Advanced Search

Citation: SONG Hua, DONG Peng-Fei, ZHANG Xu. Effect of Al Content on the n-Pentane Isomerization of the Solid Superacid Pt-SO2-4 /ZrO2-Al2O3[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2229-2234. doi: 10.3866/PKU.WHXB20100640 shu

Effect of Al Content on the n-Pentane Isomerization of the Solid Superacid Pt-SO2-4 /ZrO2-Al2O3

  • 1.

    1. College of Chemistry and Chemical Engineering, Daqing Petroleum Institute, Daqing 163318, Heilongjing Province, P. R. China;
    2. Heilongjiang Provincial Key Laboratory of Chemical Engineering of Oil and Gas, Daqing Petroleum Institute, Daqing 163318, Heilongjiang Province, P. R. China

  • Received Date: 23 December 2009
    Available Online: 13 May 2010

    Fund Project: 中国石油天然气股份有限公司科技风险创新基金(07-06D-01-04-03-02)资助项目 (07-06D-01-04-03-02)

  • Highly active and stable Pt-SO2-4 /ZrO2-Al2O3 solid superacid catalysts were prepared by simultaneously introducing appropriate amounts of Pt and Al2O3 into a SO2-4 /ZrO2 catalyst. The effect of Al content on the performance of the catalysts was studied using n-pentane isomerization as a probe reaction and the catalysts were characterized by X-ray diffraction (XRD), specific surface area measurements (BET), infrared (IR) spectroscopy, temperature-programmed reduction (TPR), thermogravimetry-differential thermal analysis (TG-DTA), and NH3 temperature-programmed desorption (NH3-TPD). The results show that Al can increase the crystallization temperature of ZrO2 and inhibit the decomposition of sulfur. Al can also increase the surface area of the catalyst, strengthen the combination between S and O, improve the redox performance of the catalyst and increase the acid strength and the acidity of the catalyst. The catalytic activity of the Pt-SO2-4 /ZrO2-Al2O3 solid superacid catalyst with a Al2O3 mass fraction of 5.0% was found to be the best. The isopentane yield was stable above 52.0% and the selectivity was higher than 98.2% within 100 h.

  • 加载中
    1. [1]

      [1]. Jin, T. S.; Yang, M. N.; Feng, G. L.; Li, T. S. Chin. J. Org. Chem., 2003, 23:1438. [靳通收, 杨米娜, 冯国良, 李同双. 有机化学, 2003, 23: 1438]

    2. [2]

      [2]. Reddy, B. M.; Sreekanth, P. M.; Lakshmanan, A. J. Mol. Catal. A- Chem., 2005, 237: 93.

    3. [3]

      [3]. Akira, N.; Hiromi, O.; Yoshikazu, K.; Kiyoshi, O. Catal. Commun., 2005, 6 : 716

    4. [4]

      [4]. Gao, Z.; Hua, W. M.; Chen, J. M.; Tang, Y. Acta Phys. -Chim. Sin., 1994, 10:897. [高 滋, 华伟明, 陈建民, 唐 颐. 物理化学学报, 1994, 10: 897]

    5. [5]

      [5]. Pan, H. H.; He, M. Y. Chin. J. Catal., 2005, 26:1067. [潘晖华, 何鸣元. 催化学报, 2005, 26: 1067]

    6. [6]

      [6]. Yao, R. P.; Zhang, M. J.; Yang, J.; Yi, D. L.; Xu, J.; Deng, F.; Yue, Y.; Ye, C. H. Acta Chim. Sin., 2005, 63:269. [姚瑞平, 张铭金, 杨 俊, 易德莲, 徐 君, 邓 风, 岳 勇, 叶朝辉. 化学学报, 2005, 63: 269]

    7. [7]

      [7]. Jin, T.; Yamaguchi, T.; Tanabe, K. J. Phys. Chem., 1986, 90: 4794

    8. [8]

      [8]. Vijay, S.; Wolf, E. E.; Miller, J. T.; Kropf, A. J. Appl. Catal. A, 2004, 264: 125

    9. [9]

      [9]. Strohmeier, B. R.; Levden, D. E.; Hercules, D. M. J. Catal., 1985, 94: 514

    10. [10]

      [10]. Abrahams, I.; Bush, A. J.; Chan, S. C. M. Krok, F.; Wrobel, W. J. Mater. Chem., 2001, 11: 1715

    11. [11]

      [11]. Formasiero, P.; Monte, R. D.; Rao, G. J. Catal., 1995, 151: 165

    12. [12]

      [12]. Zhou, R. X.; Chen, P.; Zheng, X. M.; Chen, L. S. Acta Phys. -Chim. Sin., 1996, 12:464. [周仁贤, 陈 平, 郑小明, 陈林深. 物理化学学报, 1996, 12: 464]

    13. [13]

      [13]. Zhou, R. X.; Zheng, X. M. Acta Phys. -Chim. Sin., 1995, 11: 315[周仁贤, 郑小明. 物理化学学报, 1995, 11: 315]

    14. [14]

      [14]. Wei, W. G; Jung, H. W.; Chang, L.; Che, N.; Nan, P. X.; Chung, Y. Catal. Today, 2004, 97: 307

    15. [15]

      [15]. Zhou, X. L.; Yu, G. X.; Jin, Y. Q. J. East Chin. Univ. Sci. Technol., 2007, 33:309. [周晓龙, 余国贤, 金亚清. 华东理工大学学报, 2007, 33: 309 ]

    16. [16]

      [16]. Xia, Y. D.; Hua, W. M.; Gao, Z. Acta Chim. Sin., 1999, 57:1325. [夏勇德, 华伟明, 高 滋. 化学学报, 1999, 57: 1325] 2229


  • 加载中
    1. [1]

      Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V2O5/TiO2 catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

    2. [2]

      Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036

    3. [3]

      Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

    4. [4]

      Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003

    5. [5]

      Hao Wu ,  Zhen Liu ,  Dachang Bai . 1H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020

    6. [6]

      Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386

    7. [7]

      Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H2O2 by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001

    8. [8]

      Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

    9. [9]

      Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO2 Methanation of Derived Ni-Al2O3 Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002

    10. [10]

      Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Ptδ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H2O2生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081

    11. [11]

      Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054

    12. [12]

      Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

    13. [13]

      Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102

    14. [14]

      Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C3N4 Photocatalyst for Highly-Efficient H2O2 Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005

    15. [15]

      Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO2 Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005

    16. [16]

      Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO2 over Au/Co3O4-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005

    17. [17]

      Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

    18. [18]

      Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO2 nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219

    19. [19]

      Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO2 Reduction to C2 Products and Superior Rechargeable Zn-CO2 Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027

    20. [20]

      Xiaofang Li , Zhigang Wang . 调节金助催化剂的dz2占据轨道增强光催化合成H2O2. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-0. doi: 10.1016/j.actphy.2025.100080

Get Citation
PDF
XML
Metrics
  • PDF Downloads(1182)
  • Abstract views(3359)
  • HTML views(51)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return