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Citation: Huang Jian-Bin, Gao Qiang, Wang Chuan-Zhong. The Research of a Novel Kind of Chiral Surfactant[J]. Acta Physico-Chimica Sinica, ;2003, 19(04): 302-306. doi: 10.3866/PKU.WHXB20030404 shu

The Research of a Novel Kind of Chiral Surfactant

1.
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing　100871

Received Date: 10 July 2002
Available Online: 15 April 2003

A pair of optical isomerism amphiphlic molecules L-C10HL（N-(4-decaoxygen- 2-hydroxybenzene methylene)-L-leucine） and D-C10HL（N-(4-decaoxygen-2-hydroxybenzene methylene)-D-leucine）were synthesized. It was found that these two compounds showed superior surface activity and aggregation capability at higher pH value, which is so different from the traditional carboxylate surfactants. Furthermore, the interaction of L-C10HL and D-C10HL with cyclodextrin was also investigated by fluorescence excitation spectrum and circular dichroism spectrum.
- Chiral surfactant;Vesicle;Surface activity;Fluorescence spectrum;　Circular dichroism spectrum
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