Citation:
ZHENG Wen-Qing, SUN De-Zhi, QU Xiu-Kui. Thermodynamic Properties of Dilution of Myo-inositol in Pure Water and Aqueous Sodium Halide Solutions[J]. Acta Physico-Chimica Sinica,
;2006, 22(10): 1277-1280.
doi:
10.3866/PKU.WHXB20061020
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The dilution enthalpies of myo-inositol in water and in aqueous sodium halide solutions have been determined with flow-mix-isothermal microcalorimetry at 298.15 K. The enthalpic interaction coefficients in the range of sodium halide solutions have been calculated according to the McMillan-Mayer theory. The results show that enthalpic pairwise interaction coefficients (h2) of myo-inositol are negative in aqueous sodium halide solutions and absolute values of h2 increase with elongation of radius of halogen anion.
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