Citation:
Bi Hui-Min, Che Hui-Juan, Zheng Shi-Jun, Meng Ling-Peng, Wang Dian-Xun. Gas-Solid Reaction Mechanism of X2 (X=Cl,Br) and A CN under the Condition of Super Vacuum[J]. Acta Physico-Chimica Sinica,
;2003, 19(03): 272-274.
doi:
10.3866/PKU.WHXB20030319
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The gas-solid heterogeneous reaction between X2 (X=Cl, Br) and A CN has been investigated under the condition of super vacuum, HeI photoelectron spectroscopy (PES) indicates that XNCO was produced, and we deduce that an inter mediate complex in this process was formed, i.e. the generation of new-bond and the broken of old-bond were ing simultaneously.
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