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Citation: Zheng Kang-Cheng, Kuang Dai-Bin, Shen Yong, Wang Ju-Ping. Ru(bpy)2+3 and its Di-substituted Effects of the One bpy[J]. Acta Physico-Chimica Sinica, ;2001, 17(01): 43-47. doi: 10.3866/PKU.WHXB20010109 shu

Ru(bpy)2+3 and its Di-substituted Effects of the One bpy

1.
School of Chemistry and Chemical Engineering, Zhongshan University,Guangzhou　510275

Received Date: 11 May 2000
Available Online: 15 January 2001

Studies on the complex and its 4,4′disubstituted derivates on one bpy are carried out by using DFT method at B3LYP/LanL2DZ level. The regularities of the substituent effects of stronger electronpushing group (－OCH3)and stronger electrondrawing group (－NO2) on affecting the electronic structure and its related properties, e.g., the coordination bond lengths and the spectroscopy properties, etc., have been investigated. The results obtained may be useful as references for the synthesis of the complexes, the mechanism analysis on photochemistry , electrochemistry, catalysischemistry and biochemistry of the complexes , etc.
- 2,2′-bipyridine(bpy);Ru(II) bipyridine complex;Photochemistry;　Electrochemistry;DFT method
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