Citation: CHE Hong-Wei, HAN Shu-Hua, HOU Wan-Guo, LIU Ai-Feng. Novel Synthesis of Mesoporous Nanocrystalline Zirconia[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2177-2181. doi: 10.3866/PKU.WHXB20100803 shu

Novel Synthesis of Mesoporous Nanocrystalline Zirconia

1.
1. Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China;
2. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong Province, P. R. China

Received Date: 26 March 2010
Available Online: 25 May 2010
Fund Project: 国家自然科学基金(50572057)资助项目 (50572057)

A novel strategy involving the combination of soft-templating and the solid-liquid method (CSSL) is presented for the synthesis of mesoporous nanocrystalline zirconia with a high specific surface area. The mesostructured zirconia hybrid is firstly synthesized by the soft-templating method using 1-hexadecyl-3-methylimidazolium bromide (C₁₆mim⁺Br^-) as the structure-directing agent and zirconium sulphate as an inorganic precursor. It is then ground in the presence of solid copper nitrate followed by heat-treatment in air. The resulting zirconia material, after calcination at 600 ℃, possesses a wormlike arrangement of mesopores surrounded by tetra nal ZrO₂ nanocrystallites of ca 2.50 nm diameter. The Brunauer-Emmett-Teller (BET) surface area is 240.0 m²·g^-1 and the pore size is 4.10 nm. However, no mesoporous structure exists in the obtained zirconia material that was produced using the simple soft-templating method at the same calcination temperature. The BET surface area is only 9.5 m²·g^-1 for this material.
- Mesoporous,
- Zirconia,
- Nanocrystalline,
- Soft-templating method,
- Thermal stability
1. [1]
  
  [1]. Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature, 1992, 359: 710
2. [2]
  [2]. Yu, J. M.; Yu, J. G.; Ho, W. K.; Jiang, Z. T.; Zhang, L. Z. Chem. Mater., 2002, 14: 3808
3. [3]
  [3]. Liu, R. L.; Ren, Y. J.; Shi, Y. F.; Zhang, F.; Zhang, L. J.; Tu, B.; Zhao, D. Y. Chem. Mater., 2008, 20: 1140
4. [4]
  [4]. Yuan, Q.; Yin, A. X.; Luo, C.; Sun, L. D.; Zhang, Y. W.; Duan, W. T.; Liu, H. C.; Yan, C. H. J. Am. Chem. Soc., 2008, 130: 3465
5. [5]
  [5]. Wang, T.; Zhou, J, H.; Wang, D. J.; Sun, D.; Di, Z. Y.; He, J. P. Acta Phys. -Chim. Sin., 2009, 25:2155. [王涛, 周建华, 王道军, 孙盾, 狄志勇, 何建平. 物理化学学报, 2009, 25: 2155]
6. [6]
  [6]. Fang, X. S.; Zhang, L. D. J. Mater. Sci. Technol., 2006, 22: 1
7. [7]
  [7]. Che, H. W.; Han, S. H.; Hou, W. G.; Liu, A. F.; Yu, X. J.; Sun, Y. Y.; Wang, S. S. Microporous Mesoporous Mat., 2010, 130: 1
8. [8]
  [8]. Liu, X. L.; He, J. P.; Dang, W. J.; Ji, Y. J.; Zhao, G. W.; Zhang, C. X. Acta Phys. -Chim. Sin., 2008, 24:475. [刘晓磊, 何建平, 党王娟, 计亚军, 赵桂网, 张传香, 物理化学学报, 2008, 24: 475]
9. [9]
  [9]. Yu, Y.; Liu, S. J.; Li, J.; Chen, Q. Y. Acta Phys. -Chim. Sin., 2009, 25:1890. [余勇, 刘士军, 李洁, 陈启元, 物理化学学报, 2009, 25: 1890]
10. [10]
  [10]. Yuan, J. Q.; Zhang, Y. Z.; Le, J.; Song, L. X.; Hu. X. F. Mater. Lett., 2007, 61: 1114
11. [11]
  [11]. Fang, X. S.; Bando, Y.; Gautam, U. K.; Ye, C. H.; lberg, D. J. Mater. Chem., 2008, 18: 509
12. [12]
  [12]. Ji, P. F.; Zhang, J. L.; Chen, F.; Anpo, M. J. Phys. Chem. C, 2008, 112: 17809
13. [13]
  [13]. Wan, Y.; Yang, H. F.; Zhao, D. Y. Acc. Chem. Res., 2006, 39: 423
14. [14]
  [14]. Olson, Y. T.; Zhang, J. Z. J. Mater. Sci. Technol., 2008, 24: 433
15. [15]
  [15]. Biswas, K.; Varghese, N.; Rao. C. N. R. J. Mater. Sci. Technol., 2008, 24: 615
16. [16]
  [16]. Shen, W. H.; Shi, J. L.; Chen, H. R.; Gu, J. L.; Zhu, Y. F.; Dong, X. P. Chem. Lett., 2005, 34: 390
17. [17]
  [17]. Wang, Y. Q.; Yang, C. M.; Schmidt, W.; Spliethoff, B.; Bill, E.; Schuth, F. Adv. Mater., 2005, 17: 53
18. [18]
  [18]. Lai, X.; Li, X.; Geng, W.; Tu, J.; Li, J.; Qiu, S. Angew. Chem. Int. Edit., 2007, 46: 738
19. [19]
  [19]. Seddon, K. R.; Stark, A.; Torres, M. Pure Appl. Chem., 2000, 72: 2275
20. [20]
  [20]. Kang, M.; Kim, D.; Yi, S. H.; Han, J. U.; Yie, J. E.; Kim, J. M. Catal. Today, 2004, 93-95: 695
21. [21]
  [21]. Jiao, F.; Hill, A. H.; Harrison, A.; Berko, A.; Chadwick, A. V.; Bruce, P. G. J. Am. Chem. Soc., 2008, 130: 5262
22. [22]
  [22]. Xie, Y. C.; Tang, Y. Q. Adv. Catal., 1990, 37: 1
1. [1]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
2. [2]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
3. [3]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
4. [4]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
5. [5]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
6. [6]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
7. [7]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
8. [8]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
9. [9]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
10. [10]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
11. [11]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN modified PP separator for high-stability and high-efficiency lithium-sulfur batteries. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-. doi: 10.1016/j.actphy.2025.100082
12. [12]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
13. [13]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
14. [14]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
15. [15]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
16. [16]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
17. [17]
  Jie WU , Zhihong LUO , Xiaoli CHEN , Fangfang XIONG , Li CHEN , Biao ZHANG , Bin SHI , Quansheng OUYANG , Jiaojing SHAO . Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 948-958. doi: 10.11862/CJIC.20240400
18. [18]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
19. [19]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
20. [20]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101

Get Citation

PDF

XML

Metrics

PDF Downloads(1366)
Abstract views(3377)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142