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Citation: LOU Tai-Ping, WANG Jia-Liang. Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor of LiTi₂(PO₄)₃[J]. Acta Physico-Chimica Sinica, ;2007, 23(10): 1642-1646. doi: 10.3866/PKU.WHXB20071029 shu

Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor of LiTi₂(PO₄)₃

1.
School of Materials and Metallurgy, Northeastern University, Shenyang 110004, P. R. China

Received Date: 21 March 2007
Available Online: 4 July 2007

The lithium ion conductor LiTi₂(PO₄)₃ has a very high ion exchange selectivity to Na⁺ in sodium chloride solution. The ion exchange behavior of Na/Li for LiTi2(PO4)3 in NaCl solution was investigated. The experimental results showed that the Na/Li ion exchange reaction rate increased obviously for LiTi₂ (PO₄)₃with increasing temperature, and the Na/Li ion exchange kinetics process of LiTi2(PO4)3 in sodium chloride solution could be represented approximately by the equation of JMAK(Johnson-Mehl-Aurami-Kalmo rav). The dissolution behaviors of LiTi₂(PO₄)₃in water and NaCl solution were investigated, the results showed that higher temperature, acid or alkali environment could enhance the dissolution of LiTi₂(PO₄)₃.
- LiTi₂(PO₄)₃; Ion exchange; Dissolving
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沈阳化工大学材料科学与工程学院沈阳 110142

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Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor of LiTi2(PO4)3

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通讯作者: 陈斌, bchen63@163.com

Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor of LiTi₂(PO₄)₃