Citation:
QI Jun-Jie, YANG Ya, LIAO Qing-Liang, HUANG Yun-Hua, LIU Juan, ZHANG Yue. Fabrication and Characterization of In/ZnO-SiOx Core-Shell Nanocable Heterostructures[J]. Acta Physico-Chimica Sinica,
;2009, 25(09): 1721-1724.
doi:
10.3866/PKU.WHXB20090908
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Indiumdoped ZnO-SiOx core-shell nanocable heterostructures were successfully fabricated by introducing In ions into the raw material via a simple thermal evaporation process. X-ray diffraction (XRD), transmission electron microscopy (TEM), and energy dispersive X-ray spectroscopy (EDS) were used to investigate the structure of the In/ZnO-SiOx core-shell fibers. Results indicated that the core zone of ZnO nanocables is single crystalline In/ZnO with a wurtzite structure and the shell zone is a SiOx amorphous layer. The nanocables have high aspect ratio of more than 100 with widths of 30-60 nm. The growth mechanismof the nanocable heterostructures is different fromthe commonly reported metal-seeded vapor-liquid-solid (VLS) mechanism. The synthesis of core-shell structures reveals the general potential of radial heterostructure growth for the development of nanowire-based devices.
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Keywords:
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Nanostructure
, - In-doping,
- ZnO,
- Nanocable,
- Growth mechanism
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