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Citation: Cao Li-Xin, Zhou Bao-Xue, Shi Peng-Fei, Zhou Li-Zhuang. Systematic Study of the Standard Transfer Gibbs Energy of Potassium Tetrophenylb orate from Water to Water and Alcohol Mixtures[J]. Acta Physico-Chimica Sinica, ;2001, 17(06): 565-569. doi: 10.3866/PKU.WHXB20010619 shu

Systematic Study of the Standard Transfer Gibbs Energy of Potassium Tetrophenylb orate from Water to Water and Alcohol Mixtures

1.
Department of Natural Science, Harbin Institute of Technology, Weihai Campus, W eihai　264200; Department of Applied Chemistry, Harbin Institute of Technology,Harbin　150001; Department of Chemistry, Yantai Teacher′s College, Yantai　264025

Received Date: 3 November 2000
Available Online: 15 June 2001

The standard transfer Gibbs energies (ΔtrG°)of KBPh4 from reference solvent of water to water/ethanol, water/propanol, water/2 propanol,water/ethylene glycol, water/glycerol mixtures in different proportional ratio have been studied. The interactions of KBPh4 with the above mixed solvents were analyzed. The standard transfer Gibbs energy of cavity(ΔtrG°cav) and the standard transfer Gibbs energy of interaction(ΔtrG° int) from water to water/2propanol mixtu res at 298.15 K were calculated by the Scaled Particle Theory (SPT).
- Standard transfer Gibbs energy;Standard transfer Gibbs energy of cavity;Standard transfer Gibbs energy of interaction;Potassium Tetrophenylborate
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