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Citation: Kong Yong, Mu Shao-Lin. Electrochemical Polymerization of Thionine and Properties of Polythionine[J]. Acta Physico-Chimica Sinica, ;2001, 17(04): 295-299. doi: 10.3866/PKU.WHXB20010403 shu

Electrochemical Polymerization of Thionine and Properties of Polythionine

Kong Yong ,
Mu Shao-Lin

1.
Department of Chemistry, School of Sciences,Yangzhou University,Yangzhou　225002

Received Date: 25 July 2000
Available Online: 15 April 2001

The electrochemical polymerization of thionine in the aqueous acetic solution has been carried out using cyclic voltammetry. Polythionine is a blue material. Its color can be quickly changed by applied potential. Polythionine has a od electrochemical reversibility, stability and a fast charge transfer ability in the solution of 0.50 mol•dm－3 HCl to the solution of acetate of pH 6.0. Visible and FTIR spectra of polythionine have been presented in this paper. Based on FTIR spectra, a suggestion for mechanism of polymerization of thionine is presented.
- Thionine;Electrochemical polymerization;Spectra of polythionine;　 Electrochemical properties
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