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Citation: Li Hua-Ming, Ye Xing-Kai, Wu Yue. Effect of FePc Structure on the Activity in the Oxidation of Cyclohexene Catalyzed by Pd(OAc)₂/HQ/FePc[J]. Acta Physico-Chimica Sinica, ;2001, 17(05): 432-437. doi: 10.3866/PKU.WHXB20010511 shu

Effect of FePc Structure on the Activity in the Oxidation of Cyclohexene Catalyzed by Pd(OAc)₂/HQ/FePc

1.
Changchun Institute of Applied Chemistry ,Chinese Academy of Sciences,Changchun　130022;Department of Chemistry ,Hainan Normal University ,Haikou　571158

Received Date: 8 October 2000
Available Online: 15 May 2001

In an acidic aqueous solution of acetonitrile,the catalytic activity of the catalysts consisted of Pd(OAc)2/hydroquinone(HQ) with iron phthalocyanine (FePc) from various sources was obviously different in the oxidation of cyclohexene to cyclohexanone.The analysis of the FePc using IR spectroscopy,Mssbauer spectroscopy,Xray photoelectron spectroscopy (XPS),Xray powder diffraction (XRD),scanning electron microscopy(SEM) and BET surface area measurement indicated that the catalytic activity of the multicomponent catalytic system composed of iron phthalocyanines depends on the amount of μ-oxo FePc,the crystallinity and the surface structure of iron phthalocyanine.
- Cyclohexene;Catalytic oxidation;Iron phthalocyanine(FePc)
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Effect of FePc Structure on the Activity in the Oxidation of Cyclohexene Catalyzed by Pd(OAc)2/HQ/FePc

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通讯作者: 陈斌, bchen63@163.com

Effect of FePc Structure on the Activity in the Oxidation of Cyclohexene Catalyzed by Pd(OAc)₂/HQ/FePc