Citation:
Zhou Jia-Hong, Xue Kuan-Hong, Sun Dong-Mei, Xu Shi-Min, Kong Jing-Lin. AC Impednce Study of the Aqueous Zn/V2O5 Secondary Battery[J]. Acta Physico-Chimica Sinica,
;2000, 16(05): 454-458.
doi:
10.3866/PKU.WHXB20000516
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The dependence of charge transfer resistances of electrodes in the aqueous Zn/V 2O 5 secondary battery on the Zn 2+ amount intercalated was studied by means of AC impedance experiments. The results showed that the electrode reaction on cathode was controlled by the diffusion of Zn 2+ at the beginning of the discharge process. With the increase of Zn 2+ amount intercalated into the cathode, the reaction became a kinetic controlled process, i.e.a process controlled by intercalation of Zn 2+ in V 2O 5.
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Keywords:
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Secondary battery
, - Zinc battery,
- V2O5,
- Impedance
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