, 1996, 12: 5052
23. [23]
  [23]. nzález-García, C. M.; nzález-Martín, M. L.; Gómez-Serrano, V.; Bruque, J. M.; Labajos-Broncano, L. Langmuir, 2000, 16: 3950
24. [24]
  [24]. Drach, M.; Narkiewicz-Michaek, J.; Rudziński, W. Phys. Chem. Chem. Phys., 2002, 4: 2307
25. [25]
  [25]. Calvoa, E.; Bravoa, R.; Ami a, A. Fluid Phase Equilib., 2009, 282: 14
26. [26]
  [26]. Zhang, R.; Somasundaran, P. Langmuir, 2004, 20: 8552
27. [27]
  [27]. Edwards, D. A.; Adeel, Z.; Luthy, R. G. Environ. Sci. Technol., 1994, 28: 1550
28. [28]
  [28]. Adeel, Z.; Luthy, R. G. Environ. Sci. Technol., 1995, 29: 1032
29. [29]
  [29]. Paria, S.; Yuet, P. K. Ind. Eng. Chem. Res., 2007, 46: 108
30. [30]
  [30]. Liu, Y. J. Chem. Eng. Data, 2009, 54: 1981
31. [31]
  [31]. Urbina-Villalba, G.; Reif, I.; Márquez, M. L. Colloids Surf. A, 1995, 99: 207
32. [32]
  [32]. Levitz, P. E. C. R. Geoscience, 2002, 334: 665
33. [33]
  [33]. Muller, N. Langmuir, 1993, 9: 96
34. [34]
  [34]. Kibbey, T. C. G.; Hayes, K. Environ. Sci. Technol., 1997, 31: 1171
35. [35]
  [35]. Wesemeyer, H.; Muller, B. W.; Muller, R. H. Int. J. Pharm., 1993, 89: 33
36. [36]
  [36]. Ghiaci, M.; Kalbasi, R. J.; Abbaspour, A. Colloids Surf. A, 2007, 297: 105
37. [37]
  [37]. Lindheimer, M.; Keh, E.; Zaini, S.; Partyka, S. J. Colloid Interface Sci., 1990, 138: 83
38. [38]
  [38]. Winnik, M. A.; Bystryak, S. M.; Odrobina, E. Langmuir, 2000, 16: 6118
39. [39]
  [39]. Mishra, S. K.; Kanun , S. B.; Rajeev. J. Colloid Interface Sci., 2003, 267: 42
40. [40]
  [40]. Gallardo-Moreno, A. M.; nzález-García, C. M.; nzález- Martín, M. L.; Bruque, J. M. Colloids Surf. A, 2004, 249: 57
1. [1]
  Xia Shu , Longtian Sima , Jiali Wang , Jiacheng Chu , Xieyidai·Yusunjiang , Mubareke·Maimaitijiang , Yingwei Lu , Yan Wang . Analysis of the Report Generated by the QuadraSorb evo BET Surface Area Analyzer. University Chemistry, 2025, 40(5): 391-400. doi: 10.12461/PKU.DXHX202411013
2. [2]
  Wanchun Zhu , Yongmei Liu , Li Wang , Yunshan Bai , Shu'e Song , Xiaokui Wang , Zhongyun Wu , Hong Yuan , Yunchao Li , Fuping Tian , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement and Control of Temperature. University Chemistry, 2025, 40(5): 128-136. doi: 10.12461/PKU.DXHX202503028
3. [3]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
4. [4]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
5. [5]
  Mingxin LU , Liyang ZHOU , Xiaoyu XU , Xiaoying FENG , Hui WANG , Bin YAN , Jie XU , Chao CHEN , Hui MEI , Feng GAO . Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 329-338. doi: 10.11862/CJIC.20240206
6. [6]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
7. [7]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
8. [8]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
9. [9]
  Hongxia Yan , Rui Wu , Weixu Feng , Yan Zhao , Yi Yan . Innovation Inspired by Classical Chemistry: Luminescent Hyperbranched Polysiloxanes. University Chemistry, 2025, 40(4): 154-159. doi: 10.12461/PKU.DXHX202409010
10. [10]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
11. [11]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
12. [12]
  Liangyu Gong , Jie Wang , Fengyu Du , Lubin Xu , Chuanli Ma , Shihai Yan , Zhuwei Song , Fuheng Liu , Xiuzhong Wang . Construction and Practice of “One-Point, Two-Lines and Three-Sides” Innovative Experimental Platform. University Chemistry, 2024, 39(4): 26-32. doi: 10.3866/PKU.DXHX202308023
13. [13]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
14. [14]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362
15. [15]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
16. [16]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
17. [17]
  Yongqing Kuang , Jie Liu , Jianjun Feng , Wen Yang , Shuanglian Cai , Ling Shi . Experimental Design for the Two-Step Synthesis of Paracetamol from 4-Hydroxyacetophenone. University Chemistry, 2024, 39(8): 331-337. doi: 10.12461/PKU.DXHX202403012
18. [18]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
19. [19]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
20. [20]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110

Get Citation

PDF

XML

Metrics

PDF Downloads(1157)
Abstract views(2716)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142