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Citation: WANG Jian-Hua, LI Bin, WU Hai-Yan, GUO Yu-Zhong. Synthesis of Mesoporous SnO₂ and Its Application in Lithium-Ion Battery[J]. Acta Physico-Chimica Sinica, ;2008, 24(04): 681-685. doi: 10.3866/PKU.WHXB20080423 shu

Synthesis of Mesoporous SnO₂ and Its Application in Lithium-Ion Battery

1.
Key Laboratory of Advanced Material of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, P. R. China

Received Date: 23 October 2007
Available Online: 25 January 2008

Mesoporous SnO2 was synthesized using a cationic surfactant cetytrimethylammonium bromide (CTAB) as template and tin chloride (SnCl4·5H2O) as inorganic precursor. The product was examined with X-ray diffraction (XRD), N2-adsorption/desorption isotherms (BET), and transmission electron microscopy (TEM). Electrochemical properties of the mesoporous SnO2 were measured as anode of lithium-ion battery. The results showed that a certain amount of ammonium was critical for fabricating of ordered mesoporous structure. OH - ions served as structure director, helping Sn(ClxBry )2- unit to assemble into liquid crystal and form the ordered mesoporous structure. Electrochemical measurements showed od capacity retaining ability in 40 cycles. Large irreversible capacity loss can be attributed to trapping of Li+ ion in the pores.
- Mesoporous; Tin oxide; Lithium-ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis of Mesoporous SnO2 and Its Application in Lithium-Ion Battery

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Mesoporous SnO₂ and Its Application in Lithium-Ion Battery