Home

Citation: Kong De-Sheng, Li Liang. The Semiconducting Properties of Oxide Films Formed on Chromium Studied by Capacitance Measurement[J]. Acta Physico-Chimica Sinica, ;2004, 20(06): 631-636. doi: 10.3866/PKU.WHXB20040616 shu

The Semiconducting Properties of Oxide Films Formed on Chromium Studied by Capacitance Measurement

Kong De-Sheng ,
Li Liang

1.
Department of Chemistry, Qufu Normal University, Qufu　273165;Department of Chemistry, Shandong University, Jinan　250100

Received Date: 11 December 2003
Available Online: 15 June 2004

The semiconducting properties of the oxide film formed on chromium were studied by capacitance measurement and the Mott-Schottky analysis. It is shown that the oxide films formed on chromium within the passive potential region in 0.5 mol•L－1 H2SO4 solution, the thickness of which is about 1.2±0.3 nm, behavior like a p-type semiconductor. The impedance response of the film showed a low-frequency dispersion, which can be accounted for by dielectric relaxation with complex capacitance. The effects of the film-formation potential, the polarization time, and the solution pH on the semiconductive parameters of acceptor density (NA) and flatband potential (EFB) were investigated. The increase of NA corresponds to the increase of the hydration degree of the oxide films. The linear relationship with a slope of ～59 mV/pH unit between EFB and solution pH was observed.
- Chromium;Passive film;Capacitance measurement;Acceptor density;　Flatband potential
1. [1]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
2. [2]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . High-Precision and Reliable Thermal Conductivity Measurement for Graphene Films Based on an Improved Steady-State Electric Heating Method. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-0. doi: 10.1016/j.actphy.2025.100045
3. [3]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
4. [4]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
5. [5]
  Ruihu Wang , Aidang Lu . 新型铬(VI)检测试纸的制备及应用——介绍一个应用化学综合实验. University Chemistry, 2025, 40(8): 284-290. doi: 10.12461/PKU.DXHX202410102
6. [6]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
7. [7]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
8. [8]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
9. [9]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009
10. [10]
  Weitai Wu , Laiying Zhang , Yuan Chun , Liang Qiao , Bin Ren . Course Design of Chemical Measurement Experiments in Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 64-68. doi: 10.12461/PKU.DXHX202409031
11. [11]
  Laiying Zhang , Weitai Wu , Yiru Wang , Shunliu Deng , Zhaobin Chen , Jiajia Chen , Bin Ren . Practices for Improving the Course of Chemical Measurement Experiments in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 107-112. doi: 10.12461/PKU.DXHX202409032
12. [12]
  Wanchun Zhu , Yongmei Liu , Li Wang , Yunshan Bai , Shu'e Song , Xiaokui Wang , Zhongyun Wu , Hong Yuan , Yunchao Li , Fuping Tian , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement and Control of Temperature. University Chemistry, 2025, 40(5): 128-136. doi: 10.12461/PKU.DXHX202503028
13. [13]
  Zhongyun Wu , Li Wang , Xiaokui Wang , Wanchun Zhu , Yuan Chun , Fuping Tian , Yongmei Liu , Yunshan Bai , Hong Yuan , Yufeng Li , Shu'e Song , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement and Control of Pressure. University Chemistry, 2025, 40(5): 137-147. doi: 10.12461/PKU.DXHX202503027
14. [14]
  Shu'e Song , Xiaokui Wang , Yongmei Liu , Wanchun Zhu , Hong Yuan , Fuping Tian , Yunshan Bai , Yunchao Li , Li Wang , Zhongyun Wu , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Viscosity, Density and Optical Properties. University Chemistry, 2025, 40(5): 148-156. doi: 10.12461/PKU.DXHX202503026
15. [15]
  Fuping Tian , Yunshan Bai , Wanchun Zhu , Yufeng Li , Yongmei Liu , Shu'e Song , Hong Yuan , Zhongyun Wu , Li Wang , Xiaokui Wang , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Thermal Properties. University Chemistry, 2025, 40(5): 157-164. doi: 10.12461/PKU.DXHX202503054
16. [16]
  Yunchao Li , Hong Yuan , Yuan Chun , Xiaokui Wang , Fuping Tian , Yunshan Bai , Yongmei Liu , Wanchun Zhu , Shu'e Song , Zhongyun Wu , Li Wang , Yufeng Li , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Electrical Properties. University Chemistry, 2025, 40(5): 165-177. doi: 10.12461/PKU.DXHX202503055
17. [17]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yamauchi Yusuke , Melhi Saad , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 2404006-0. doi: 10.3866/PKU.WHXB202404006
18. [18]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
19. [19]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
20. [20]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046

Get Citation

PDF

XML

Metrics

PDF Downloads(2619)
Abstract views(3388)
HTML views(83)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return